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We present model-assisted density fitting (MADF) basis set generator, an algorithm for generating primitive atomic Gaussian density fitting (DF) basis sets (DFBSs) from a contracted Gaussian orbital basis set (OBS). The MADF algorithm…

Chemical Physics · Physics 2025-10-14 Kshitijkumar A. Surjuse , Edward F. Valeev

The many-body perturbation theory within the $GW$ approximation is a widely used method for describing the electronic band structures in real materials. Its application to large-scale systems is, however, impeded by its high computational…

Materials Science · Physics 2026-05-22 Min-Ye Zhang , Peize Lin , Rong Shi , Xinguo Ren

Quasiparticle (QP) excitations are extremely important for understanding and predicting charge transfer and transport in molecules, nanostructures and extended systems. Since density functional theory (DFT) within the Kohn-Sham (KS)…

Chemical Physics · Physics 2017-07-18 Vojtech Vlcek , Eran Rabani , Daniel Neuhauser , Roi Baer

Within the framework of many-body perturbation theory based on Green's functions, the $GW$ approximation has emerged as a pivotal method for computing quasiparticle energies and excitation spectra. However, its high computational cost and…

Chemical Physics · Physics 2025-12-25 Yueyang Zhang , Wei Wu , Peifeng Su

In recent years, Rectified flow (RF) has gained considerable popularity largely due to its generation efficiency and state-of-the-art performance. In this paper, we investigate the degree to which RF automatically adapts to the intrinsic…

Machine Learning · Statistics 2026-02-24 Saptarshi Roy , Alessandro Rinaldo , Purnamrita Sarkar

We introduce a new strategy for coupling the parallel in time (parareal) iterative methodology with multiscale integrators. Following the parareal framework, the algorithm computes a low-cost approximation of all slow variables in the…

Numerical Analysis · Mathematics 2015-11-19 Gil Ariel , Seong Jun Kim , Richard Tsai

Interferometric scattering microscopy (iSCAT) can image the dynamics of nanometer-scale systems. The typical approach to analyzing interferometric images involves intensive processing, which discards data and limits the precision of…

Hard combinatorial optimization problems, often mapped to Ising models, promise potential solutions with quantum advantage but are constrained by limited qubit counts in near-term devices. We present an innovative quantum-inspired framework…

Quantum Physics · Physics 2024-12-25 Co Tran , Quoc-Bao Tran , Hy Truong Son , Thang N Dinh

Dynamical screening is a key property of charged many-particle systems. Its theoretical description is based on the $GW$ approximation that is extensively applied for ground-state and equilibrium situations but also for systems driven out…

Strongly Correlated Electrons · Physics 2023-02-14 Jan-Philip Joost , Niclas Schlünzen , Hannes Ohldag , Michael Bonitz , Fabian Lackner , Iva Březinová

The numerical simulation of multiphase flows involving dispersed components with large scale disparities, such as the collisions between millimeter-sized bubbles and micron-sized mineral particles in flotation, poses a significant…

Fluid Dynamics · Physics 2026-05-21 Linfeng Jiang , Enrico Calzavarini , Dominik Krug

The recently developed interpolative separable density fitting (ISDF) decomposition is a powerful way for compressing the redundant information in the set of orbital pairs, and has been used to accelerate quantum chemistry calculations in a…

Computational Physics · Physics 2017-11-07 Kun Dong , Wei Hu , Lin Lin

We present, within Kohn-Sham Density Functional Theory calculations, a quantitative method to identify and assess the partitioning of a large quantum mechanical system into fragments. We then show how within this framework simple…

Chemical Physics · Physics 2017-09-28 Stephan Mohr , Michel Masella , Laura E. Ratcliff , Luigi Genovese

We propose a projected Wasserstein gradient descent method (pWGD) for high-dimensional Bayesian inference problems. The underlying density function of a particle system of WGD is approximated by kernel density estimation (KDE), which faces…

Machine Learning · Computer Science 2021-02-16 Yifei Wang , Peng Chen , Wuchen Li

We propose the regularized compressed double factorization (RC-DF) method to classically compute compressed representations of molecular Hamiltonians that enable efficient simulation with noisy intermediate scale (NISQ) and error corrected…

Given a set of Kohn-Sham orbitals from an insulating system, we present a simple, robust, efficient and highly parallelizable method to construct a set of, optionally orthogonal, localized basis functions for the associated subspace. Our…

Computational Physics · Physics 2014-11-05 Anil Damle , Lin Lin , Lexing Ying

We introduce a general framework for large-scale model-based derivative-free optimization based on iterative minimization within random subspaces. We present a probabilistic worst-case complexity analysis for our method, where in particular…

Optimization and Control · Mathematics 2021-02-25 Coralia Cartis , Lindon Roberts

We present an implementation of the $GW$ space-time approach that allows cubic-scaling all-electron calculations with standard Gaussian basis sets without exploiting any localization nor sparsity considerations. The independent-electron…

Computational Physics · Physics 2021-04-29 Ivan Duchemin , Xavier Blase

We study the iterative methods for large moment systems derived from the linearized Boltzmann equation. By Fourier analysis, it is shown that the direct application of the block symmetric Gauss-Seidel (BSGS) method has slower convergence…

Numerical Analysis · Mathematics 2024-07-11 Xiaoyu Dong , Zhenning Cai

This article is concerned with the numerical solution of subspace optimization problems, consisting of minimizing a smooth functional over the set of orthogonal projectors of fixed rank. Such problems are encountered in particular in…

Numerical Analysis · Mathematics 2022-10-17 Eric Cancès , Gaspard Kemlin , Antoine Levitt

The $GW$ approximation is a widely used method for computing electron addition and removal energies of molecules and solids. The computational effort of conventional $GW$ algorithms increases as $O(N^4)$ with the system size $N$, hindering…

Chemical Physics · Physics 2024-09-12 Mia Schambeck , Dorothea Golze , Jan Wilhelm