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Optical absorption spectra of higher fullerenes (C70 and C76) as well as of C60 are calculated by a tight binding model with a long range Coulomb interaction. A reasonable parameter set gives calculated spectra which are in overall…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya

Optical absorption spectra of C_70 and C_76 are calculated by a tight binding model with a long ranged Coulomb interaction. The spectrum of C_70 is in overall agreement with the experiment of molecules in a solution. The variations of the…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya , Shuji Abe

Effects of Coulomb interactions and lattice fluctuations in the optical absorption spectra of C60 and C70 are theoretically investigated by using a tight binding model with long-range Coulomb interaction and bond disorder. Anisotropy…

Condensed Matter · Physics 2008-02-03 Kikuo Harigaya , Shuji Abe

The optical excitations in $\rug$ and higher fullerenes, including isomers of C$_{76}$, C$_{78}$, and C$_{84}$, are theoretically investigated. We use a tight binding model with long-range Coulomb interactions, treated by the Hartree-Fock…

Condensed Matter · Physics 2008-02-03 Kikuo Harigaya

Recent synthetic studies on the organic molecules tetracene and pentacene have found certain dimers and oligomers to exhibit an intense absorption in the visible region of the spectrum which is not present in the monomer or many…

Charge-transfer (CT) exciton effects are investigated for the optical absorption spectra of crosslinked C60 systems by using the intermediate exciton theory. We consider the C60-dimers, and the two (and three) molecule systems of the…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya

We investigate the effect of exciton coupling on the optical absorption spectrum of polymer molecules under conditions of strong inhomogeneous broadening. We demonstrate that the dependence of the maximum in the rescaled absorption spectrum…

Chemical Physics · Physics 2009-11-13 A. L. Burin , J. A. Dickman , D. B. Uskov , C. F. F. Hebbard , G. C. Schatz

Optical absorption spectra of C60^6- are theoretically investigated in order to analyze the optical properties of alkali metal doped fullerites A6C60. We use a tight binding model with long ranged Coulomb interactions and bond disorder.…

Condensed Matter · Physics 2009-10-22 Kikuo Harigaya

Molecular exciton effects in the neutral and maximally doped C$_{60}$ (C$_{70}$) are considered using a tight binding model with long-range Coulomb interactions and bond disorder. By comparing calculated and observed optical spectra, we…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya , Shuji Abe

Charge-transfer (CT) exciton effects are investigated for the optical absorption spectra of crosslinked C60 systems by using the intermediate exciton theory. We consider the C60-dimers, and the two (and three) molecule systems of the…

chem-ph · Physics 2008-02-03 K. Harigaya

Optical absorption spectra of poly(thiophene vinylene) (PTV) conjugated polymers have been studied at room temperature in the spectral range of 450 to 800 nm. A dominant peak located at 577 nm and a prominent shoulder at 619 nm are…

Chemical Physics · Physics 2008-02-06 A. V. Gavrilenko , T. D. Matos , C. E. Bonner , S. -S. Sun , C. Zhang , V. I. Gavrilenko

The optical excitations in C$_{60}$ and higher fullerenes, including isomers of C$_{76}$, C$_{78}$, and C$_{84}$, are theoretically investigated. We use a tight binding model with long-range Coulomb interactions, treated by the Hartree-Fock…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya

The linear optical absorption spectra of three isomers of planar boron cluster B$_{13}$ are calculated using time-dependent spin-polarized density functional approach. The geometries of these cluster are optimized at the B3LYP/6-311+G*…

Atomic and Molecular Clusters · Physics 2013-02-12 Ravindra Shinde , Meenakshi Tayade

We measure the optical absorption spectra and optical conductivities of excitons and trions in monolayers of metal dichalcogenide MoS$_{2}$ and compare the results with theoretical models. Our results show that the Wannier-Mott model for…

Mesoscale and Nanoscale Physics · Physics 2014-06-04 Changjian Zhang , Haining Wang , Weimin Chan , Christina Manolatou , Farhan Rana

We extend the Su-Schrieffer-Heeger model of polyacetylene to C_{60} and C_{70} molecules, and solve numerically. The calculations of the undoped systems agree well with the known results. When the system (C_{60} or C_{70}) is doped with one…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya

Helicenes, a class of organic molecules consisting of ortho-fused benzene rings in a spring-like configuration have found several interesting applications in nonlinear optical materials and opto-electronic devices. Under the action of…

Chemical Physics · Physics 2023-03-08 Veera Sundararaghavan , Vikas Varshney , Davide Simone

The effects of chemical disorder on the electronic and optical properties of semiconductor alloy multilayers are studied based on the tight-binding theory and single-site coherent potential approximation. Due to the quantum confinement of…

Mesoscale and Nanoscale Physics · Physics 2010-06-03 Alireza Saffarzadeh , Leili Gharaee

A recently developed linear-scaling density-functional theory (LS-DFT) formalism is used to calculate optical absorption spectra of hybrids of C60 and the conjugated polymers poly(para-phenylene) (PPP) and poly(para-phenylene vinylene)…

Materials Science · Physics 2013-04-02 Laura E. Ratcliff , Peter D. Haynes

In this paper, we report large-scale configuration interaction (CI) calculations of linear optical absorption spectra of various isomers of magnesium clusters Mg$_{n}$ (n=2--5), corresponding to valence transitions. Geometry optimization of…

Atomic and Molecular Clusters · Physics 2017-11-28 Ravindra Shinde , Alok Shukla

We theoretically investigate optical absorption spectra of $\soc^{6-}$ and $\rug^{6-}$, and discuss relations with the optical properties of alkali metal doped fullerides $A_6\soc$ and $A_6\rug$. This is a valid approach for systems where…

Condensed Matter · Physics 2007-05-23 Kikuo Harigaya
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