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Ionic liquids offer unique bulk and interfacial characteristics as battery electrolytes. Our continuum approach naturally describes the electrolyte on a macroscale. An integral formulation for the molecular repulsion,which can be…

Chemical Physics · Physics 2022-11-30 Max Schammer , Arnulf Latz , Birger Horstmann

Asymmetric valences in a binary electrolyte can significantly affect the performance of systems such as reverse electrodialysis cells, batteries, and supercapacitors. To generate a theoretical understanding of this effect, we consider a…

Chemical Physics · Physics 2026-05-05 Georgina C. Ryan , Mohit P. Dalwadi , Ian M. Griffiths

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

Materials Science · Physics 2020-05-05 Fan Wang , Ming Tang

Strong correlations are known to severely reduce the mobility of charge carriers near half-filling and thus have an important influence on the current carrying properties of grain boundaries in the high-$T_c$ cuprates. In this work we…

Superconductivity · Physics 2012-04-17 F. A. Wolf , S. Graser , F. Loder , T. Kopp

We develop a computational method for modeling electrostatic interactions of arbitrarily-shaped, polarizable objects on colloidal length scales, including colloids/nanoparticles, polymers, and surfactants, dispersed in explicit ion…

Soft Condensed Matter · Physics 2024-06-18 Emily Krucker-Velasquez , James W. Swan , Zachary Sherman

Electric fields and currents, which are used in innovative materials processing and electrochemical energy conversion, can often alter microstructures in unexpected ways. However, little is known about the underlying mechanisms. Using…

Materials Science · Physics 2021-05-12 Jiuyuan Nie , Chongze Hu , Qizhang Yan , Jian Luo

A multi-phase field model is employed to study the microstructural evolution of an alloy undergoing liquid dealloying. The model proposed extends upon the original approach of Geslin et al. to consider dealloying in the presence of grain…

Materials Science · Physics 2023-08-07 Nathan Bieberdorf , Mark D. Asta , Laurent Capolungo

Accurately measuring the cycle lifetime of commercial lithium-ion batteries is crucial for performance and technology development. We introduce a novel hybrid approach combining a physics-based equation with a self-attention model to…

Machine Learning · Computer Science 2025-05-07 Constantin-Daniel Nicolae , Sara Sameer , Nathan Sun , Karena Yan

Fast ionic conduction is a defining property of solid electrolytes for all-solid-state batteries. Previous studies have suggested that liquid-like cation motion associated with fast ionic transport can disrupt crystalline symmetry, thereby…

A number of experimental and theoretical findings in age hardening alloys suggest that specific solute elements preferentially segregate to and reduce the energy of the interphase boundary (IB). This segregation mechanism can stabilize the…

Materials Science · Physics 2019-10-29 Sourabh B Kadambi , Fadi Abdeljawad , Srikanth Patala

Solute segregation along grain boundaries (GBs) profoundly affects their thermodynamic and kinetic behaviors in polycrystalline materials. Recently, the spectral approach has emerged as a powerful tool to predict GB segregation. However,…

Materials Science · Physics 2025-05-27 Zuoyong Zhang , Chuang Deng

Solid state batteries have emerged as a potential next-generation energy storage device due to safety and energy density advantages. Development of electrolyte is one of the most important topics in solid state batteries. Electrochemical…

Materials Science · Physics 2021-10-04 Changyu Deng , Wei Lu

We propose a boundary element method for the accurate solution of the cell-by-cell bidomain model of electrophysiology. The cell-by-cell model, also called Extracellular-Membrane-Intracellular (EMI) model, is a system of reaction-diffusion…

Numerical Analysis · Mathematics 2024-06-28 Giacomo Rosilho de Souza , Rolf Krause , Simone Pezzuto

We present a novel phase-field approach for investigating solute segregation in a moving grain boundary. In our model, the correct choice of various parameters can control the solute-grain boundary interaction potential, resulting in…

Materials Science · Physics 2023-08-17 Sandip Guin , Miral Verma , Soumya Bandyopadhyay , Yu-Chieh Lo , Rajdip Mukherjee

Ionic fluids under conductive confinement are central to technologies such as batteries, supercapacitors, and fuel cells. Their interfacial behavior governs energy storage and electrochemical processes. Despite their importance, the…

Soft Condensed Matter · Physics 2025-12-02 Philipp Stärk , Alexander Schlaich

We derive a steady-state, electromagnetic solution for collisional plasma and apply it to computing the total conductance for a vertically stratified ionosphere interrogated by a 3D signal with finite transverse wavelength, which we compare…

Plasma Physics · Physics 2022-11-22 Russell B. Cosgrove

A model based on the continuous atomic density function (ADF) approach is applied to predict the atomic structure of grain boundaries (GBs) in iron. Symmetrical [100] and [110] tilt GBs in bcc iron are modeled with the ADF method and…

Materials Science · Physics 2014-02-05 O. Kapikranian , H. Zapolsky , Ch. Domain , R. Patte , C. Pareige , B. Radiguet , P. Pareige

In this paper we study a system of partial differential equations which models lithium-ion batteries. The system describes the conservation of Lithium and conservation of charges in the solid and electrolyte phases, together with the…

Analysis of PDEs · Mathematics 2022-02-08 Xiangsheng Xu

This paper proposes a new convex model predictive control strategy for dynamic optimal power flow between battery energy storage systems distributed in an AC microgrid. The proposed control strategy uses a new problem formulation, based on…

Systems and Control · Computer Science 2017-05-16 Thomas Morstyn , Branislav Hredzak , Ricardo P. Aguilera , Vassilios G. Agelidis

We develop an Over Barrier Model for computing charge exchange between ions and one-active-electron atoms at low impact energies. The main feature of the model is the treatment of the barrier crossing process by the electron within a…

Atomic Physics · Physics 2007-05-23 F. Sattin