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In some respects, a cluster consisting of many atoms may be regarded as a single large atom. Knowing the dielectric properties of such a cluster permits one to evaluate the form of the van der Waals (dispersion) interactions between two…

Soft Condensed Matter · Physics 2009-11-07 M. M. Calbi , S. M. Gatica , D. Velegol , M. W. Cole

Dispersion interactions are usually derived assuming fixed internal spectra of the interacting quantum systems. Here, we relax this assumption and study how self-consistent electromagnetic backaction modifies van der Waals interactions when…

Quantum Physics · Physics 2026-05-06 Johannes Fiedler

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

We obtained new nonrelativistic expression for the dynamical van der Waals atom -surface interaction energy of very convenient form for different applications. It is shown that classical result (Ferrell and Ritchie, 1980) holds only for a…

Other Condensed Matter · Physics 2011-08-10 G. V. Dedkov , A. A. Kyasov

van der Waals interactions govern the physics of a plethora of molecular structures. It is well known that the leading term in the distance-based London expansion of the van der Waals energy for atomic and molecular dimers decays as…

Chemical Physics · Physics 2017-11-22 Mireia Via-Nadal , Mauricio Rodríguez-Mayorga , Eduard Matito

Motivated by recent experiments on electric transport through single molecules and quantum dots, we investigate a model for transport that allows for significant coupling between the electrons and a boson mode isolated on the molecule or…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Urban Lundin , Ross H. McKenzie

We calculate the quantum heat generation, the interaction force and the frictional torque for two rotating spherical nanoparticles with a radius $R$. In contrast to the static case, when there is an upper limit in the radiative heat…

Quantum Physics · Physics 2017-08-09 A. I. Volokitin

The atomic dipole polarizability, $\alpha$, and the van der Waals (vdW) radius, $R_{\rm vdW}$, are two key quantities to describe vdW interactions between atoms in molecules and materials. Until now, they have been determined independently…

Chemical Physics · Physics 2018-11-07 Dmitry V. Fedorov , Mainak Sadhukhan , Martin Stöhr , Alexandre Tkatchenko

Ultracold polar molecules trapped on an optical lattice is a many-body system that, under appropriate conditions, may support collective excitations reminiscent of excitons in solid state crystals. Here, we discuss the rotational…

Atomic Physics · Physics 2017-08-23 Marina Litinskaya , Roman V. Krems

Rydberg atoms are used in a wide range of applications due to their peculiar properties like strong dipolar and van der Waals interactions. The choice of Rydberg state has a huge impact on the strength and angular dependence of the…

Atomic Physics · Physics 2025-11-04 Karen Wadenpfuhl , C. Stuart Adams

We investigate entanglement in a linear chain of $N$ polar molecules coupled by dipole interaction. In our model, nearest neighbour interaction predominate, and we compute entanglement with the help of a two-party correlation entanglement…

Quantum Physics · Physics 2008-10-01 Pérola Milman , Arne Keller

The recoil of atoms in dense ensembles during light matter interactions is studied using quantized vibrational states for the atomic motion. The recoil resulting from the forces due to the near-field collective dipole interactions and…

Quantum Physics · Physics 2025-03-24 Deepak A. Suresh , F. Robicheaux

We study the non-equilibrium many-body dynamics of a cold gas of ground state alkali atoms weakly admixed by Rydberg states with laser light. On a timescale shorter than the lifetime of the dressed states, effective dipole-dipole or van der…

Atomic Physics · Physics 2012-10-18 A. W. Glaetzle , R. Nath , B. Zhao , G. Pupillo , P. Zoller

We investigate theoretically the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited alkali-metal atom taking into account its fine-structure. The interaction involves the combination…

Chemical Physics · Physics 2017-09-13 Maxence Lepers , Olivier Dulieu

Interactions between objects can be classified as fundamental or emergent. Fundamental interactions are either extremely short-range or decay inversely with the separation distance, such as the Coulomb potential between charges or the…

Quantum Physics · Physics 2025-11-12 Loris Di Cairano , Matteo Gori , Reza Karimpour , Alexandre Tkatchenko

The onset of collision dynamics between an ion and a Rydberg atom is studied in a regime characterized by a multitude of collision channels. These channels arise from coupling between a non-polar Rydberg state and numerous highly polar…

Supersonic beams of polar molecules are deflected using inhomogeneous electric fields. The quantum-state selectivity of the deflection is used to spatially separate molecules according to their quantum state. A detailed analysis of the…

Isolated dielectric spheres support resonant electromagnetic modes which are analogous to electronic orbitals and, like their electronic counterparts, can form bonding or anti-bonding interactions between neighbouring spheres. By…

Soft Condensed Matter · Physics 2009-10-30 M. I. Antonoyiannakis , J. B. Pendry

We study polar molecule scattering in quasi-one-dimensional geometries. Elastic and reactive collision rates are computed as a function of collision energy and electric dipole moment for different confinement strengths. The numerical…

We describe a simple scheme for the implementation and control of effective spin-spin interactions in self-assembled crystals of cold polar molecules. In our scheme spin states are encoded in two long-lived rotational states of the…

Quantum Physics · Physics 2015-05-30 Y. L. Zhou , M. Ortner , P. Rabl
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