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Electronic structure simulation is an anticipated application for quantum computers. Due to high-dimensional quantum entanglement in strongly correlated systems, the quantum resources required to perform such simulations are far beyond the…

Quantum Physics · Physics 2022-01-25 Jie Liu , Zhenyu Li , Jinlong Yang

Constructing appropriate unitary matrix operators for new quantum algorithms and finding the minimum cost gate sequences for the implementation of these unitary operators is of fundamental importance in the field of quantum information and…

Quantum Physics · Physics 2013-02-26 Anmer Daskin , Sabre Kais

Hybrid quantum-classical approaches offer potential solutions to quantum chemistry problems, yet they often manifest as constrained optimization problems. Here, we explore the interconnection between constrained optimization and generalized…

Quantum Physics · Physics 2025-03-27 Muqing Zheng , Bo Peng , Ang Li , Xiu Yang , Karol Kowalski

Variational quantum algorithms are considered to be appealing applications of near-term quantum computers. However, it has been unclear whether they can outperform classical algorithms or not. To reveal their limitations, we must seek a…

Quantum Physics · Physics 2020-12-15 Kosuke Mitarai , Yasunari Suzuki , Wataru Mizukami , Yuya O. Nakagawa , Keisuke Fujii

Computationally efficient and accurate quantum mechanical approximations to solve the many-electron Schr\"odinger equation are at the heart of computational materials science. In that respect the coupled cluster hierarchy of methods plays a…

Materials Science · Physics 2022-01-11 Tina N. Mihm , Tobias Schäfer , Sai Kumar Ramadugu , Andreas Grüneis , James J. Shepherd

One promising application of near-term quantum devices is to prepare trial wavefunctions using short circuits for solving different problems via variational algorithms. For this purpose, we introduce a new circuit design that combines…

Quantum Physics · Physics 2025-01-24 Abhinav Anand , Kenneth R. Brown

In classical computational chemistry, the coupled-cluster ansatz is one of the most commonly used $ab~initio$ methods, which is critically limited by its non-unitary nature. The unitary modification as an ideal solution to the problem is,…

Quantum Physics · Physics 2017-03-01 Yangchao Shen , Xiang Zhang , Shuaining Zhang , Jing-Ning Zhang , Man-Hong Yung , Kihwan Kim

Point splitting has been suggested as a way to deal with anomalous commutators in quantum field theory. It has been pointed out by D.G. Boulware[4] that in order to obtain a mathematically consistent theory the Hamiltonian operator must be…

Quantum Physics · Physics 2008-12-02 Dan Solomon

To obtain estimates of electronic energies, the Variational Quantum Eigensolver (VQE) technique performs separate measurements for multiple parts of the system Hamiltonian. Current quantum hardware is restricted to projective single-qubit…

Quantum Physics · Physics 2019-10-22 Artur F. Izmaylov , Tzu-Ching Yen , Robert A. Lang , Vladyslav Verteletskyi

A key task in quantum computation is the application of a sequence of gates implementing a specific unitary operation. However, the decomposition of an arbitrary unitary operation into simpler quantum gates is a nontrivial problem. Here we…

Quantum Physics · Physics 2016-03-23 Swathi S. Hegde , K. R. Koteswara Rao , T. S. Mahesh

Twirling noise affecting quantum gates is essential in understanding and controlling errors, but applicable operations to noise are usually restricted by symmetries inherent in quantum gates. In this work, we propose symmetric Clifford…

Quantum Physics · Physics 2025-06-18 Kento Tsubouchi , Yosuke Mitsuhashi , Kunal Sharma , Nobuyuki Yoshioka

The variational quantum eigensolver (VQE) algorithm combines the ability of quantum computers to efficiently compute expectation values with a classical optimization routine in order to approximate ground state energies of quantum systems.…

We employ quantum circuit learning to simulate quantum field theories (QFTs). Typically, when simulating QFTs with quantum computers, we encounter significant challenges due to the technical limitations of quantum devices when implementing…

High Energy Physics - Theory · Physics 2025-04-08 Kazuki Ikeda

The Hamiltonian of a quantum system is represented in terms of operators corresponding to the kinetic and potential energies of the system. The expectation value of a Hamiltonian and Hamiltonian simulation are two of the most fundamental…

Quantum Physics · Physics 2024-06-14 Benchi Zhao , Keisuke Fujii

We explore how to build quantum circuits that compute the lowest energy state corresponding to a given Hamiltonian within a Symmetry subspace by explicitly encoding it into the circuit. We create an explicit unitary and a variationally…

Quantum Physics · Physics 2021-12-28 Raja Selvarajan , Manas Sajjan , Sabre Kais

Unknown unitary inversion is a fundamental primitive in quantum computing and physics. Although recent work has demonstrated that quantum algorithms can invert arbitrary unknown unitaries without accessing their classical descriptions,…

Quantum Physics · Physics 2025-06-26 Yin Mo , Tengxiang Lin , Xin Wang

For the variational quantum eigensolver we propose to generate trial wavefunctions from a small amount of selected Pauli terms of the problem Hamiltonian. Two different approaches, one inspired by the quantum approximate optimization…

Quantum Physics · Physics 2019-08-27 Gian Salis , Nikolaj Moll

We study the quantum computational power of a generic class of anisotropic solid state Hamiltonians. A universal set of encoded logic operations are found which do away with difficult-to-implement single-qubit gates in a number of quantum…

Quantum Physics · Physics 2016-09-08 L. -A. Wu , D. A. Lidar

Pauli-based computation (PBC) is driven by a sequence of adaptively chosen, non-destructive measurements of Pauli observables. Any quantum circuit written in terms of the Clifford+$T$ gate set and having $t$ $T$ gates can be compiled into a…

Quantum Physics · Physics 2023-10-04 Filipa C. R. Peres , Ernesto F. Galvão

We propose a computational protocol for quantum simulations of Fermionic Hamiltonians on a quantum computer, enabling calculations which were previously not feasible with conventional encoding and ansatses of variational quantum…

Quantum Physics · Physics 2023-03-15 Benchen Huang , Nan Sheng , Marco Govoni , Giulia Galli