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Wadsley-Roth crystal structures are an attractive class of materials for batteries because lithium diffusion is facilitated by the ReO3-like block structure with electron transport enabled by edge-sharing along shear planes. However, clear…

Topological constraints have long been known to provide efficient mechanisms for localizing and storing energy across a range of length scales, from knots in DNA to turbulent plasmas. Despite recent theoretical and experimental progress on…

Soft Condensed Matter · Physics 2020-11-11 Vishal P. Patil , Žiga Kos , Miha Ravnik , Jörn Dunkel

Numerical simulations are a powerful tool for the development and improvement of Li-ion batteries. Modeling the mass transport of the involved electrolytic solutions requires precise determination of the corresponding electrolyte…

Chemical Physics · Physics 2024-11-21 Lukas Lehnert , Maryam Nojabaee , Arnulf Latz , Birger Horstmann

The spinel-structured lithium manganese oxide (LiMn$_2$O$_4$) is a material currently used as cathode for secondary lithium-ion batteries, but whose properties are not yet fully understood. Here, we report a computational investigation of…

Materials Science · Physics 2018-03-14 David Santos-Carballal , Phuti E. Ngoepe , Nora H. de Leeuw

Liquid Metal Batteries (LMBs) are a promising concept for cheap electrical energy storage at grid level. These are built as a stable density stratification of three liquid layers, with two liquid metals separated by a molten salt. In order…

The diffusion coefficient of Li$^+$ ions ($D_{\rm Li}$) in the battery material Li$_x$CoO$_2$ has been investigated by muon-spin relaxation ($\mu^+$SR). Based on the experiments in zero-field and weak longitudinal-fields at temperatures up…

Materials Science · Physics 2016-08-14 Jun Sugiyama , Kazuhiko Mukai , Yutaka Ikedo , Hiroshi Nozaki , Martin Månsson , Isao Watanabe

We examine the evolution of Li in the Galactic disk,basing our model on the compilation of Li v.Fe observations in stars of iron abundance ranging between halo values,which give a baseline for the disk Li abundance,and 0.2 dex above…

Astrophysics · Physics 2007-05-23 E , Casuso , J. E. Beckman

Halide solid-state electrolytes have emerged as promising candidates for all-solid-state lithium batteries due to their high oxidative stability and deformability, yet their moderate ionic conductivity remains a bottleneck. While…

Materials Science · Physics 2026-02-02 Boyuan Xu , Chen Qian , Liyi Bai , Chenlu Wang , Feng Ding , Qisheng Wu

Lithium's susceptibility to burning in stellar interiors makes it an invaluable tracer for delineating the evolutionary pathways of stars, offering insights into the processes governing their development. Observationally, the complex Li…

Rate coefficients for inelastic collisions between Li and H atoms covering all transitions between the asymptotic states Li(2s,2p,3s,3p,3d,4s,4p,4d,4f)+H(1s) and Li^+ +H^- are presented for the temperature range 2000-8000 K based on recent…

Astrophysics · Physics 2009-11-10 P. S. Barklem , A. K. Belyaev , M. Asplund

Cubic spinel Li$_{\rm 1+x}$Ti$_2$O$_4$ is a promising electrode material as it exhibits a high lithium diffusivity and undergoes minimal changes in lattice parameters during lithiation and delithiation, thereby ensuring favorable…

Based on accurate X-ray structure analysis of GdB6 over the temperature range 85-300 K it has been shown that anomalously strong charge carrier scattering in the quantum diffusion regime of charge transport in this compound arises due to…

Ensuring solid-state lithium batteries perform well across a wide temperature range is crucial for their practical use. Molecular dynamics (MD) simulations can provide valuable insights into the temperature dependence of the battery…

Materials Science · Physics 2024-03-22 Zicun Li , Jianxing Huang , Xinguo Ren , Jinbin Li , Ruijuan Xiao , Hong Li

Using cryogenic transmission electron microscopy, we revealed three dimensional (3D) structural details of the electrochemically plated lithium (Li) flakes and their solid electrolyte interphase (SEI), including the composite SEI skin-layer…

Particle transport, acceleration and energisation are phenomena of major importance for both space and laboratory plasmas. Despite years of study, an accurate theoretical description of these effects is still lacking. Validating models with…

Using a computational crystal structure search in the Li-Fe-B ternary system, we predict a stable phase of Li3Fe8B8, featuring 1D channels that enable rapid Li-ion transport. Ab initio molecular dynamics simulations show that the Li-ion…

Here, using unique in-situ liquid secondary ion mass spectroscopy on isotope-labelled solid-electrolyte-interphase (SEI), assisted by cryogenic transmission electron microscopy and constrained ab initio molecular dynamics simulation, for…

We numerically investigate the dynamics of multiply charged hydrogenic ions in near-optical linearly polarized laser fields with intensities of order 10^16 to 10^17 W/cm^2. Depending on the charge state Z of the ion the relation of strength…

Quantum Physics · Physics 2009-11-06 S. X. Hu , C. H. Keitel

Solid-state electrolytes (SSEs) require ionic conductivities that are competitive with liquid electrolytes to realize applications in all-solid state batteries. Although numerous materials have been discovered, the underlying mechanisms…

The non-equilibrium relaxational properties of a three dimensional Coulomb glass model are investigated by kinetic Monte Carlo simulations. Our results suggest a transition from stationary to non-stationary dynamics at the equilibrium glass…

Disordered Systems and Neural Networks · Physics 2007-05-23 Alejandro B. Kolton , D. R. Grempel , Daniel Dominguez