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We investigate the statistical mechanics of an inhomogeneous Coulomb fluid composed of charged particles with static polarizability. We derive the weak- and the strong-coupling approximations and evaluate the partition function in a planar…

Soft Condensed Matter · Physics 2013-04-22 Vincent Démery , David S. Dean , Rudolf Podgornik

To reduce the impact of charging effects on satellites, cheap and lightweight conductive coatings are desirable. We mimic space-like charging environments in ultra-high vacuum (UHV) chambers during deposition of charges via the electron…

Mesoscale and Nanoscale Physics · Physics 2023-09-06 M. Wendt , R. Lange , F. Dorn , J. Berdermann , I. Barke , S. Speller

Electric double layers (EDL) with counterions only, say electrons with the elementary charge $-e$, in thermal equilibrium at the inverse temperature $\beta$ are considered. In particular, we study the effect of the surface charge modulation…

Statistical Mechanics · Physics 2022-07-26 Ladislav Šamaj

Ionic liquids have attracted a lot of research attention for their applications in novel optoelectronic structures and devices as an optical means of regulating electricity. Although the electro-optic effect of ionic liquids is mentioned in…

Optics · Physics 2019-02-20 Ji Zhou , Shikui Dong , Zhihong He , Julius Caesar Puoza , Yanhu Zhang

We propose a detailed description of the structure of the layer formed by polyelectrolyte chains adsorbed onto an oppositely charged surface in the semi-dilute regime. We combine the mean-field Poisson-Boltzmann-Edwards theory and the…

Soft Condensed Matter · Physics 2019-02-20 Manoel Manghi , Miguel Aubouy

Electric fields arising from the distribution of charge in metal halide perovskite solar cells are critical for understanding the many weird and wonderful optoelectronic properties displayed by these devices. Mobile ionic defects are…

In this study, we examine thermal conductivity and the thermal Hall effect in electron-ion plasmas relevant to hot neutron stars, white dwarfs, and binary neutron star mergers, focusing on densities found in the outer crusts of neutron…

High Energy Astrophysical Phenomena · Physics 2024-11-18 Arus Harutyunyan , Armen Sedrakian

We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…

Soft Condensed Matter · Physics 2016-10-05 Sidney J. de Carvalho , Ralf Metzler , Andrey G. Cherstvy

This chapter deals with charged polymers (polyelectrolytes) in solution and at surfaces. The behavior of polyelectrolytes is markedly different from that of neutral polymers. In bulk solutions, i.e. disregarding the surface effect, there…

Soft Condensed Matter · Physics 2009-09-25 Roland R. Netz , David Andelman

The photo-induced desorption and oxidation of CO on Ru(0001) is simulated using ab initio molecular dynamics with electronic friction that accounts for the non-equilibrated excited electrons and phonons. Different (O,CO) coverages are…

Materials Science · Physics 2023-07-06 Auguste Tetenoire , J. Iñaki Juaristi , Maite Alducin

Electrosprays are a powerful technique to generate charged micro/nanodroplets. In the last century, the technique received extensive study and successful applications, including a Nobel price in Chemistry. However, nowadays its use in…

Fluid Dynamics · Physics 2012-08-07 Alvaro G. Marin , Ignacio G. Loscertales , Antonio Barrero

An ultra-strong photovoltaic effect has recently been reported for electrons trapped on a liquid Helium surface under a microwave excitation tuned at intersubband resonance [D. Konstantinov et. al. : J. Phys. Soc. Jpn. 81, 093601 (2012) ].…

Mesoscale and Nanoscale Physics · Physics 2013-07-24 F. Closa , E. Raphael , A. D. Chepelianskii

A cryogenic apparatus is described that enables a new experiment, nEDM@SNS, with a major improvement in sensitivity compared to the existing limit in the search for a neutron Electric Dipole Moment (EDM). It uses superfluid $^4$He to…

Intense electrostatic fields, such as those able to break bonds and cause field-ion emission, can fundamentally alter the behaviour of atoms at and on the surface. Using density functional theory (DFT) calculations on the Li (110) surface…

Materials Science · Physics 2025-02-11 Shyam Katnagallu , Huan Zhao , Se-Ho Kim , Baptiste Gault , Christoph Freysoldt , Jörg Neugebauer

We consider the interactions between two uncharged planar macroscopic surfaces immersed in an electrolyte solution which are induced by interfacial selectivity. These forces are taken into account by introducing a depletion free-energy…

Soft Condensed Matter · Physics 2009-10-31 M. N. Tamashiro , P. Pincus

We generalize the predictions for attractions between over-all neutral surfaces induced by charge fluctuations/correlations to non-uniform systems that include dielectric discontinuities, as is the case for mixed charged lipid membranes in…

Soft Condensed Matter · Physics 2009-10-31 Rebecca Menes , Philip Pincus , Bean Stein

Liquid adsorption in nanoporous materials induces their deformation due to strong capillary forces. The linear relationship between the liquid pressure and the solid strain (pore-load modulus) provides an experimental technique to determine…

Soft Condensed Matter · Physics 2017-10-31 J. Puibasset

Counterion distribution around an isolated flexible polyelectrolyte in the presence of a divalent salt is evaluated using the adsorption model [M. Muthukumar, J. Chem. Phys. {\bf 120}, 9343 (2004)] that considers Bjerrum length, salt…

Soft Condensed Matter · Physics 2008-12-29 Arindam Kundagrami , M. Muthukumar

We study phonon-mediated adsorption and desorption of an electron at dielectric surfaces with deep polarization-induced surface potentials where multi-phonon transitions are responsible for electron energy relaxation. Focusing on…

Other Condensed Matter · Physics 2015-05-27 R. L. Heinisch , F. X. Bronold , H. Fehske

We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov
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