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Polymer electrolytes are intensely investigated for use as solid electrolytes in next generation lithium-ion and lithium-metal batteries. However, little is known about the structural and dynamical properties of polymer electrolytes close…

Soft Condensed Matter · Physics 2021-12-02 Andreas Thum , Diddo Diddens , Andreas Heuer

We investigate the behaviour of electric fields originating from adsorbates deposited on a cryogenic atom chip as it is cooled from room temperature to cryogenic temperature. Using Rydberg electromagnetically induced transparency we measure…

Atomic Physics · Physics 2014-01-17 K. S. Chan , M. Siercke , C. Hufnagel , R. Dumke

The electric fields near the heterogeneous metal/dielectric surface of an atom chip were measured using cold atoms. The atomic sensitivity to electric fields was enhanced by exciting the atoms to Rydberg states that are 10^8 times more…

Atomic Physics · Physics 2012-11-02 J. D. Carter , O. Cherry , J. D. D. Martin

We study the impact of an unshielded dielectric $\unicode{x2013}$ here, a bare optical fiber $\unicode{x2013}$ on a $^{40}$Ca${^+}$ ion held several hundred $\mu$m away in a cryogenic surface electrode trap. We observe distance-dependent…

Atomic Physics · Physics 2026-03-11 M. Bruff , L. Sonderhouse , K. N. David , J. Stuart , D. H. Slichter , D. Leibfried

We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…

Soft Condensed Matter · Physics 2018-05-23 Derek Frydel , Rudolf Podgornik

Computer simulations are used to investigate the response of a charged colloid and its surrounding microion cloud to an external electric field. Both static fields (DC) and alternating fields (AC) are considered. A mesoscopic simulation…

Soft Condensed Matter · Physics 2013-07-19 Jiajia Zhou , Roman Schmitz , Burkard Duenweg , Friederike Schmid

Mean-field theory and scaling arguments are presented to model polyelectrolyte adsorption from semi-dilute solutions onto charged surfaces. Using numerical solutions of the mean-field equations, we show that adsorption exists only for…

Soft Condensed Matter · Physics 2009-11-10 A. Shafir , D. Andelman , R. R. Netz

The behavior of electrolyte solutions close to a charged surface is studied theoretically. A modified Poisson-Boltzmann equation which takes into account the volume excluded by the ions in addition to the electrostatic interactions is…

Soft Condensed Matter · Physics 2007-05-23 I. Borukhov , D. Andelman , H. Orland

Electrostatic charging of insulating fine particles can be responsible for numerous phenomena ranging from lightning in volcanic plumes to dust explosions. However, even basic aspects of how fine particles become charged are still unclear.…

Materials Science · Physics 2018-04-04 Victor Lee , Nicole M. James , Scott Waitukaitis , Heinrich M. Jaeger

The results of a study that helps understand the mechanisms of adsorption of polyelectrolytes on particles, using numerical simulation methods, specifically the one known as dissipative particle dynamics are reported here. The adsorption of…

Soft Condensed Matter · Physics 2016-08-24 M. A. Balderas Altamirano , R. Camacho , E. Pérez , A. Gama Goicochea

The structure of polar liquids and electrolytic solutions, such as water and aqueous electrolytes, at interfaces underlies numerous phenomena in physics, chemistry, biology, and engineering. In this work, we develop a continuum theory that…

Soft Condensed Matter · Physics 2022-07-13 J. Pedro de Souza , Alexei A. Kornyshev , Martin Z. Bazant

Electrometry near a dielectric surface is performed using Rydberg electromagnetically induced transparency (EIT). The large polarizability of high n-state Rydberg atoms gives this method extreme sensitivity. We show that adsorbates on the…

Atomic Physics · Physics 2015-05-28 R. P. Abel , C. Carr , U. Krohn , C. S. Adams

The purpose of this project is to investigate the use of charge couple devices (CCDs) to detect electrons directly. This can be done in transmission electron microscopy (TEM) for electrons over 100 KeV, but for space plasma instruments,…

Instrumentation and Detectors · Physics 2015-10-28 S. R. Mirfayzi

In the present study, we have investigated, using Monte Carlo simulations (MC), the adsorption of polyelectrolytes on the charged nanopatterned surfaces. Different surface patterns were considered and we noticed that the amount of…

Soft Condensed Matter · Physics 2020-02-04 Amin Bakhshandeh , Maximiliano Segala

We investigate ionization at a solid-water interface in applied electric field. We attach an electrode to a dielectric film bearing silanol or carboxyl groups with an areal density $\Gamma_0$, where the degree of dissociation $\alpha$ is…

Soft Condensed Matter · Physics 2016-09-29 Ryuichi Okamoto , Akira Onuki

The adsorption of hydrogen at nonpolar GaN(1-100) surfaces and its impact on the electronic and vibrational properties is investigated using surface electron spectroscopy in combination with density functional theory (DFT) calculations. For…

Materials Science · Physics 2017-06-28 L. Lymperakis , J. Neugebauer , M. Himmerlich , S. Krischok , M. Rink , J. Kröger , V. M. Polyakov

The problem of charged polymer chains (polyelectrolytes) as they adsorb on a planar surface is addressed theoretically. We review the basic mechanisms and theory underlying polyelectrolyte adsorption on a single surface in two situations:…

Soft Condensed Matter · Physics 2012-01-31 David Andelman , Jean-Francois Joanny

Experiments carried out at our laboratories have led to observing a new type of electrification, now called surface photocharging. For a consistent description, we are weighing carefully the experimental evidence against the common…

Materials Science · Physics 2007-05-23 O. Ivanov , R. Dyulgerova , M. Georgiev

The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions…

Soft Condensed Matter · Physics 2009-10-31 I. Borukhov , D. Andelman , H. Orland

Plasma-boundaries floating in an ionized gas are usually negatively charged. They accumulate electrons more efficiently than ions which leads to the formation of a quasi-stationary electron film at the boundaries. We propose, in a…

Plasma Physics · Physics 2009-08-24 Franz X. Bronold , H. Deutsch , H. Fehske