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Halide perovskites have emerged as promising materials for next-generation photovoltaics, laser sources and X-ray detectors. There is intense debate as to whether some photoactive halide perovskites exhibit ferroelectric behaviour and…

Materials Science · Physics 2026-01-21 Weilun Li , Qimu Yuan , Michael B. Johnston , Joanne Etheridge

The power conversion efficiency of photovoltaic devices based on semiconductor perovskites has reached ~20% after just several years of research efforts. With concomitant discoveries of other promising applications in lasers, light-emitting…

The application of ferroelectric materials (i.e. solids that exhibit spontaneous electric polarisation) in solar cells has a long and controversial history. This includes the first observations of the anomalous photovoltaic effect (APE) and…

Materials Science · Physics 2015-03-06 Keith T. Butler , Jarvist M. Frost , Aron Walsh

Excellent conversion efficiencies of over 20 % and facile cell production have placed hybrid perovskites at the forefront of novel solar cell materials with CH3NH3PbI3 being its archetypal compound. The question why CH3NH3PbI3 has such…

Materials Science · Physics 2019-07-16 Joachim Breternitz , Frederike Lehmann , Sarah A. Barnett , Harriott Nowell , Susan Schorr

The performance of organometallic perovskite solar cells has rapidly surpassed that of both conventional dye-sensitised and organic photovoltaics. High power conversion efficiency can be realised in both mesoporous and thin-film device…

Halide perovskite semiconductors respond to electric fields in a way that varies across time and length scales. We discuss the microscopic processes that give rise to the macroscopic polarization of these materials, ranging from the optical…

Materials Science · Physics 2018-12-04 Jacob N. Wilson , Jarvist M. Frost , Suzanne K. Wallace , Aron Walsh

Lead halide perovskites have emerged as promising materials for optoelectronic applications due to their exceptional properties. In the all-inorganic CsPbBr3 perovskites, ferroelastic domains formed during phase transitions enhance bulk…

The development of next generation perovskite-based optoelectronic devices relies critically on the understanding of the interaction between charge carriers and the polar lattice in out-of-equilibrium conditions. While it has become…

Ferroelectric photovoltaic materials are an alternative to semiconductor-based photovoltaics and offer the advantage of above bandgap photovoltage generation. However, there are few known compounds, and photovoltaic efficiencies remain low.…

Materials Science · Physics 2018-01-31 A. S. Makhort , F. Chevrier , D. Kundys , B. Doudin , B. Kundys

Despite their puzzling vibrational characteristics that include strong signatures of anharmonicity and thermal disorder already around room temperature, halide perovskites exhibit favorable optoelectronic properties for applications in…

Materials Science · Physics 2022-02-08 Christian Gehrmann , Sebastián Caicedo-Dávila , Xiangzhou Zhu , David A. Egger

Excitonic/electronic coupling and cooperative interactions in self-assembled lead halide perovskite nanocrystals were reported to give rise to a collective low energy emission peak with accelerated dynamics. Here we report that similar…

Halide perovskite (HaP) semiconductors are revolutionizing photovoltaic (PV) solar energy conversion by showing remarkable performance of solar cells made with esp. tetragonal methylammonium lead tri-iodide (MAPbI3). In particular, the low…

Bulk photovoltaic effect in noncentrosymmetric materials is a fundamental and significant property that holds potential for high-efficiency energy harvesting, such as photoelectric application and photocatalysis. Here, based on first…

Materials Science · Physics 2024-05-14 Keyu An , Zhuang Qian , Haoqiang Ai , Zhichao Yu , Shuangpeng Wang , Hui Pan

Organometallic lead halide perovskites are highly efficient materials for solar cells and other optoelectronic applications due to their high quantum efficiency and exceptional semiconducting properties. A peculiarity of these perovskites…

In recent years, halide perovskite-based solar cells have received intensive attention, and demonstrated power conversion efficiency as high as 25.8%. With regard to the toxicity of Pb and the instability of organic elements, all inorganic…

Materials Science · Physics 2022-05-04 Dibyajyoti Saikia , Mahfooz Alam , Jayanta Bera , Atanu Betal , Appala Naidu Gandhi , Satyajit Sahu

Lead halide perovskites possess high photoluminescence (PL) efficiency and strong electron-phonon interactions, and therefore the optical cooling using up-conversion PL has been expected. We investigate anti-Stokes PL from green-luminescent…

The transition to smart wearable and flexible optoelectronic devices communicating with each other and performing neuromorphic computing at the edge is a big goal in next-generation optoelectronics. These devices should perform their…

Metal halide perovskites are promising materials for optoelectronic applications owing to their outstanding optical and electronic properties. Among them, all-inorganic perovskites such as CsPbBr$_3$ offer superior thermal and chemical…

Organic-inorganic halide perovskites recently have emerged as a promising material for highly effective light-emitting diodes (LEDs) and solar cells (SCs). Despite efficiencies of both perovskite SCs and LEDs are already among the best, the…

Integration of high-quality photon emitters at specific locations within nanophotonic structures or optoelectronic devices is a key to innovating on-chip optical control and quantum technologies. Halide perovskite nanoparticles have great…

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