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Starting from a classical thermodynamic approach, we derive rate-type equations to describe the behavior of heat flow in deformable media. Constitutive equations are defined in the material (Lagrangian) description where the standard time…

Mathematical Physics · Physics 2024-02-02 Claudio Giorgi , Angelo Morro , Federico Zullo

We present a rigorous approach that leads, from a many-particle description, to a nonlinear, stochastic constitutive relation for the modeling of transient heat conduction processes at nanoscale. By enforcing statistical consistency, in…

Statistical Mechanics · Physics 2018-04-02 Weiqi Chu , Xiantao Li

We present a physics-based neural network framework for the discovery of constitutive models in fully coupled thermomechanics. In contrast to classical formulations based on the Helmholtz energy, we adopt the internal energy and a…

Computational Engineering, Finance, and Science · Computer Science 2026-05-25 Hagen Holthusen , Paul Steinmann , Ellen Kuhl

This paper deals with the time differential dual-phase-lag heat transfer models aiming, at first, to identify the eventually restrictions that make them thermodynamically consistent. At a first glance it can be observed that the capability…

Mathematical Physics · Physics 2021-03-19 Stan Chirita , Michele Ciarletta , Vincenzo Tibullo

We discuss a relativistic model for heat conduction, building on a convective variational approach to multi-fluid systems where the entropy is treated as a distinct dynamical entity. We demonstrate how this approach leads to a relativistic…

General Relativity and Quantum Cosmology · Physics 2011-02-11 C. S. Lopez-Monsalvo , N. Andersson

We provide a thermodynamic framework for binary mixtures of Korteweg fluids with two velocities and two temperatures. The constitutive functions are allowed to depend on the diffusion velocity and the specific internal energy of both…

Fluid Dynamics · Physics 2021-09-22 Vito Antonio Cimmelli , Matteo Gorgone , Francesco Oliveri , Angelo Raffaele Pace

We derive two different generalized heat-transport equations: The most general one, of the first order in time and second order in space, encompasses some well known heat equations and describes the hyperbolic regime in the absence of…

Statistical Mechanics · Physics 2019-06-11 Patrizia Rogolino , Róbert Kovács , Péter Ván , Vito Antonio Cimmelli

A linear irreversible thermodynamic framework of heat conduction in rigid conductors is introduced. The deviation from local equilibrium is characterized by a single internal variable and a current intensity factor. A general constitutive…

Statistical Mechanics · Physics 2014-04-08 P. Ván , T. Fülöp

Extended irreversible thermodynamics is a theory that expands the classical framework of nonequilibrium thermodynamics by going beyond the local-equilibrium assumption. A notable example of this is the Maxwell-Cattaneo heat flux model,…

Mathematical Physics · Physics 2025-09-18 François Gay-Balmaz

The second entropy theory for non-equilibrium thermodynamics is used to show that the optimum structure or pattern of a time-dependent system corresponds to the maximum entropy. A formula for the total entropy of convective heat flow is…

Statistical Mechanics · Physics 2012-09-11 Phil Attard

Some analogies between different nonequilibrium heat conduction models, particularly, random walk, discrete variable model, and Boltzmann transport equation with the single relaxation time approximation, have been discussed. We show that…

Statistical Mechanics · Physics 2018-02-21 Sergey Sobolev

We discuss heat conductivity from the point of view of a variational multi-fluid model, treating entropy as a dynamical entity. We demonstrate that a two-fluid model with a massive fluid component and a massless entropy can reproduce a…

Fluid Dynamics · Physics 2011-09-07 N. Andersson , G. L. Comer

A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…

Statistical Mechanics · Physics 2009-04-15 Hao Ge

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

We propose a general procedure for evaluating, directly from microphysics, the constitutive relations of heat-conducting fluids in regimes of large fluxes of heat. Our choice of hydrodynamic formalism is Carter's two-fluid theory, which…

Nuclear Theory · Physics 2024-02-09 Lorenzo Gavassino

The second law of thermodynamics is a useful and universal tool to derive the generalizations of the Fourier's law. In many cases, only linear relations are considered between the thermodynamic fluxes and forces, i.e., the conduction…

Statistical Mechanics · Physics 2019-12-25 Róbert Kovács , Patrizia Rogolino

Within the theory of interacting continua, we develop a model for a heat conducting mixture of two interacting fluids described in terms of the densities and the velocities for each fluid and the temperature field for the mixture as a…

Soft Condensed Matter · Physics 2021-09-02 Josef Málek , Ondřej Souček

In this paper, we develop a variational foundation for stochastic thermodynamics of finite-dimensional, continuous-time systems. Requiring the second law (non-negative average total entropy production) systematically yields a consistent…

Statistical Mechanics · Physics 2026-05-07 Héctor Vaquero del Pino , François Gay-Balmaz , Hiroaki Yoshimura , Lock Yue Chew

Second law of thermodynamics imposes that in any thermodynamic process the entropy production must be nonnegative. In continuum physics such a requirement is fulfilled by postulating the constitutive equations which represent the material…

Mathematical Physics · Physics 2022-02-03 V. A. Cimmelli , P. Rogolino

A generally relativistic theory of thermodynamics is developed, based on four main physical principles: heat is a local form of energy, therefore described by a thermal energy tensor; conservation of mass, equivalent to conservation of…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Sean A. Hayward
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