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Superionic conductors, or solid-state ion-conductors surpassing 0.01 S/cm in conductivity, can enable more energy dense batteries, robust artificial ion pumps, and optimized fuel cells. However, tailoring superionic conductors require…

Instrumentation and Detectors · Physics 2024-07-23 Kim H. Pham , Scott K. Cushing

Solid ionic conductors are essential components of batteries and fuel cells. In many cases, ionic conduction through crystalline materials with substitutional disorder can be modeled with atomic-scale lattice model percolation simulations.…

Materials Science · Physics 2023-02-15 Alexander Urban

Electrical conductivity of dry, slow cooled (AgPO$_3$)$_{1-x}$(AgI)$_x$ glasses is examined as a function of temperature, frequency and glass composition. From these data compositional trends in activation energy for conductivity E$_A$(x),…

Materials Science · Physics 2015-05-14 M. Micoulaut , M. Malki , D. I. Novita , P. Boolchand

The thermal resistance associated with the interface between a solid and a liquid is analyzed from an atomistic point of view. Partial evaluation of the associated Green-Kubo integral elucidates the various factors governing heat transport…

Statistical Mechanics · Physics 2022-01-26 Nicolas G. Hadjiconstantinou , Mathew M. Swisher

Amorphous polymers are known as thermal insulators, increasing their thermal conductivities have not been guided by fully understood physics. In this work, we use molecular dynamics simulations to study the thermal transport mechanism of…

Soft Condensed Matter · Physics 2019-04-03 Xingfei Wei , Tengfei Luo

The amorphous solids can be theoretically modeled by anharmonic disordered lattices. However, most of theoretical studies on thermal conductivity in anharmonic disordered lattices only focus on the potentials of hard-type (HT)…

Statistical Mechanics · Physics 2023-03-16 Jianjin Wang , Chi Xiong , Daxing Xiong

Many complex crystals show a flattening or even increasing lattice thermal conductivity at high temperatures, which deviates from the traditional 1/T decay trend given by conventional phonon theory. In this work, we predict the thermal…

Materials Science · Physics 2023-12-20 Janak Tiwari , Tianli Feng

We study the electronic thermal conductivity $\kappa_\textrm{el}$ and the thermal diffusion constant $D_\textrm{Q,el}$ in the square lattice Hubbard model using the finite-temperature Lanczos method. We exploit the Nernst-Einstein relation…

Strongly Correlated Electrons · Physics 2022-12-28 Martin Ulaga , Jernej Mravlje , Peter Prelovšek , Jure Kokalj

Ternary pnictides semiconductors with II-IV-V2 stoichiometry hold potential as cost effective thermoelectric materials with suitable electronic transport properties, but their lattice thermal conductivities ($\kappa$) are typically too…

Glasses usually represent the lower limit for the thermal conductivity of solids, but a fundamental understanding of lattice heat transport in amorphous materials can provide design rules to beat such a limit. Here we investigate the role…

Materials Science · Physics 2021-01-27 Nicholas W. Lundgren , Giuseppe Barbalinardo , Davide Donadio

The current work is focused on the impact of the lithium stoichiometry on electrical conductivity, acoustic properties and high-temperature stability of single crystalline Li(Nb,Ta)O$_{3}$ at high temperatures. The crystals grown from…

Fluid, heat and species transport and oxygen reduction in the cathode of a PEM fuel cell are simulated using multi relaxation lattice Boltzmann method. Heat generation due to oxygen reduction and its effects on transport and reaction are…

Fluid Dynamics · Physics 2021-03-03 M. Jithin , Saurabh Siddharth , Malay K. Das , Ashoke De

Recently, machine-learning approaches have accelerated computational materials design and the search for advanced solid electrolytes. However, the predictors are currently limited to static structural parameters, which may not fully account…

Materials Science · Physics 2026-01-19 Jiyeon Kim , Donggeon Lee , Dongwoo Lee , Xin Li , Yea-Lee Lee , Sooran Kim

Investigation of the inherent field-driven charge transport behaviour of 3D lead halide perovskites has largely remained a challenging task, owing primarily to undesirable ionic migration effects near room temperature. In addition, the…

High-temperature bad-metal transport has been recently studied both theoretically and in experiments as one of the key signatures of strong electronic correlations. Here we use the dynamical mean field theory (DMFT) and its cluster…

Strongly Correlated Electrons · Physics 2020-09-23 A. Vranic , J. Vucicevic , J. Kokalj , J. Skolimowski , R. Zitko , J. Mravlje , D. Tanaskovic

Fast ionic conduction is a defining property of solid electrolytes for all-solid-state batteries. Previous studies have suggested that liquid-like cation motion associated with fast ionic transport can disrupt crystalline symmetry, thereby…

Inorganic clathrates such as Ba$_8$Ga$_{x}$Ge$_{46-x}$ and Ba$_8$Al$_{x}$Si$_{46-x}$ commonly exhibit very low thermal conductivities. A quantitative computational description of this important property has proven difficult, in part due to…

We apply the Green-Kubo (G-K) approach to obtain the thermal conductivity tensor of $\beta$-1,3,5,7-tetranitro-1,3,5,7-tetrazocane ($\beta$-HMX) as a function of pressure and temperature from equilibrium molecular dynamics (MD) simulations.…

Materials Science · Physics 2023-09-18 Andrey Pereverzev , Tommy Sewell

In the design of materials with low lattice thermal conductivity, compounds with high density, low speed of sound, and complexity at either the atomic, nano- or microstructural level are preferred. The layered compound Mg$_3$Sb$_2$ defies…

Materials Science · Physics 2018-04-05 Wanyue Peng , Guido Petretto , Gian-Marco Rignanese , Geoffroy Hautier , Alexandra Zevalkink

A systematic study was performed to measure the effective thermal conductivity of ceramic particle beds, a promising heat transfer and thermal energy storage media for concentrating solar power (CSP). The thermal conductivity of the ceramic…

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