Related papers: Path integral for the quartic oscillator: An accur…
We derive the semiclassical series for the partition function of a one-dimensional quantum-mechanical system consisting of a particle in a single-well potential. We do this by applying the method of steepest descent to the path-integral…
Recent advances in the asymptotic analysis of energy levels of potentials produce relative errors in eigenvalue sums of order $10^{-34}$, but few non-trivial potentials have been solved numerically to such accuracy. We solve the general…
The partition function is an essential quantity in statistical mechanics, and its accurate computation is a key component of any statistical analysis of quantum system and phenomenon. However, for interacting many-body quantum systems, its…
The Lie--Trotter product formula is a foundational approximation for the quantum partition function, yet obtaining rigorous error bounds for the unbounded Hamiltonians common in physics remains a significant challenge. This paper provides a…
In this work, the energy eigenvalues are calculated for the quadratic ($\frac{g^2 x^2}{2}$), pure quartic ($\lambda x^4 $), and quartic anharmonic oscillators ($\frac{g^2 x^2}{2} + \lambda x^4 $) by applying variational method. For this,…
A convenient way to calculate $N$-particle quantum partition functions is by confining the particles in a weak harmonic potential instead of using a finite box or periodic boundary conditions. There is, however, a slightly different…
We derive two path integral estimators for the derivative of the quantum mechanical potential of mean force (PMF), which may be numerically integrated to yield the PMF. For the first estimator, we perform the differentiation on the exact…
We propose a simple estimator that allows to calculate the absolute value of a system's partition function from a finite sampling of its canonical ensemble. The estimator utilizes a volume correction term to compensate the effect that the…
The path integral formalism is applied to derive the full partition function of a generalized Su-Schrieffer-Heeger Hamiltonian describing a particle motion in a bath of oscillators. The electronic correlations are computed versus…
Introducing a perturbative definition, phase space path integrals can be calculated without slicing. This leads to a short-time expansion of the quantum-mechanical path amplitude, or a high-temperature expansion of the unnormalized density…
A method for nonperturbative path integral calculation is proposed. Quantum mechanics as a simplest example of a quantum field theory is considered. All modes are decomposed into hard (with frequencies $\omega^2 >\omega^2_0$) and soft (with…
We propose a new method for the efficient approximation of a class of highly oscillatory weighted integrals where the oscillatory function depends on the frequency parameter $\omega \geq 0$, typically varying in a large interval. Our…
The manner in which probability amplitudes of paths sum up to form wave functions of a harmonic oscillator, as well as other, simple 1-dimensional problems, is described. Using known, closed-form, path-based propagators for each problem, an…
It is shown that for the one-dimensional quantum anharmonic oscillator with potential $V(x)= x^2+g^2 x^4$ the Perturbation Theory (PT) in powers of $g^2$ (weak coupling regime) and the semiclassical expansion in powers of $\hbar$ for…
This paper investigates the thermodynamics of a large class of non-Hermitian, $PT$-symmetric oscillators, whose energy spectrum is entirely real. The spectrum is estimated by second-order WKB approximation, which turns out to be very…
We present a method to approximate partition functions of quantum systems using mixed-state quantum computation. For positive semi-definite Hamiltonians, our method has expected running-time that is almost linear in $(M/(\epsilon_{\rm…
We describe a method to compute thermodynamic quantities in the harmonic approximation for identical bosons and fermions in an external confining field. We use the canonical partition function where only energies and their degeneracies…
We present two algorithms, one quantum and one classical, for estimating partition functions of quantum spin Hamiltonians. The former is a DQC1 (Deterministic quantum computation with one clean qubit) algorithm, and the first such for…
In many situations, one can approximate the behavior of a quantum system, i.e. a wave function subject to a partial differential equation, by effective classical equations which are ordinary differential equations. A general method and…
Imaginary-time path integral (PI) is a rigorous tool to treat nuclear quantum effects in static properties. However, with its high computational demand, it is crucial to devise precise estimators. We introduce generalized PI estimators for…