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Diamond holds significant promise for a wide range of applications due to its exceptional physicochemical properties. Investigating the controlled diamond preparation from nanocarbon precursors with varying dimensions is crucial to optimize…

Materials Science · Physics 2025-02-18 Jiaxin Ming , Jingyi Tian , Liming Zhao , Jiayin Li , Guoshuai Du , Lixing Kang , Zheng Hu , Yabin Chen

Novel ultra-hard carbon allotrope is proposed with mechanical, dynamic, and thermal properties like diamond. Based on energy criteria from computations within density functional theory DFT, tetragonal C8 stoichiometry is identified as a…

Materials Science · Physics 2022-09-13 Samir F. Matar

Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these charac- teristics and have even been expected to be harder…

Materials Science · Physics 2015-06-29 Huafeng Dong , Artem R. Oganov , Qiang Zhu , Guang-Rui Qian

Nitrogen vacancy (NV-) color centers in diamond are a prime candidate for use in quantum information devices, owing to their spin-1 ground state, straightforward optical initialization and readout, and long intrinsic coherence times in a…

Quantum Physics · Physics 2015-06-19 Anna J. Parker , Hai-Jing Wang , Yiran Li , Alexander Pines , Jonathan P. King

Interconnect materials with ultralow dielectric constant, and good thermal and mechanical properties are crucial for the further miniaturization of electronic devices. Recently, it has been demonstrated that ultrathin amorphous boron…

Boron nitride (BN) is an exceptional material and among its polymorphs, two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and c-BN) phases are most common. The phase stability regimes of these BN phases are still…

Using atomistic simulations we investigate the thermodynamical properties of a single atomic layer of hexagonal boron nitride (h-BN). The thermal induced ripples, heat capacity, and thermal lattice expansion of large scale h-BN sheets are…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Sandeep Kumar Singh , M. Neek-Amal , S. Costamagna , F. M. Peeters

Diamond is a promising material for high-power electronic applications in both the dc and rf domains. However, the predicted advantages are yet to be realized for a number of technical challenges. In particular, n-type devices have not been…

Applied Physics · Physics 2019-01-31 Namita Narendra , Jagdish Narayan , Ki Wook Kim

We report an extensive study of the properties of carbyne using first-principles calculations. We investigate carbyne's mechanical response to tension, bending, and torsion deformations. Under tension, carbyne is about twice as stiff as the…

Materials Science · Physics 2013-12-03 Mingjie Liu , Vasilii I. Artyukhov , Hoonkyung Lee , Fangbo Xu , Boris I. Yakobson

Polarized negative muons were used to study the behaviour of the boron acceptor centre in synthetic diamond produced by the chemical vapour deposition (CVD) method. The negative muon substitutes one of the electrons in a carbon atom, and…

Boron nitride (BN) is a structurally versatile insulator since it can be found in several crystalline structures with interesting mechanical and electrical properties, making this material attractive for technological applications. Seeking…

Heat management becomes more and more critical, especially in miniaturized modern devices, so the exploration of highly thermally conductive materials with electrical insulation and favorable mechanical properties is of great importance.…

Boron-doped diamond crystals (BDD, C$_{1-x}$B$_{x}$) exhibit exceptional mechanical strength, electronic tunability, and resistance to radiation damage. This makes them promising materials for use in gamma-ray crystal-based light sources.…

In the present paper, we investigate the structural, thermodynamic, dynamic, elastic, and electronic properties of doped 2D diamond C$_4$X$_2$ (X = B or N) nanosheets in both AA$'$A$''$ and ABC stacking configurations, by first-principles…

Materials Science · Physics 2024-01-10 Bruno Ipaves , João F. Justo , Biplab Sanyal , Lucy V. C. Assali

The ultrathin one-dimensional sp3 diamond nanothreads (NTHs), as successfully synthesised recently, have greatly augmented the interests from the carbon community. In principle, there can exist different stable NTH structures. In this work,…

Materials Science · Physics 2018-03-20 Haifei Zhan , Gang Zhang , John M. Bell , Yuantong Gu

Nano-polycrystalline diamond (NPD) and nanotwinned diamond (NtD) were successfully synthesized in multi-anvil high pressure apparatus at high pressure and high temperature (HPHT) conditions using precursors of onion carbons. We found that…

Materials Science · Physics 2017-02-28 Qiang Tao , Xin Wei , Min Lian , Hongliang Wang , Xin Wang , Shushan Dong , Tian Cui , Pinwen Zhu

Pressure is a unique tool to tune the interplay between structural, electronic and magnetic interactions. It leads to remarkable properties of materials such as recent temperature records in superconductivity. Advanced magnetic measurements…

The nitrogen-vacancy (NV) center is a well utilized system for quantum technology, in particular quantum sensing and microscopy. Fully employing the NV center's capabilities for metrology requires a strong understanding of the behavior of…

Mesoscale and Nanoscale Physics · Physics 2019-03-13 M. S. J. Barson , P. M. Reddy , S. Yang , N. B. Manson , J. Wrachtrup , M. W. Doherty

The pressure-induced structural transition in fcc C$_{60}$ fullerene by shock compression and rapid quenching is investigated by a semi-empirical tight-binding molecular dynamics simulation, adopting a constant-pressure scheme and a method…

Computational Physics · Physics 2007-05-23 Akihito Kikuchi , Shinji Tsuneyuki

Using first principles calculations, this work investigates the suitability of diamond/c-BN heterojunctions for high frequency, high power device applications. The key quantities of band offsets and interface charge polarization are…

Materials Science · Physics 2023-10-12 Jeffrey T. Mullen , James A. Boulton , Minghao Pan , Ki Wook Kim