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The mixing of organic cations represents yet another direction to explore in the field of chiral organic-inorganic hybrid metal halides (OIHMH). Here, we perform structural optimizations, electronic structures, and non-linear optical (NLO)…

Chiroptical effects, characterized by different optical responses for left- (LCP) and right- handed circularly polarized light (RCP), are powerful and valuable tools in optics with wide applications in polarization resolved imaging and…

Optics · Physics 2018-05-02 Weimin Ye , Xiaodong Yuan , Chucai Guo , Jianfa Zhang , Biao Yang , Shuang Zhang

Chiral metal halide perovskites have emerged as promising optoelectronic materials for emission and detection of circular polarized visible light. Despite chirality being realized by adding chiral organic cations or ligands, the chiroptical…

Materials Science · Physics 2023-09-26 Sofia Apergi , Geert Brocks , Shuxia Tao

Hybrid organic-inorganic perovskites with chiral organic cations are very interesting for optoelectronic applications because of their intrinsically chiral light-matter interactions. Chiral distortions in these materials lead to circular…

High harmonic generation (HHG) records the ultrafast electronic response of matter to light, encoding key properties of the interrogated quantum system, such as chirality. The first implementation of chiral HHG [Cireasa et al. Nat. Phys.…

Chiral perovskites owing to their broken mirror symmetry exhibit selective absorption of circularly polarized light manifesting a strong circular dichroism (CD). CD spectroscopy has been a key technique to understand chiral perovskites and…

Materials Science · Physics 2026-02-10 Reshna Shrestha , Wanyi Nie

Chiral light sources realized in ultracompact device platforms are highly desirable for various applications. Among active media employed for thin-film emission devices, lead-halide perovskites have been extensively studied for…

The ultrafast polarization response to incident light and ensuing exciton/carrier generation are essential to outstanding optoelectronic properties of lead halide perovskites (LHPs). A large number of mechanistic studies in the LHP field to…

Chiroptical effects using circularly polarized light produce signals that change sign when switching either molecular handedness (enantiosensitivity) or the light helicity (circular dichroism). Here, we break this…

Organic-inorganic hybrid halide perovskites have ignited tremendous interests for photovoltaic applications. However, their nonlinear optical response has not been studied although many of these structures lack the centrosymmetry and…

Materials Science · Physics 2020-02-14 Wenshen Song , Guang-Yu Guo , Su Huang , Lan Yang , Li Yang

We demonstrate theoretically that non-chiral perovskite layers can exhibit circular dichroism (CD) in the absence of a magnetic field and without chiral activation by chiral molecules. The effect is shown to be due to splitting of helical…

Mesoscale and Nanoscale Physics · Physics 2024-12-03 Peter C. Sercel , Zeev Valy Vardeny , Alexander L. Efros

Planar chiral structures possess a two dimensional handedness that is associated with broken mirror symmetry. Such motifs span vast length scales; examples include certain pinwheel molecules, nautilus shells, cyclone wind patterns and…

Chiral circularly polarized (CP) light is central to many photonic technologies, from optical communication of spin information to novel display and imaging technologies. As such, there has been significant effort in the development of…

Materials Science · Physics 2023-07-25 Li Wan , Yizhou Liu , Matthew J. Fuchter , Binghai Yan

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

Optics · Physics 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

We study the chirality of periodically poled MgO-doped lithium niobate (MgO:PPLN) by electro-optic (EO) effect. It shows that optical propagation is reciprocal in MgO:PPLN when quasi-phase-matching (QPM) condition is satisfied, which is…

Optics · Physics 2012-04-19 Lei Shi , Linghao Tian , Xianfeng Chen

Light-matter strong coupling (LMSC) is intriguing state in which light and matter are coherently hybridized inside cavity. It has been gaining widespread recognition as an excellent way for controlling material properties without any…

Optics · Physics 2024-03-19 Daichi Okada , Fumito Araoka

The interplay of polarization and magnetism in materials with light can create rich nonlinear magneto-optical (NLMO) effects, and the recent discovery of two-dimensional (2D) van der Waals magnets provides remarkable control over NLMO…

Materials Science · Physics 2024-04-30 Dezhao Wu , Meng Ye , Haowei Chen , Yong Xu , Wenhui Duan

Chirality is a fundamental asymmetry phenomenon, with chiral optical elements exhibiting asymmetric response in reflection or absorption of circularly polarized light. Recent realizations of such elements include nanoplasmonic systems with…

We identify the existence of nonlinear optical (NLO) activity in a number of novel $ABX_3$-type metal-free perovskites, where $A$ is a highly tuneable organic cation, $B$ is a NH$_4$ cation and $X$ a halide anion. Through systematic…

Circular dichroism (CD) induced by spin angular momentum of light is vital to investigate the chirality of microscopic objects such as molecules, proteins and metamaterials. However, orbital angular momentum (OAM) of light failed to…

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