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So far transport properties of nanoscale contacts have been mostly studied within the static scattering approach. The electron dynamics and the transient behavior of current flow, however, remain poorly understood. We present a numerical…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Na Sai , Neil Bushong , Ryan Hatcher , Massimiliano Di Ventra

The nanoscopic mass and charge distribution within the double layer at electrified interfaces plays a key role in electrochemical phenomena of huge technological relevance for energy production and conversion. However, in spite of its…

Chemical Physics · Physics 2019-05-29 Remi Khatib , Ashwinee Kumar , Stefano Sanvito , Marialore Sulpizi , Clotilde S. Cucinotta

Molecular self-assembly, the function of biomembranes, and the performance of organic solar cells rely on molecular interactions on the nanoscale. The understanding and design of such intrinsic or engineered heterogeneous functional soft…

Chemical Physics · Physics 2013-12-30 Benjamin Pollard , Eric A. Muller , Karsten Hinrichs , Markus B. Raschke

High electric fields can significantly alter catalytic environments and the resultant chemical processes. Such fields arise naturally in biological systems but can also be artificially induced through localized excitations at nanoscale.…

Explicit molecular dynamics simulations were applied to a pair of amorphous silica nanoparticles in aqueous solution, of diameter 4.4 nm with four different background electrolyte concentrations, to extract the mean force acting between the…

Chemical Physics · Physics 2009-11-13 S. Jenkins , S. R. Kirk , M. Persson , J. Carlen , Z. Abbas

The rheology of nanoparticle suspensions for nanoparticles of various shapes with equal mass is studied using molecular dynamics simulations. The equilibrium structure and the response to imposed shear are analyzed for suspensions of…

Soft Condensed Matter · Physics 2015-05-18 David R. Heine , Matt K. Petersen , Gary S. Grest

Nitrogen-vacancy (NV) based quantum sensors hold great potential for real-time single-cell sensing with far-reaching applications in fundamental biology and medical diagnostics. Although highly sensitive, the mapping of quantum measurements…

Semiconductor surfaces were divided into charge categories, i.e. surface acceptor, donor and neutral ones that are suitable for simulations of their properties within a slab model. The potential profiles, close to the charged surface…

Materials Science · Physics 2016-11-09 Stanisław Krukowski , Paweł Kempisty , Paweł Strąk

While fluids near a solid surface are at the core of applications in energy storage/conversion, electrochemistry/electrowetting and adsorption/catalysis, their nanoscale behavior remains only partially deciphered. Beyond conventional…

Soft Condensed Matter · Physics 2026-01-07 Cecilia Herrero , Lyderic Bocquet , Benoit Coasne

Metal surfaces with disorder or with nanostructure modifications are studied, allowing for a localized charge layer (CL) in addition to continuous charges (CC) in the bulk, both charges having a compressional or diffusive non-local…

Mesoscale and Nanoscale Physics · Physics 2012-07-02 Baruch Horovitz , Carsten Henkel

The drying of colloidal suspensions leads to complex deposition patterns, accompanied by instabilities such as cracking and delamination. In this study, we experimentally investigate the coupled influence of particle surface charge and…

Soft Condensed Matter · Physics 2026-01-27 A. Madhav Sai Kumar , A. Hari Govindha , Ranajit Mondal , Kirti Chandra Sahu

While important for many industrial applications, chemical reactions responsible for charging of solids in water are often poorly understood. We theoretically investigate the charging kinetics of solid-liquid interfaces, and find that the…

Soft Condensed Matter · Physics 2023-02-08 Willem Boon , Marjolein Dijkstra , René van Roij

When solid surfaces are immersed in aqueous solutions, some of their charges can dissociate and leave behind charge patches on the surface. Although the charges are distributed heterogeneously on the surface, most of the theoretical models…

Soft Condensed Matter · Physics 2013-11-19 Dan Ben-Yaakov , David Andelman , Haim Diamant

Surface energy is a fundamental property of materials and is particularly important in describing nanomaterials where atoms or molecules at the surface constitute a large fraction of the material. Traditionally, surface energy is considered…

Mesoscale and Nanoscale Physics · Physics 2024-04-24 Jason J. Calvin , Amanda S. Brewer , Michelle F. Crook , Tierni M. Kaufman , A. Paul Alivisatos

Nanoscale phase-control is one of the most powerful approaches to specifically tailor electrical fields in modern nanophotonics. Especially the precise sub-wavelength assembly of many individual nano-building-blocks has given rise to…

Optics · Physics 2021-05-26 Lisa Saemisch , Niek F. van Hulst , Matz Liebel

Cellular uptake of nanoplastics is instrumental in their environmental accumulation and transfer to humans through the food chain. Despite extensive studies using spherical plastic nanoparticles, the influence of the morphological…

Soft Condensed Matter · Physics 2023-08-29 Xin Yong , Ke Du

We study charged nanoparticles adsorbed onto surfactant bilayers using small-angle scattering of synchrotron radiation. The in-plane interaction of the particles is well described by a DLVO component (measured independently in solution) and…

We develop and verify a phase-sensitive second harmonic generation spectroscopic scheme that allows for direct determination of the absolute surface charge density and surface potential of a water interface without need of prior interfacial…

Chemical Physics · Physics 2019-08-27 Laetitia Dalstein , Kuo-Yang Chiang , Yu-Chieh Wen

We perform molecular dynamics simulations to understand the translational and rotational diffusion of Janus nanoparticles at the interface between two immiscible fluids. Considering spherical particles with different affinity to fluid…

Fluid Dynamics · Physics 2016-05-04 Hossein Rezvantalab , German Drazer , Shahab Shojaei-Zadeh

The surface charge of a water interface determines many fundamental processes in physical chemistry and interface science, and it has been intensively studied for over a hundred years. We summarize experimental methods to characterize the…

Chemical Physics · Physics 2021-09-23 Yuki Uematsu