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We present a simple method for fast and cheap thermal analysis on supercooled glass-forming liquids. This "Thermalization Calorimetry" technique is based on monitoring the temperature and its rate of change during heating or cooling of a…

An effect of laser-cooling of water was observed for the first time with a temperature decrease dT = -2.2 K after irradiation of liquid water surface by a powerful Ar-Xe pulse laser with a pulse energy of about 1 J and wavelength L = 1.73,…

Other Condensed Matter · Physics 2010-11-03 I. V. Kholin , D. A. Zayarnyi

Liquid water exhibits anomalous behavior in the supercooled region. A popular hypothesis to explain supercooled water's anomalies is the existence of a metastable liquid-liquid transition terminating at a critical point. The hypothesized…

Chemical Physics · Physics 2020-01-08 V. P. Voronov , V. E. Podnek , M. A. Anisimov

Because of the negative inclination of the solid-liquid phase separation line in water, ice Ih melts on compression. On further increase in pressure the liquid water transforms into a high density metastable glassy state, characterized by a…

Soft Condensed Matter · Physics 2021-04-22 Saumyak Mukherjee , Biman Bagchi

Any structural transformation of water is sensitive to an external electric field, since water molecules have dipole moments. We study influence of external uniform electric field on crystallization of supercooled water enclosed between two…

Soft Condensed Matter · Physics 2019-09-05 Ramil M. Khusnutdinoff , Anatolii V. Mokshin

The striking anomalies in physical properties of supercooled water that were discovered in the 1960-70s, remain incompletely understood and so provide both a source of controversy amongst theoreticians, and a stimulus to experimentalists…

Chemical Physics · Physics 2016-05-31 Sander Woutersen , Michiel Hilbers , Zuofeng Zhao , C. Austen Angell

We investigate with computer simulations the effect of applying an electric field on the water-to-ice transition. We use a combination of state-of-the-art simulation techniques to obtain phase boundaries and crystal growth rates (direct…

The phase transition between water and ice is ubiquitous and one of the most important phenomena in nature. Here, we performed time-resolved x-ray scattering experiments capturing the melting and recrystallization dynamics of ice. The…

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

We discuss the crystallization process from the supersaturated melt in terms of its non-equilibrium properties. In particular, we quantify the amount of heat that is produced irreversibly when a suspension of hard spheres crystallizes. This…

Statistical Mechanics · Physics 2015-04-17 Sven Dorosz , Thomas Voigtmann , Tanja Schilling

Surface freezing is a phenomenon in which crystallization is enhanced at a vapor-liquid interface. In some systems, such as $n$-alkanes, this enhancement is dramatic, and results in the formation of a crystalline layer at the free interface…

Soft Condensed Matter · Physics 2017-09-13 Amir Haji Akbari , Pablo G. Debenedetti

Temperature-driven polyamorphism has been reported in various supercooled liquids and glasses. The dynamical and structural routes followed by the system during such crossovers are however not universal and appear to be related to intrinsic…

Disordered Systems and Neural Networks · Physics 2018-08-29 S. Hechler , B. Ruta , M. Stolpe , E. Pineda , Z. Evenson , O. Gross , W. Hembree , A. Bernasconi , R. Busch , I. Gallino

Fast scanning calorimetry (FSC) was employed to investigate glass softening dynamics in amorphous solid water (ASW) nano-aggregates with thicknesses ranging from 2 to 20 nm. ASW nano-aggregates were prepared by vapor-deposition on the…

Soft Condensed Matter · Physics 2014-11-03 Deepanjan Bhattacharya , Liam OReilly , Vlad Sadtchenko

The mid-infrared heating of interfacial water with different initial temperatures is studied using non-equilibrium molecular dynamics simulation. It is found that under the irradiation of a pulse at 3360-3380 $cm^{-1}$ the two-dimensional…

Soft Condensed Matter · Physics 2022-07-19 Liu-Ye Meng , Rong-Yao Yang , Wei-Zhou Jiang

The process of homogeneous crystal nucleation has been considered in a model liquid, where the interparticle interaction is described by a short-range spherical oscillatory potential. Mechanisms of initiating structural ordering in the…

Materials Science · Physics 2018-12-18 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

Thin layers of water on biomolecular and other nanostructured surfaces can be supercooled to temperatures not accessible with bulk water. Chen et al. [PNAS 103, 9012 (2006)] suggested that anomalies near 220 K observed by quasi-elastic…

Soft Condensed Matter · Physics 2010-03-04 W. Doster , S. Busch , A. M. Gaspar , M. -S. Appavou , J. Wuttke , H. Scheer

We describe the phase diagram of amorphous solid water by performing molecular dynamics simulations. Our simulations follow different paths in the phase diagram: isothermal compression/decompression, isochoric cooling/heating and isobaric…

Soft Condensed Matter · Physics 2009-11-11 Nicolas Giovambattista , H. Eugene Stanley , Francesco Sciortino

Extreme electron-ion non-equilibrium states, generated by ultrafast laser excitation, lead to melting processes that are fundamentally different from those under conventional thermal equilibrium and remain not fully understood. Through…

Computational Physics · Physics 2025-11-27 Qiyu Zeng , Xiaoxiang Yu , Bo Chen , Shen Zhang , Kaiguo Chen , Dongdong Kang , Jiayu Dai

In this work, we provide mechanistic insight into the initial stages of formation of ice across the limit of stability of supercooled water. Such an analysis is particularly important since crystal nucleation is not a relevant mechanism…

Statistical Mechanics · Physics 2026-05-26 Ashutosh Srivastava , Pankaj A. Apte

Amorphization of silicon is crucial to applications in photonics, microelectronics and solar cell technologies. Ultrafast lasers have been used to generate amorphous silicon from crystalline silicon using rapid nonthermal melting and…