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A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

Statistical Mechanics · Physics 2013-05-29 Hiroki Majima , Akira Suzuki

From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic…

Mathematical Physics · Physics 2014-11-21 Gian Paolo Beretta , Enzo Zanchini

The second law of thermodynamics can be expressed in terms of entropy production, which can be used to quantify the degree of irreversibility of a process. In this Chapter, we consider the standard scenario of open quantum systems, where a…

Quantum Physics · Physics 2025-01-31 Giorgio Zicari , Barış Çakmak , Mauro Paternostro

In the present work, we study the entropy productions in a system controlled by double control parameters. By introducing a thermal fluctuation part, we solve the problem that the second law of the thermodynamics seems to be violated by the…

Statistical Mechanics · Physics 2015-08-21 Jang-il Sohn

Living systems maintain or increase local order by working against the Second Law of Thermodynamics. Thermodynamic consistency is restored as they dissipate heat, thereby increasing the net entropy of their environment. Recently introduced…

Biological Physics · Physics 2021-05-03 Dominic J. Skinner , Jörn Dunkel

The definition of nonequilibrium entropy is provided for the general nonequilibrium processes by connecting thermodynamics with statistical physics, and the principle of entropy increment in the nonequilibrium processes is also proved in…

Data Analysis, Statistics and Probability · Physics 2007-05-23 Xiaochun Mei

This paper presents an {\it ab initio} derivation of the expression given by irreversible thermodynamics for the rate of entropy production for different classes of diffusive processes. The first class are Lorentz gases, where…

Chaotic Dynamics · Physics 2009-11-07 J. R. Dorfman , P. Gaspard , T. Gilbert

The emerging field of stochastic thermodynamics extends classical ideas of entropy, heat and work to non-equilibrium systems. One notable finding is that the second law of thermodynamics typically only holds after taking appropriate…

Statistical Mechanics · Physics 2024-02-27 Paul C Bressloff

The work done when a system at thermal equilibrium is externally driven by a unitary control parameter leads to irreversible entropy production. The entropy produced can be thought of as a combination of coherence generation and a…

Quantum Physics · Physics 2024-12-30 Krishna Shende , Kavita Dorai , Arvind

We consider conservative quantum evolutions possibly interrupted by macroscopic measurements. When started in a nonequilibrium state, the resulting path-space measure is not time-reversal invariant and the weight of time-reversal breaking…

Statistical Mechanics · Physics 2007-05-23 I. Callens , W. De Roeck , T. Jacobs , C. Maes , K. Netocny

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

This is a short review of the statistical mechanical definition of entropy production for systems composed of a large number of interacting components. Emphasis is on open systems driven away from equilibrium where the entropy production…

Statistical Mechanics · Physics 2015-06-02 Christian Maes

The entropy shows an unavoidable tendency of disorder in thermostatistics according to the second thermodynamics law. This provides a minimization entropy principle for quantum thermostatistics with the von Neumann entropy and nonextensive…

Quantum Physics · Physics 2021-04-09 M. X. Luo , X. Wang

We study the multiple definitions of the entropy production for discrete-time Markov processes in single systems and composite systems. These definitions have been studied in single systems, but less so in composite systems. With a clear…

Statistical Mechanics · Physics 2025-05-30 Masanao Igarashi

Nonequilibrium phase transitions can be typified in a similar way to equilibrium systems, for instance, by the use of the order parameter. However, this characterization hides the irreversible character of the dynamics as well as its…

Statistical Mechanics · Physics 2019-07-10 C. E. Fernández Noa , Pedro E. Harunari , M. J. de Oliveira , C. E. Fiore

Bridging the second law of thermodynamics and microscopic reversible dynamics has been a longstanding problem in statistical physics. We here address this problem on the basis of quantum many-body physics, and discuss how the entropy…

Statistical Mechanics · Physics 2018-01-03 Kazuya Kaneko , Eiki Iyoda , Takahiro Sagawa

As remarked by Boltzmann, the Second Law of Thermodynamics is notable for the fact that it is readily proved using elementary statistical arguments, but becomes harder and harder to verify the more precise the microscopic description of a…

Quantum Physics · Physics 2026-04-03 Marco A. Jimenez-Valencia , Charles A. Stafford

Irreversible phenomena, such as the production of entropy and heat, arise from fundamental reversible dynamics because the forward dynamics is too complex, in the sense that it becomes impossible to provide the necessary information to keep…

General Physics · Physics 2014-04-30 Karl-Georg Schlesinger

The stochastic entropy generated during the evolution of a system interacting with an environment may be separated into three components, but only two of these have a non-negative mean. The third component of entropy production is…

Statistical Mechanics · Physics 2013-05-30 Ian J. Ford , Richard E. Spinney

We discuss entropy production in nonequilibrium steady states by focusing on paths obtained by sampling at regular (small) intervals, instead of sampling on each change of the system's state. This allows us to study directly entropy…

Statistical Mechanics · Physics 2011-09-07 Daniel ben-Avraham , Sven Dorosz , Michel Pleimling
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