Related papers: The Young-Laplace equation for a solid-liquid inte…
An analytical solution based on a diffuse interface model is presented for an isothermal evaporation problem under sub-saturation pressure. The macroscopic equations are derived from the free-energy method, widely recognized in the lattice…
Using the chemical potential of a solid in a dissolved state or the corresponding component of the chemical potential tensor at equilibrium with the solution, a new concept of grand thermodynamic potential for solids has been suggested.…
Fluid flows in coupled systems consisting of a free-flow region and the adjacent porous medium appear in a variety of environmental settings and industrial applications. In many applications, fluid flow is non-parallel to the fluid-porous…
A continuum model of crystalline solid equilibrium is presented in which the underlying periodic lattice structure is taken explicitly into account. This model also allows for both point and line defects in the bulk of the lattice and at…
The influence of the external pressure and surface energy on the wetting transition at nanotextured interfaces is studied using molecular dynamics and continuum simulations. The surface roughness of the composite interface is introduced via…
We consider the free boundary problem for two layers of immiscible, viscous, incompressible fluid in a uniform gravitational field, lying above a rigid bottom in a three-dimensional horizontally periodic setting. The effect of surface…
For well-stirred multiphase fluid systems the mean interface area per unit volume, or "specific interface area" $S_V$, is a significant characteristic of the system state. In particular, it is important for the dynamics of systems of…
It is generally accepted that the effective velocity of a viscous flow over a porous bed satisfies the Beavers-Joseph slip law. To the contrary, in the case of a forced infiltration of a viscous fluid into a porous medium the interface law…
Vibrations can dynamically stabilize otherwise unstable liquid interfaces and produce new dynamic equilibria, called vibro-equilibria. Typically, the vibrations are homogeneous in the liquid and the liquid interface remains approximately…
In part 1, we proposed a model of dynamics of wetting for slow movements near a contact line formed at the interface of two immiscible fluids and a solid when viscous dissipation remains bounded. The contact line is not a material line and…
Structural correlations at a liquid-solid interface were explored with molecular dynamics simulations of a model aluminium system using the Ercolessi-Adams potential and up to 4320 atoms. Substrate atoms were pinned to their equilibrium…
An overview of some analytical approaches to the computation of the structural and thermodynamic properties of single component and multicomponent hard-sphere fluids is provided. For the structural properties, they yield a thermodynamically…
Four results associated with the diffuse-interface model (DIM) for contact lines are reported in this paper. First, a boundary condition is derived, which states that the fluid near a solid wall must have a certain density $\rho_{0}$…
Thermodynamic quantities of the hard-sphere system in the steady state with a small heat flux are calculated within the continuous media approach. Analytical expressions for pressure, internal energy, and entropy are found in the…
To express the capillary stress in the diffuse interface method, there are two different formulations in the literature: one formulation is proportional to the density and the other is to the density gradient. Confusingly, these two…
A closed virial equation-of-state for the low density fluid phase of hard disks is obtained from the known virial coefficients. The equation exhibits 6-figure accuracy for the thermodynamic (MD) pressure up to the reduced number density ~…
We present a theory for the kinetics of surfactant adsorption at the interface between an aqueous solution and another fluid (air, oil) phase. The model relies on a free-energy formulation. It describes both the diffusive transport of…
Confined fluids display complex behavior due to layering and local packing. Here, we disentangle these effects by confining a hard-sphere fluid to the surface of a cylinder, such the circumference extends only over a few particle diameters.…
By using a limit analysis for the motion equations of viscous fluid endowed with internal capillarity, we are able to propose a dynamical expression for the surface tension of moving liquid-vapour interfaces without any phenomenological…
We show that an electro-osmotic flow near the slippery hydrophobic surface depends strongly on the mobility of surface charges, which are balanced by counter-ions of the electrostatic diffuse layer. For a hydrophobic surface with immobile…