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Currently, molecular tunnel junctions are recognized as important active elements of various nanodevices. This gives a strong motivation to study physical mechanisms controlling electron transport through molecules. Electron motion through…

Mesoscale and Nanoscale Physics · Physics 2013-01-24 Natalya A. Zimbovskaya

Several models of thermionic energy nanoconverters have been proposed to study the transport phenomena that take place in electronic devices. For example, in resonant tunneling junctions those phenomena are manifested through the…

Mesoscale and Nanoscale Physics · Physics 2020-06-02 G. Valencia-Ortega , L. A. Arias-Hernandez

We develop a theory of far from the equilibrium transport in arrays of tunnel junctions. We find that if the rate of the electron-electron interactions exceeds the rate of the electron-phonon energy exchange, the energy relaxation ensuring…

Mesoscale and Nanoscale Physics · Physics 2009-12-10 N. M. Chtchelkatchev , V. M. Vinokur , T. I. Baturina

In a current-carrying single-molecular junction (SMJ), a hierarchy of hybrid energy transport processes takes place under a highly nonequilibrium situation, including energy transfer from electrons to molecular vibrations via…

Mesoscale and Nanoscale Physics · Physics 2022-11-02 Gen Li , Bing-Zhong Hu , Wen-Hao Mao , Nuo Yang , Jing-Tao Lü

In this work we report the results of theoretical analysis of the effect of thermal environment on the thermoelectric efficiency of molecular junctions. The environment is represented by two thermal phonon baths associated with the…

Materials Science · Physics 2014-06-25 Natalya A. Zimbovskaya

In this work we theoretically study steady state thermoelectric transport through a single-molecule junction with a long chain-like bridge. Electron transmission through the system is computed using a tight-binding model for the bridge. We…

Mesoscale and Nanoscale Physics · Physics 2018-03-02 Natalya A. Zimbovskaya , Abraham Nitzan

Novel organic materials formed from functional molecules are attractive for various nanoelectronic applications because they are environmentally friendly, widely available and inexpensive. Recent advancement in bottom-up fabrication methods…

Mesoscale and Nanoscale Physics · Physics 2022-12-14 Abdalghani Daaoub , Renhang Wang , Ross Davidson , Sara Sangtarash , Hatef Sadeghi

Electron transport characteristics are investigated through some molecular chains attached to two non-superconducting electrodes by the use of Green's function method. Here we do parametric calculations based on the tight-binding…

Mesoscale and Nanoscale Physics · Physics 2009-07-31 Santanu K. Maiti

By using nonequilibrium Green's functions and the equation of motion method, we formulate a self-consistent field theory for the electron transport through a single molecular junction (SMJ) coupled with a vibrational mode. We show that the…

Mesoscale and Nanoscale Physics · Physics 2015-09-28 Guo-Hui Ding , Bing Dong

Electron transport properties through single conjugated molecules sandwiched between two non-superconducting electrodes are studied by the use of Green's function technique. Based on the tight-binding model, we do parametric calculations to…

Mesoscale and Nanoscale Physics · Physics 2009-11-06 Santanu K. Maiti

We study the model of a molecular switch comprised of a molecule with a soft vibrational degree of freedom coupled to metallic leads. In the presence of strong electron-ion interaction, different charge states of the molecule correspond to…

Mesoscale and Nanoscale Physics · Physics 2008-12-18 Fabio Pistolesi , Yaroslav M. Blanter , Ivar Martin

We consider the steady-state thermoelectric transport through a vibrating molecular quantum dot that is contacted to macroscopic leads. For moderate electron-phonon interaction strength and comparable electronic and phononic timescales, we…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 T. Koch , J. Loos , H. Fehske

We consider a molecular junction immersed in a solvent where the electron transfer is dominated by Marcus-type steps. However, the successive nature of the charge transfer through the junction does not imply that the solvent reach thermal…

Statistical Mechanics · Physics 2022-03-23 Henning Kirchberg , Abraham Nitzan

The linear thermoelectric properties of molecular junctions are theoretically studied close to room temperature within a model including electron-electron and electron-vibration interactions on the molecule. A nonequilibrium adiabatic…

Mesoscale and Nanoscale Physics · Physics 2015-11-26 C. A. Perroni , D. Ninno , V. Cataudella

We study the electrical conductance $G$ and the thermopower $S$ of single-molecule junctions, and reveal signatures of different transport mechanisms: off-resonant tunneling, on-resonant coherent (ballistic) motion, and multi-step hopping.…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Roman Korol , Michael Kilgour , Dvira Segal

We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the…

Mesoscale and Nanoscale Physics · Physics 2017-12-27 J. C. Klöckner , J. C. Cuevas , F. Pauly

Understanding how the mechanism of charge transport through molecular tunnel junctions depends on temperature is crucial to control electronic function in molecular electronic devices. With just a few systems investigated as a function of…

Mesoscale and Nanoscale Physics · Physics 2016-05-27 Alvar R. Garrigues , Lejia Wang , Enrique del Barco , Christian A. Nijhuis

We investigate transport properties of different realizations of one-dimensional quantum wires coupled to a number of external electrodes in terms of the full counting statistics. Focusing on the set-ups in which edge states of Majorana…

Mesoscale and Nanoscale Physics · Physics 2016-03-15 A. Komnik

Experimental studies on single-molecule junctions are typically in need of a simple theoretical approach that can reproduce or be fitted to experimentally measured transport data. In this context, the single-level variant of the Landauer…

Chemical Physics · Physics 2021-02-10 Jakub K. Sowa , Rudolph A. Marcus

Motivated by recent experiments [Lee et al. Nature 498, 209 (2013)], we present here a detailed theoretical analysis of the Joule heating in current-carrying single-molecule junctions. By combining the Landauer approach for quantum…