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We performed large-scale molecular dynamics simulations based on a machine-learning force field (MLFF) to investigate the Li-ion transport mechanism in cation-disordered Li$_3$TiCl$_6$ cathode at six different temperatures, ranging from…

Materials Science · Physics 2024-06-19 Selva Chandrasekaran Selvaraj , Volodymyr Koverga , Anh T. Ngo

Solid-state superionic conductors (SSICs) are promising alternatives to liquid electrolytes in batteries and other energy storage technologies. The rational design of SSICs and ultimately their deployment in battery technologies is hindered…

Chemical Physics · Physics 2023-06-02 Harender S. Dhattarwal , Rahul Somni , Richard C. Remsing

Solid state lithium- and sodium-ion batteries utilize solid ionicly conducting compounds as electrolytes. However, the ionic conductivity of such materials tends to be lower than their liquid counterparts, necessitating research efforts…

Materials Science · Physics 2020-03-12 Yijie Xu , Yun Zong , Kedar Hippalgaonkar

Recently, machine-learning approaches have accelerated computational materials design and the search for advanced solid electrolytes. However, the predictors are currently limited to static structural parameters, which may not fully account…

Materials Science · Physics 2026-01-19 Jiyeon Kim , Donggeon Lee , Dongwoo Lee , Xin Li , Yea-Lee Lee , Sooran Kim

Mixed ionic-electronic conductors (MIECs) exhibit both high ionic and electronic conductivity to improve the battery performance. In this work, we investigate the mechanism and stability of transport channels in our recently developed MIEC…

Materials Science · Physics 2026-05-29 Selva Chandrasekaran Selvaraj , Daiwei Wang , Donghai Wang , Anh T. Ngo

Fast ionic conduction is a defining property of solid electrolytes for all-solid-state batteries. Previous studies have suggested that liquid-like cation motion associated with fast ionic transport can disrupt crystalline symmetry, thereby…

We discover many new crystalline solid materials with fast single crystal Li ion conductivity at room temperature, discovered through density functional theory simulations guided by machine learning-based methods. The discovery of new solid…

Materials Science · Physics 2019-04-22 Austin D. Sendek , Ekin D. Cubuk , Evan R. Antoniuk , Gowoon Cheon , Yi Cui , Evan J. Reed

Lithium superionic conductors (LSICs) are crucial for next-generation solid-state batteries, offering exceptional ionic conductivity and enhanced safety for renewable energy and electric vehicles. However, their discovery is extremely…

Materials Science · Physics 2024-12-17 Dong Chen , Bingxu Wang , Shunning Li , Wentao Zhang , Kai Yang , Yongli Song , Guo-Wei Wei , Feng Pan

Li-Ion Solid-State Electrolytes (Li-SSEs) are a promising solution that resolves the critical issues of conventional Li-Ion Batteries (LIBs) such as poor ionic conductivity, interfacial instability, and dendrites growth. In this study, a…

Materials Science · Physics 2022-02-15 Seungpyo Kang , Minseon Kim , Kyoungmin Min

Solid-ion conductors (SICs) comprising non-ionic plastic crystals and lithium salts often require compositing with polymers to render them processable for use in solid-state lithium-metal batteries. Here, we show that polymer-doped plastic…

Sodium-ion batteries (SIBs) have garnered significant attention in recent years as a promising alternative to lithium-ion batteries (LIBs) due to their low cost, abundant sodium resources, and excellent cycling performance. Hard carbon…

Materials Science · Physics 2024-12-05 Zhaoming Wang , Guanghui Shi , Guanghui Wang , Man Wang , Xiao Wang , Feng Ding

Discovering new superionic materials is essential for advancing solid-state batteries, which offer improved energy density and safety compared to the traditional lithium-ion batteries with liquid electrolytes. Conventional computational…

Lithium zirconium chlorides (LZCs) present a promising class of cost-effective solid electrolyte for next-generation all-solid-state batteries. The unique crystal structure of LZCs plays a crucial role in facilitating lithium-ion mobility,…

Materials Science · Physics 2025-10-09 Hanzeng Guo , Volodymyr Koverga , Selva Chandrasekaran Selvaraj , Anh T. Ngo

With the rapid development of energy storage technology, high-performance solid-state electrolytes (SSEs) have become critical for next-generation lithium-ion batteries. These materials require high ionic conductivity, excellent…

Materials Science · Physics 2025-02-17 Hongwei Du , Jian Hui , Lanting Zhang , Hong Wang

The quasiparticle method, which has achieved a great success in solid state electronics and crystal lattice vibration, is adopted to study the solid state ion transport. A general recipe is put forward to map the classical solid state ion…

Materials Science · Physics 2024-02-13 Jiaming Hu

Lithium chloride LiCl is widely used as a prototype system to study the strongly dissociated 1-1 electrolyte solution. Here, we combined experimental measurements and classical molecular dynamics simulations to study the ion conduction in…

Soft Condensed Matter · Physics 2019-05-14 Are Yllö , Chao Zhang

Basic understanding of the driving forces of ion conduction in solids is critical to the development of new solid-state ion conductors. Physical understanding of ion conduction is limited due to strong deviations from harmonic vibrational…

Materials Science · Physics 2020-12-15 Thomas M. Brenner , Christian Gehrmann , Roman Korobko , Tsachi Livneh , David A. Egger , Omer Yaffe

Solid-state batteries require lithium-ion conductors that combine high ionic conductivity with stability under harsh electrochemical and chemical conditions. Here, we investigate the chemical factors governing the stability of NASICON-type…

Materials Science · Physics 2026-03-26 Zhuohan Li , KyuJung Jun , Bowen Deng , Gerbrand Ceder

We present a high-throughput computational screening for fast lithium-ion conductors to identify promising materials for application in all solid-state electrolytes. Starting from more than 30,000 Li-containing experimental structures…

Materials Science · Physics 2026-01-07 Tushar Singh Thakur , Loris Ercole , Nicola Marzari

The available sites for ions in a typical disordered ionic conductor are determined. For this purpose we devised a straightforward algorithm which via cluster analysis identifies these sites from long time ionic trajectories below the glass…

Condensed Matter · Physics 2009-11-10 Heiko Lammert , Magnus Kunow , Andreas Heuer
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