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Surface charge controls many static and dynamic properties of soft matter and micro/nanofluidic systems, but its unambiguous measurement forms a challenge. Standard characterization methods typically probe an effective surface charge, which…

Soft Condensed Matter · Physics 2018-08-28 Remco Hartkamp , Anne-Laure Biance , Li Fu , Jean-François Dufrêche , Oriane Bonhomme , Laurent Joly

Two main approaches in particle-based simulations for modeling a charged surface are using explicit, discrete charges and continuum, uniform charges. It is well-known that these two approaches could lead to substantially distinct ionic…

Soft Condensed Matter · Physics 2022-08-02 Jiaxing Yuan , Yanwei Wang

In order to detect the effect of the surface charge discreteness on the properties at the solid-liquid interface, molecular dynamics simulation model taking consideration of the vibration of wall atoms was used to investigate the ion and…

Chemical Physics · Physics 2016-12-20 Yinghua Qiu , Yunfei Chen

The interaction of mass-selected atomic clusters and nanoparticles with surfaces attracts strong interest in view of fundamental research and technological applications. Understanding dynamics of the deposition process is important for…

Atomic and Molecular Clusters · Physics 2021-07-12 Yannick Fortouna , Pablo de Vera , Alexey Verkhovtsev , Andrey V. Solov'yov

Nanoparticles in solution acquire charge through dissociation or association of surface groups. Thus, a proper description of their electrostatic interactions requires the use of charge-regulating boundary conditions rather than the…

Soft Condensed Matter · Physics 2021-04-07 Tine Curk , Erik Luijten

Thermo-osmosis refers to fluid migration due to temperature gradient. The mechanistic understanding of thermo-osmosis in charged nano-porous media is still incomplete, while it is important for several environmental and energy applications,…

Chemical Physics · Physics 2023-07-14 Wei Qiang Chen , Andrey P Jivkov , Majid Sedighi

Surface charging is a phenomenon ubiquitously observable in in-situ transmission electron microscopy of non-conducting specimens as a result of electron beam/sample interactions or optical stimuli and often limits the achievable image…

Mesoscale and Nanoscale Physics · Physics 2024-08-27 Jonathan T. Weber , Sascha Schäfer

Nanofluidic systems show great promises for applications in energy conversion, where their performance can be enhanced by nanoscale liquid-solid slip. However, efficiency is also controlled by surface charge, which is known to reduce slip.…

Soft Condensed Matter · Physics 2020-06-30 Yanbo Xie , Li Fu , Thomas Niehaus , Laurent Joly

The charge state of dielectric surfaces in aqueous environments is of fundamental and technological importance. Here, we study the influence of dissolved molecular CO$_2$ on the charging of three, chemically different surfaces (SiO$_2$,…

Triboelectric charging strongly affects the operation cycle and handling of materials and can be used to harvest mechanical energy through triboelectric nanogenerator set-up. Despite ubiquity of triboelectric effects, a lot of mechanisms…

Large-scale molecular dynamics simulations are used to simulate a layer of nanoparticles diffusing on the surface of a liquid. Both a low viscosity liquid, represented by Lennard-Jones monomers, and a high viscosity liquid, represented by…

Soft Condensed Matter · Physics 2013-01-10 Shengfeng Cheng , Gary S. Grest

By performing spectroscopic single-particle measurements at cryogenic temperatures over the course of hours we study %By performing spectroscopic longtime single-particle measurements at cryogenic temperatures we study both the spectral…

Mesoscale and Nanoscale Physics · Physics 2017-11-13 Sven-Hendrik Lohmann , Christian Strelow , Alf Mews , Tobias Kipp

Although significant insights have been obtained into chemical and physical properties that govern to the performance of catalysts in traditional thermal processes, the work on electro-, photo-, or plasma-catalytic approaches has been…

Chemical Physics · Physics 2021-04-20 Kristof M. Bal , Stijn Huygh , Erik C. Neyts

We present a general formalism of ultrafast diffractive voltammetry approach as a contact-free tool to investigate the ultrafast surface charge dynamics in nanostructured interfaces. As case studies, the photoinduced surface charging…

Chemical Physics · Physics 2015-06-17 Kiseok Chang , Ryan A. Murdick , Zhensheng Tao , Tzong-Ru T. Han , Chong-Yu Ruan

Understanding the dynamics of charge exchange between a solid surface and a liquid is fundamental to various situations, ranging from nanofiltration to catalysis and electrochemistry. Charge transfer is ultimately determined by…

Comprehensive characterization of nanomaterials for medical applications is a challenging and complex task due to the multitude of parameters which need to be taken into consideration in a broad range of conditions. Routine methods such as…

Acquiring quantitative information on charge transfer (CT) dynamics at the nanoscale remains an important scientific challenge. In particular, CT processes in single molecules at surfaces needs to be investigated to be properly controlled…

Mesoscale and Nanoscale Physics · Physics 2017-06-20 Hatem Labidi , Henry Pinto , Jerzy Leszczynski , Damien Riedel

In this paper, we explore the effect of a finite surface charge mobility on the interfacial transport: conductance, streaming currents, electro- and diffusio-osmotic flows. We first show that the surface charge mobility modifies the…

Soft Condensed Matter · Physics 2019-02-04 Timothée Mouterde , Lydéric Bocquet

Surface stresses, in nano-sized anode particles undergoing chemomechanical interactions, have a relaxing effect on the diffusion-induced stresses thus improving the mechanical endurance of the particles, whereas, the compressive effect of…

Soft Condensed Matter · Physics 2021-02-23 Amrita Sengupta , Jeevanjyoti Chakraborty

The sliding motion of aqueous droplets on hydrohobic surfaces leads to charge separation at the trailing edge, with implications from triple-line friction to hydrovoltaic energy generation. Charges deposited on the solid surface have been…

Soft Condensed Matter · Physics 2025-09-12 Zouhir Benrahla , Tristan Saide , Louis Burnaz , Emilie Verneuil , Simon Gravelle , Jean Comtet
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