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Due to their unique dimensionality, the physical properties of two-dimensional materials are deeply impacted by their surroundings, calling for a thorough understanding and control of these effects. We investigated the influence of the…

By employing x-ray photoelectron spectroscopy (XPS), we have been able to establish the occurrence of charge-transfer doping in few-layer graphene covered with electron acceptor (TCNE) and donor (TTF) molecules. We have performed…

Materials Science · Physics 2015-06-04 D. Choudhury , B. Das , D. D. Sarma , C. N. R. Rao

The unique properties of graphene offer immense opportunities for applications to many scientific fields, as well as societal needs, beyond our present imagination. One of the important features of graphene is the relatively simple…

Materials Science · Physics 2018-04-27 Otakar Frank , Mildred S. Dresselhaus , Martin Kalbac

Nitrogen-doped epitaxial graphene grown on SiC(000?1) was prepared by exposing the surface to an atomic nitrogen flux. Using Scanning Tunneling Microscopy (STM) and Spectroscopy (STS), supported by Density Functional Theory (DFT)…

Conjugated polymers can be reversibly doped by electrochemical means. This doping introduces new sub-bandgap optical absorption bands in the polymer while decreasing the bandgap absorption. To study this behavior, we have prepared an…

Materials Science · Physics 2015-05-27 J. Hwang , M. Nikolou , B. Ihas , R. Clark , M. Cornick , D. B. Tanner , I. Schwendeman , J. R. Reynolds

We investigate the atomic and electronic structures of cyclooctatetraene (COT) molecules on graphene and analyze their dependence on external gate voltage using first-principles calculations. The external gate voltage is simulated by adding…

Materials Science · Physics 2018-10-15 Sehoon Oh , Michael F. Crommie , Marvin L. Cohen

Ultrathin CrSBr flakes are exfoliated \emph{in situ} on Au(111) and Ag(111) and their electronic structure is studied by angle-resolved photoemission spectroscopy. The thin flakes' electronic properties are drastically different from those…

We demonstrate a flip-chip device for performing low-temperature acoustoelectric measurements on exfoliated two-dimensional materials. With this device, we study gate-tunable acoustoelectric transport in an exfoliated monolayer graphene…

Mesoscale and Nanoscale Physics · Physics 2018-11-22 J. R. Lane , L. Zhang , M. A. Khasawneh , B. N. Zhou , E. A. Henriksen , J. Pollanen

Graphene, a one-atom thick zero gap semiconductor [1, 2], has been attracting an increasing interest due to its remarkable physical properties ranging from an electron spectrum resembling relativistic dynamics [3-12] to ballistic transport…

Mesoscale and Nanoscale Physics · Physics 2011-11-09 T. O. Wehling , K. S. Novoselov , S. V. Morozov , E. E. Vdovin , M. I. Katsnelson , A. K. Geim , A. I. Lichtenstein

We analyse doping of graphene grown on SiC in two models which differ by the source of charge transfered to graphene, namely, from SiC surface and from bulk donors. For each of the two models, we find the maximum electron density induced in…

Materials Science · Physics 2010-09-20 Sergey Kopylov , Alexander Tzalenchuk , Sergey Kubatkin , Vladimir I. Fal'ko

We have demonstrated that the island nucleation in the initial stage of epitaxial thin film growth can be tuned by substrate surface charge doping. This charge effect was investigated using spin density functional theory calculation in…

Materials Science · Physics 2015-06-19 Wenmei Ming , Feng Liu

For centrosymmetric materials such as monolayer graphene, no optical second harmonic generation (SHG) is generally expected because it is forbidden under the electric-dipole approximation. Yet we observed a strong, doping induced SHG from…

Mesoscale and Nanoscale Physics · Physics 2019-02-12 Yu Zhang , Di Huang , Yuwei Shan , Tao Jiang , Zhihong Zhang , Kaihui Liu , Lei Shi , Jinluo Cheng , John E. Sipe , Wei-Tao Liu , Shiwei Wu

Effect of doping of graphene either by Boron (B), Nitrogen (N) or co-doped by B and N is studied using density functional theory. Our extensive band structure and density of states calculations indicate that upon doping by N (electron…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Sugata Mukherjee , T. P. Kaloni

Scattering dynamics influence the graphenes transport properties and inhibits the charge carrier deterministic behaviour. The intra or inter-band scattering mechanisms are vital for graphenes optical conductivity response under specific…

Mesoscale and Nanoscale Physics · Physics 2024-04-02 Palash Saha , Bala Murali Krishna Mariserla

Graphene devices require electric contacts with metals, particularly with gold. Scanning tunneling spectroscopy studies of electron local density of states performed on mono-, bi- and tri- graphene layer deposited on metallic conductive…

Materials Science · Physics 2009-01-05 Z. Klusek , P. Dabrowski , P. Kowalczyk , W. Kozlowski , P. Blake , M. Szybowicz , T. Runka , W. Olejniczak

Optical pump-terahertz probe differential transmission measurements of as-prepared single layer graphene (AG)(unintentionally hole doped with Fermi energy $E_F$ at $\sim$180 meV), nitrogen doping compensated graphene (NDG) with $E_F$…

Materials Science · Physics 2015-06-22 Srabani Kar , Dipti R. Mohapatra , Eric Freysz , A. K. Sood

By means of density functional theory (DFT) calculations we have quantitatively estimated the impact of the spontaneous polarization (SP) of the SiC(0001) substrate on the electronic properties of quasi-freestanding graphene (QFG) decoupled…

Materials Science · Physics 2015-01-27 J. Slawinska , H. Aramberri , J. I. Cerdà

We show that the work function of exfoliated single layer graphene can be modified by irradiation with swift (E_{kin}=92 MeV) heavy ions under glancing angles of incidence. Upon ion impact individual surface tracks are created in graphene…

Materials Science · Physics 2015-06-12 O. Ochedowski , B. Kleine Bussmann , B. Ban d'Etat , H. Lebius , M. Schleberger

The doping of lighter non-metals like boron and nitrogen into graphene represents a promising advancement in the field of nano-electronic devices, particularly in the development of field-effect transistors (FETs). These doped…

Materials Science · Physics 2023-08-16 Vivek Kumar Yadav

Solid mixed conductors with significant ionic as well as electronic conduction play a pivotal role for mass transfer and storage as required in battery electrodes. Single-phase materials with simultaneously high electronic and ionic…

Mesoscale and Nanoscale Physics · Physics 2017-09-11 M. Kühne , F. Paolucci , J. Popovic , P. M. Ostrovsky , J. Maier , J. H. Smet
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