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We analyze, by means of an RPA calculation, the conditions under which a mixture of oppositely charged polyelectrolytes can micro-segregate in the neighborhood of a charged surface creating a layered structure. A number of stable layers can…

Soft Condensed Matter · Physics 2009-10-31 F. J. Solis , M. Olvera de la Cruz

Tuning dimensionality in van der Waals materials with finite interlayer coupling has introduced various electronic phase transitions by conventional mechanical exfoliation. Particularly when the electronic order is tied to the modulation of…

Strongly Correlated Electrons · Physics 2023-01-12 Hyoung Kug Kim , So Young Kim , C. J. Won , Sang-Wook Cheong , Jonghwan Kim , Jun Sung Kim , Tae-Hwan Kim

The interplay between strong Coulomb interactions and randomness has been a long-standing problem in condensed matter physics. According to the scaling theory of localization, in two-dimensional systems of noninteracting or weakly…

Strongly Correlated Electrons · Physics 2007-05-23 S. V. Kravchenko , M. P. Sarachik

Phase separation in salt-free symmetric mixtures of oppositely charged rodlike polyelectrolytes is studied using quasi-analytical calculations. Stability analyses for the isotropic-isotropic and the isotropic-nematic phase transitions in…

Soft Condensed Matter · Physics 2010-07-20 Rajeev Kumar , Debra Audus , Glenn H. Fredrickson

We consider single band of conduction electrons interacting with displacements of the transitional ions. In the classical regime strong enough coupling transforms the harmonic elastic energy for an ion to the one of the well with two deep…

Superconductivity · Physics 2015-06-04 Lev P. Gor'kov

As is well known in electrolyte theory, electrostatic fields are attenuated by the presence of mobile charges in the solution. This seems to limit the possibility of an electrostatic repulsion model of biological interactions such as cell…

Biological Physics · Physics 2012-01-04 Eshel Faraggi

The ion distribution of electrolytes near interfaces with dielectric contrast has important consequences for electrochemical processes and many other applications. To date, most studies of such systems have focused on geometrically simple…

Soft Condensed Matter · Physics 2018-11-14 Huanxin Wu , Honghao Li , Francisco J. Solis , Monica Olvera de la Cruz , Erik Luijten

The capacitance of the double layer formed at a metal/ionic-conductor interface can be remarkably large, so that the apparent width of the double layer is as small as 0.3 \AA. Mean-field theories fail to explain such large capacitance. We…

Soft Condensed Matter · Physics 2010-03-30 Brian Skinner , M. S. Loth , B. I. Shklovskii

Density functional theory is used to describe electrolyte solutions in contact with electrodes of planar or spherical shape. For the electrolyte solutions we consider the so-called civilized model, in which all species present are treated…

Soft Condensed Matter · Physics 2017-04-24 Andreas Reindl , Markus Bier , S. Dietrich

We show that when particles are suspended in an electrolyte confined between corrugated charged surfaces, electrokinetic flows lead to a new set of phenomena such as particle separation, mixing for low-Reynolds micro- and nano-metric…

Soft Condensed Matter · Physics 2015-06-22 Paolo Malgaretti , Ignacio Pagonabarraga , J. Miguel Rubi

We study theoretically the two interacting one-dimensional helical modes at the edges of the quantum spin Hall systems. A new type of inter-edge correlated liquid (IECL) without the spin gap is found. This liquid shows the diverging density…

Superconductivity · Physics 2015-05-13 Yukio Tanaka , Naoto Nagaosa

We investigate the role of nuclear motion and strong-field-induced electronic couplings during the double ionization of deuterated water using momentum-resolved coincidence spectroscopy. By examining the three-body dicationic dissociation…

We discuss properties of strongly correlated two-dimensional electron gas in semiconductor layers at low electron concentrations assuming that the electron liquid is close to crystalization. Analogy with the theory of 3He is emphasized.

Mesoscale and Nanoscale Physics · Physics 2009-10-31 B. Spivak

We study the electric double layer near a charged soft surface by using a mean-field approach including non-uniform size effect and solvent polarization. Based on a free energy model, electrostatic potential and number densities of water…

Soft Condensed Matter · Physics 2022-02-10 Jun-Sik Sin , Nam-Hyok Kim , Chung-Sik Sin

We explore theoretically the modifications to the interactions between charged surfaces across an ionic solution caused by the presence of dielectric polymers. Although the chains are neutral, the polymer physics and the electrostatics are…

Soft Condensed Matter · Physics 2007-05-23 O. A. Croze , M. E. Cates

A quasi-two-dimensional (Q2D) electron liquid (EL) is formed at the interface of a semiconductor heterojunction. For an accurate characterization of the Q2D EL, many-body effects need to be taken into account beyond the random phase…

Condensed Matter · Physics 2009-10-28 C. Bulutay , M. Tomak

The screened Coulomb interaction between uniformly charged flat plates is considered at very small plate separations for which the Debye layers are strongly overlapped, in the limit of small electrical potentials. If the plates are of…

Soft Condensed Matter · Physics 2017-02-06 Sandip Ghosal , John D. Sherwood

Understanding ion relaxation dynamics in overlapping electric double layers (EDLs) is critical for the development of efficient nanotechnology based electrochemical energy storage, electrochemomechanical energy conversion and…

Chemical Physics · Physics 2014-11-04 Vaibhav Thakore , James J. Hickman

Understanding overcharging and charge inversion is one of the long-standing challenges in soft matter and biophysics. To study these phenomena, we employ the modified Gaussian renormalized fluctuation theory, which allows for the…

Soft Condensed Matter · Physics 2024-01-01 Nikhil R. Agrawal , Chao Duan , Rui Wang

In this review, we shortly summarize the basic theoretical milestones achieved in the mean-field theory of room temperature ionic liquids (RTILs) on charged electrodes since the publication of Kornyshev's seminal paper in 2007. We pay…

Soft Condensed Matter · Physics 2021-12-28 Yury A. Budkov , Andrei L. Kolesnikov