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Using fundamental-measure density functional theory we investigate entropic wetting in an asymmetric binary mixture of hard spheres with positive non-additivity. We consider a general planar hard wall, where preferential adsorption is…

Soft Condensed Matter · Physics 2015-05-28 Paul Hopkins , Matthias Schmidt

We develop a diffuse solid method that is versatile and accurate for modeling wetting and multiphase flows in highly complex geometries. In this scheme, we harness N + 1-component phase field models to investigate interface shapes and flow…

Selectivity of particles in a region of space can be achieved by applying external potentials to influence the particles in that region. We investigate static and dynamical properties of size selectivity in binary fluid mixtures of two…

Soft Condensed Matter · Physics 2010-01-18 Roland Roth , Markus Rauscher , Andrew J. Archer

We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A)…

Disordered Systems and Neural Networks · Physics 2009-11-11 S. K. Das , S. Puri Jawaharlal , J. Horbach , Kurt Binder

On the basis of a previous theoretical approach to the plastic flow of highly refined materials, a physical explanation for diffusion bonding is essayed, which yields closed--form equations relating the bonding progress with time,…

Materials Science · Physics 2010-07-02 Miguel Lagos , César Retamal

From hydrogels and plastics to liquid crystals, soft solids cover a wide array of synthetic and biological materials that play key enabling roles in advanced technologies such as 3D printing, soft robotics, wearable electronics,…

Soft Condensed Matter · Physics 2022-11-15 Surjyasish Mitra , Quoc Vo , Marcus Lin , Tuan Tran

When a solid plate is withdrawn from a partially wetting liquid, a liquid layer dewets the moving substrate. High-speed imaging reveals alternating thin and thick regions in the entrained layer in the transverse direction at steady state.…

Fluid Dynamics · Physics 2020-11-18 Mengfei He

Thermodynamic perturbation theory for central-force (TPT-CF) type of associating potential is used to study the phase behavior of symmetric binary mixture of associating particles with spherically symmetric interaction. The model is…

Soft Condensed Matter · Physics 2013-12-18 Yu. V. Kalyuzhnyi , T. V. Hvozd

We present a model based on the lattice Boltzmann equation that is suitable for the simulation of dynamic wetting. The model is capable of exhibiting fundamental interfacial phenomena such as weak adsorption of fluid on the solid substrate…

We study the equilibrium of a liquid film on an attractive spherical substrate for an intermolecular interaction model exhibiting both fluid-fluid and fluid-wall long-range forces. We first reexamine the wetting properties of the model in…

Statistical Mechanics · Physics 2013-10-04 Andreas Nold , Alexandr Malijevský , Serafim Kalliadasis

Multivalent particles have the ability to form multiple bonds to a substrate. Hence, a multivalent interaction can be strong, even if the individual bonds are weak. However, much more interestingly, multivalency greatly increases the…

Soft Condensed Matter · Physics 2017-04-04 Tine Curk , Jure Dobnikar , Daan Frenkel

We determine the solvent mediated contribution to the effective potentials for model colloidal or nano- particles dispersed in a binary solvent that exhibits fluid-fluid phase separation. Using a simple density functional theory we…

Soft Condensed Matter · Physics 2011-06-24 Paul Hopkins , Andrew J. Archer , Robert Evans

We use recent theoretical advances to develop a new functional form for interatomic forces in bulk silicon. The theoretical results underlying the model include a novel analysis of elastic properties for the diamond and graphitic structures…

Materials Science · Physics 2016-08-31 Martin Z. Bazant , Efthimios Kaxiras , J. F. Justo

The understanding of the spreading of liquids on solid surfaces is an important challenge for contemporary physics. Today, the motion of the contact line formed at the intersection of two immiscible fluids and a solid is still subject to…

Classical Physics · Physics 2009-11-13 Henri Gouin

Surface properties of mixtures of charged platelike colloids and salt in contact with a charged planar wall are studied within density functional theory. The particles are modeled by hard cuboids with their edges constrained to be parallel…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Ludger Harnau , S. Dietrich

We study the global influence of curvature on the free energy landscape of two-dimensional binary mixtures confined on closed surfaces. Starting from a generic effective free energy, constructed on the basis of symmetry considerations and…

Soft Condensed Matter · Physics 2019-09-11 Piermarco Fonda , Melissa Rinaldin , Daniela J. Kraft , Luca Giomi

We present a systematic study of capillary filling for a binary fluid by using a mesoscopic lattice Boltzmann model for immiscible fluids describing a diffusive interface moving at a given contact angle with respect to the walls. The…

Fluid Dynamics · Physics 2009-11-13 S. Chibbaro

We study the dependence of the surface tension of a fluid interface on the density profile of a third suspended phase. By means of an approximated model for the binary mixture and of a perturbative approach we derive close formulas for the…

Statistical Mechanics · Physics 2021-02-03 Alessio Squarcini , Paolo Malgaretti

The wetting properties of solid substrates with customary (i.e., macroscopic) random roughness are considered as a function of the microscopic contact angle of the wetting liquid and its partial pressure in the surrounding gas phase.…

Soft Condensed Matter · Physics 2015-03-19 S. Herminghaus

We investigated the behavior of H$_2$, main constituent of the gas phase in dense clouds, after collision with amorphous solid water (ASW) surfaces, one of the most abundant chemical species of interstellar ices. We developed a general…

Chemical Physics · Physics 2020-03-20 G. Molpeceres , J. Kästner