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Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…

Mesoscale and Nanoscale Physics · Physics 2021-03-09 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…

Chemical Physics · Physics 2025-05-16 Xinwei Ji , Tao E. Li

The polarization dependence of nonequilibrium transitions in a multistable cavity-polariton system is studied under a nanosecond long resonant optical excitation at the normal and magic angle incidences with various polarizations of the…

Mesoscale and Nanoscale Physics · Physics 2015-05-28 S. S. Gavrilov , A. S. Brichkin , A. A. Demenev , A. A. Dorodnyy , S. I. Novikov , S. G. Tikhodeev , N. A. Gippius , V. D. Kulakovskii

Microcavity polaritons are light-matter quasiparticles that arise from the strong coupling between excitons and photons confined in a semiconductor microcavity. They typically operate at visible or near visible wavelengths. They combine the…

Mesoscale and Nanoscale Physics · Physics 2020-11-06 Dmitry D. Solnyshkov , Guillaume Malpuech , Philippe St-Jean , Sylvain Ravets , Jacqueline Bloch , Alberto Amo

The optical hybridization of the electronic states in strongly coupled molecule-cavity systems have revealed unique properties such as lasing, room temperature polariton condensation, and the modification of excited electronic landscapes…

We consider a semiconductor polymer chain coupled to a single electromagnetic mode in a cavity. The excitations of the chain have a mixed exciton-photon character and are described as polaritons. Polaritons are coupled to the lattice by the…

Mesoscale and Nanoscale Physics · Physics 2007-06-13 M. V. Katkov , Y. V. Pershin , C. Piermarocchi

We report on the realization of polariton quantum boxes in a semiconductor microcavity under strong coupling regime. The quantum boxes consist of mesas that confine the cavity photon, etched on top of the spacer of a microcavity. For mesas…

We investigate the steady states of a lossy array of nonlinear optical resonators that are driven by lasers and interact via mutual photon tunneling. For weak nonlinearities, we find two-mode squeezing of polaritons in modes whose…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Michael J. Hartmann

In this theoretical work, we study a double quantum dot interacting strongly with a microcavity, while undergoing resonant tunneling. Effects of interdot tunneling on the light-matter hybridized states are determined, and tunability of…

Quantum Physics · Physics 2018-11-08 Marlon S. Domínguez , David F. Macias-Pinilla , Hanz Y. Ramírez

We present a comprehensive investigation of the light-matter interaction dynamics in two-dimensional materials coupled with a spectrally isolated cavity mode in the strong coupling regime. The interaction between light and matter breaks the…

Mesoscale and Nanoscale Physics · Physics 2023-12-18 Maria Vittoria Gurrieri , Emil V. Denning , Kristian Seegert , Philip T. Kristensen , Jesper Mørk

Molecular polaritons, hybrid light-matter states formed from the strong coupling of molecular transitions and discrete photonic modes, are a compelling platform for optical control of chemical reactivity. Despite the origins of the field of…

Chemical Physics · Physics 2026-02-11 Jane C. Nelson , Trevor H. Wright , Neo Lin , Madeline Rohde , Marissa L. Weichman

Molecules constitute compact hybrid quantum optical systems that can interface photons, electronic degrees of freedom, localized mechanical vibrations and phonons. In particular, the strong vibronic interaction between electrons and nuclear…

We study the collective behavior of molecules placed in an infrared (IR) microcavity, incorporating the local fluctuations, i.e., dynamical disorder. The cooperative feature in vibrational polaritons is shown to be dynamically eroded, due…

Quantum Physics · Physics 2018-06-19 Zhedong Zhang , Kai Wang , Zhenhuan Yi , Shaul Mukamel , Marlan O. Scully

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

Polaritons in microcavities are versatile quasi-2D bosonic particles with a high degree of coherence and strong nonlinearities, thanks to their hybrid light-matter character. In their condensed form, they display striking quantum…

Recent experiments in polariton chemistry have demonstrated that reaction rates can be modified by vibrational strong coupling to an optical cavity mode. Importantly, this modification only occurs when the frequency of the cavity mode is…

Chemical Physics · Physics 2023-05-15 Marit R. Fiechter , Johan E. Runeson , Joseph E. Lawrence , Jeremy O. Richardson

I analyze a scheme that is capable of producing large Kerr nonlinearities on cavity-atom polaritons in a cavity QED system consisting of multiple three-level atoms confined in a cavity mode. A weak control laser coupled to the atoms from…

Optics · Physics 2015-05-14 Yifu Zhu

Recent experiments have revealed the profound effect of strong light-matter interactions in optical cavities on the electronic ground state of molecular systems. This phenomenon, known as vibrational strong coupling (VSC), can modify…

Quantum Physics · Physics 2023-12-19 Thomas Schnappinger , Markus Kowalewski

Experimental studies indicate that optical cavities can affect chemical reactions, through either vibrational or electronic strong coupling and the quantized cavity modes. However, the current understanding of the interplay between…

We review the recent developments of the polariton physics in microcavities featuring the exciton-photon strong coupling at room-temperature, and leading to the achievement of room-temperature polariton condensates. Such cavities embed…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 Thierry Guillet , Christelle Brimont