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The ground-state hyperfine splitting values of high-Z boronlike ions are calculated. Calculation of the interelectronic-interaction contribution is based on a combination of the 1/Z perturbation theory and the large-scale…

Atomic Physics · Physics 2009-11-13 N. S. Oreshkina , D. A. Glazov , A. V. Volotka , V. M. Shabaev , I. I. Tupitsyn , G. Plunien

We explore the possibility of calculating electronic excited states by using perturbation theory along a range-separated adiabatic connection. Starting from the energies of a partially interacting Hamiltonian, a first-order correction is…

Chemical Physics · Physics 2014-12-15 Elisa Rebolini , Julien Toulouse , Andrew M. Teale , Trygve Helgaker , Andreas Savin

We present a new dimensional scaling transformation of the Schrodinger equation for the two electron bond. This yields, for the first time, a good description of the two electron bond via D-scaling. There also emerges, in the large-D limit,…

Chemical Physics · Physics 2009-11-11 Anatoly A. Svidzinsky , Marlan O. Scully , Dudley R. Herschbach

A G{\"o}rling-Levy (GL)-based perturbation theory along the range-separated adiabatic connection is assessed for the calculation of electronic excitation energies. In comparison with the Rayleigh-Schr{\"o}dinger (RS)-based perturbation…

Chemical Physics · Physics 2018-05-23 Elisa Rebolini , Andrew M. Teale , Trygve Helgaker , Andreas Savin , Julien Toulouse

We predict neutron-proton scattering cross-sections and polarization observables up to next-to-next-to-next-to leading order in a renormalization-group invariant description of the strong nucleon-nucleon interaction. Low-energy constants…

Nuclear Theory · Physics 2024-06-12 Oliver Thim , Andreas Ekström , Christian Forssén

By using a Coulomb potential modified by the interaction between the magnetic moments of the electron and proton, we have calculated the energy levels of a hydrogen atom. We have obtained fine structure, hyperfine structure and the Lamb…

General Physics · Physics 2015-10-20 Voicu Dolocan

Perturbative methods are attractive to describe the electronic structure of molecular systems because of their low-computational cost and systematically improvable character. In this work, a two-step perturbative approach is introduced…

Chemical Physics · Physics 2023-11-15 Loris Delafosse , Amr Hussein , Saad Yalouz , Vincent Robert

The present review includes the description of theoretical methods for the investigations of the spectra of hydrogen-like systems. Various versions of the quasipotential approach and the method of the effective Dirac equation are…

High Energy Physics - Phenomenology · Physics 2011-07-19 Valeri V. Dvoeglazov , Rudolf N. Faustov , Yuri N. Tyukhtyaev

The O(4) supersymmetry of the hydrogen atom is utilized to construct a complete basis using only the bound state wave functions. For a large class of perturbations, an expansion of the electron (exciton) wave function into such a complete…

Mathematical Physics · Physics 2012-05-25 E. A. Muljarov

In this work, we introduce a selective and scalable extension of the multi-step Rayleigh-Schrodinger and Brillouin-Wigner perturbative scheme (see arXiv:2408.16505), designed to efficiently access the low-energy spectrum of molecular…

Chemical Physics · Physics 2025-09-30 Oussama Bindech , Saad yalouz , Vincent Robert

A precise calculation of the ground-state energy of the complex PT-symmetric Hamiltonian $H=p^2+{1/4}x^2+i \lambda x^3$, is performed using high-order Rayleigh-Schr\"odinger perturbation theory. The energy spectrum of this Hamiltonian has…

Quantum Physics · Physics 2009-10-31 Carl M. Bender , Gerald V. Dunne

Perturbation theory is used systematically to investigate the symmetries of the Dirac Hamiltonian and their breaking in atomic nuclei. Using the perturbation corrections to the single-particle energies and wave functions, the link between…

Nuclear Theory · Physics 2011-04-15 Haozhao Liang , Pengwei Zhao , Ying Zhang , Jie Meng , Nguyen Van Giai

We make a comparison between the energy levels of the hydrogen atom, calculated by using standard methods, and that by using a modified Coulomb potential due to the interaction between the magnetic moments of the proton and electron. In…

Atomic Physics · Physics 2014-07-09 Voicu Dolocan

Measurements of energy separations in highly charged ions can in many cases nowadays be performed with very high accuracy, an accuracy that sometimes cannot be matched by the corresponding theoretical calcula- tions. Furthermore, it has…

Atomic Physics · Physics 2013-01-01 Ingvar Lindgren , Sten Salomonson , Johan Holmberg

Rydberg atomic quantum receivers have been seen as novel radio frequency measurements and the high sensitivity to a large range of frequencies makes it attractive for communications reception. However, their unique physical characteristics…

Signal Processing · Electrical Eng. & Systems 2025-09-24 Hao Wu , Xinyuan Yao , Rui Ni , Chen Gong , Kaibin Huang

Energy levels of neutral atoms have been re-examined by applying an alternative perturbative scheme in solving the Schrodinger equation for the Yukawa potential model with a modified screening parameter. The predicted shell binding energies…

Quantum Physics · Physics 2009-11-11 Sameer M. Ikhdair , Ramazan Sever

Accurate quantum mechanics based predictions of property trends are so important for materials design and discovery that even inexpensive approximate methods are valuable. We use the Alchemical Integral Transform (AIT) to study…

Chemical Physics · Physics 2024-09-16 Simon León Krug , O. Anatole von Lilienfeld

The energy difference between two iso-electronic systems can be accurately approximated by the alchemical first order Hellmann-Feynmann derivative for the averaged Hamiltonian. This approximation is exact up to third order because…

Chemical Physics · Physics 2025-09-05 O. Anatole von Lilienfeld , Giorgio Domenichini

We study energy spectrum for hydrogen atom with deformed Heisenberg algebra leading to minimal length. We develop correct perturbation theory free of divergences. It gives a possibility to calculate analytically in the 3D case the…

Quantum Physics · Physics 2009-12-14 M. M. Stetsko , V. M. Tkachuk

A high-precision numerical calculation is reported for the self-energy correction to the hyperfine splitting and to the bound-electron g factor in hydrogenlike ions with low nuclear charge numbers. The binding nuclear Coulomb field is…

Atomic Physics · Physics 2009-11-13 V. A. Yerokhin , U. D. Jentschura
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