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Disorder enhances desired properties, as well as creating new avenues for synthesizing materials. For instance, hardness and yield stress are improved by solid-solution strengthening, a result of distortions and atomic size mismatches.…

Over the past decade, the field of high-entropy ceramics (HECs) has expanded rapidly to encompass a broad range of oxides, borides, silicides, and other ceramic solid solutions. In 2020, we proposed extending HECs to compositionally complex…

Materials Science · Physics 2026-01-21 Jian Luo

High-entropy alloys, which exist in the high-dimensional composition space, provide enormous unique opportunities for realizing unprecedented structural and functional properties. A fundamental challenge, however, lies in how to predict the…

Materials Science · Physics 2021-05-20 Jie Qi , Andrew M. Cheung , S. Joseph Poon

High-entropy alloys and ceramics containing at least five principal elements have recently received high attention for various mechanical and functional applications. The application of severe plastic deformation (SPD), particularly the…

Materials Science · Physics 2023-09-19 Parisa Edalati , Masayoshi Fuji , Kaveh Edalati

High entropy materials, which include high entropy alloys, carbides, and borides, are a topic of substantial research interest due to the possibility of a large number of new material compositions that could fill gaps in application needs.…

Materials Science · Physics 2020-07-16 Lavina Backman , Joshua Gild , Jian Luo , Elizabeth J. Opila

High-entropy materials have attracted considerable interest due to the combination of useful properties and promising applications. Predicting their formation remains the major hindrance to the discovery of new systems. Here we propose a…

By breaking the restrictions on traditional alloying strategy, the high entropy concept has promoted the exploration of the central area of phase space, thus broadening the horizon of alloy exploitation. This review highlights the marriage…

Materials Science · Physics 2022-08-30 Tianping Ying , Tongxu Yu , Yanpeng Qi , Xiaolong Chen , Hideo Hosono

In the quest of new materials that can withstand severe irradiation and mechanical extremes for advanced applications (e.g. fission reactors, fusion devices, space applications, etc), design, prediction and control of advanced materials…

Traditionally, increasing compositional complexity and chemical diversity of high entropy alloy ceramics whilst maintaining a stable single-phase solid solution has been a primary design strategy for the development of new ceramics.…

Materials Science · Physics 2024-03-19 O. V. Pshyk , A. Vasylenko , P. Kuttel , B. Wicher , P. Schweizer , J. Michler , T. E. J. Edwards

High entropy oxides are emerging as an exciting new avenue to design highly tailored functional behaviors that have no traditional counterparts. Study and application of these materials are bringing together scientists and engineers from…

High-entropy materials often outperform their lower-entropy relatives in various aspects, such as thermal stability and fracture toughness. While there are extensive research activities in the field of high-entropy alloys, comparably little…

Materials Science · Physics 2018-03-01 Paul H. Mayrhofer , Alexander Kirnbauer , Philipp Ertelthaler , Christian M. Koller

High strength and high toughness are usually mutually exclusive in engineering materials. Improving the toughness of strong but brittle materials like ceramics thus relies on the introduction of a metallic or polymeric ductile phase to…

Ceramics are easy to break, and very few generic mechanisms are available for improving their mechanical properties, e.g., the 1975-discovered anti-fracture mechanism is strictly limited to zirconia and hafnia. Here we report a general…

Materials Science · Physics 2021-02-02 Haidong Bian , Quanfeng He , Junhua Luan , Yu Bu , Yong Yang , Zhengtao Xu , Jian Lu , Yang Yang Li

The practically unlimited high-dimensional composition space of high-entropy materials (HEMs) has emerged as an exciting platform for functional materials design and discovery. However, the identification of stable and synthesizable HEMs…

Materials Science · Physics 2024-03-01 Dibyendu Dey , Liangbo Liang , Liping Yu

A comprehensive literature review on recently rediscovered Co- and/or CoNi-based superalloys, strengthened by the {\gamma}' phase, revealed a relationship between the configurational entropy of the system and the {\gamma}' solvus…

Ceramics are typically brittle at ambient conditions due to their covalent or ionic bonding and limited dislocation activities. While plasticity, and occasionally superplasticity, can be achieved in ceramics at high temperatures through…

High-entropy alloys are characterized by high configurational entropy. Since the discovery of high-entropy alloys (HEA) in 2004, entropy engineering has provided a promising direction for exploiting composition, lattice disorder, band…

Materials Science · Physics 2019-11-12 S. Joseph Poon , Jian He

High-entropy ceramics (HECs) have quickly gained attention since 2015. To date, nearly all work has focused on five-component, equimolar compositions. This perspective article briefly reviews different families of HECs and selected…

Materials Science · Physics 2020-03-24 Andrew J. Wright , Jian Luo

It has been shown that oxide ceramics containing multiple transition and/or rare-earth elements in equimolar ratios have a strong tendency to crystallize in simple single phase structures, stabilized by the high configurational entropy. In…

Materials Science · Physics 2019-03-27 Ralf Witte , Abhishek Sarkar , Robert Kruk , Benedikt Eggert , Richard A. Brand , Heiko Wende , Horst Hahn

Layered, hexagonal crystal structures, like zeta and eta phases, play an important role in ultra-high temperature ceramics, often significantly increasing toughness of carbide composites. Despite their importance open questions remain about…

Materials Science · Physics 2025-08-27 Kat Nykiel , Brian Wyatt , Babak Anasori , Alejandro Strachan
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