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Polariton chemistry has been hailed as a potential new route to direct molecular processes with electromagnetic fields. To make further strides, it is essential for the community to clarify which unusual polaritonic phenomena are true…

Chemical Physics · Physics 2025-11-19 Alexander M. McKillop , Marissa L. Weichman

The observation that materials can change their properties when placed inside or near an optical resonator, has sparked a fervid interest in understanding the effects of strong light-matter coupling on molecular dynamics, and several…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Gerrit Groenhof

We benchmark a selection of semiclassical and perturbative dynamics techniques by investigating the correlated evolution of a cavity-bound atomic system to assess their applicability to study problems involving strong light-matter…

Quantum Physics · Physics 2020-01-29 Norah M. Hoffmann , Christian Schäfer , Niko Säkkinen , Angel Rubio , Heiko Appel , Aaron Kelly

Intense light-matter interaction largely relies on the use of high-power light sources, creating fields comparable to, or even stronger than, the field keeping the electrons bound in atoms. Under such conditions, the interaction induces…

Quantum Physics · Physics 2025-10-23 P. Stammer , J. Rivera-Dean , P. Tzallas , M. F. Ciappina , M. Lewenstein

Classical theory asserts that several electromagnetic waves cannot interact with matter if they interfere destructively to zero, whereas quantum mechanics predicts a nontrivial light-matter dynamics even when the average electric field…

In this contribution we deal with several issues one encounters when trying to couple quantum matter to classical gravitational fields. We start with a general background discussion and then move on to two more technical sections. In the…

General Relativity and Quantum Cosmology · Physics 2023-10-13 Domenico Giulini , André Großardt , Philip K. Schwartz

In this work we provide a complete model of semiclassical theories by including back-reaction and correlation into the picture. We specially aim at the interaction between light and a two-level atom, and we also illustrate it via the…

Quantum Physics · Physics 2019-10-28 Gerardo García , Laura Ares , Alfredo Luis

Polaritonic chemistry exploits strong light-matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both…

Optics · Physics 2022-08-25 Jacopo Fregoni , Francisco J. García-Vidal , Johannes Feist

The transport of ultra-cold atoms in magneto-optical potentials provides a clean setting in which to investigate the distinct predictions of classical versus quantum dynamics for a system with coupled degrees of freedom. In this system,…

The emergent semiclassical time approach to resolving the problem of time in quantum gravity involves heavy slow degrees of freedom providing via an approximately Hamilton-Jacobi equation an approximate timestandard with respect to which…

General Relativity and Quantum Cosmology · Physics 2015-05-27 Edward Anderson

We present a time-dependent variational approach with the multiple Davydov $D_2$ trial state to simulate the dynamics of light-matter systems when the field is in a coherent state with an arbitrary finite mean photon number. The variational…

Quantum Physics · Physics 2024-07-18 Yiying Yan , Zhiguo Lü , JunYan Luo

The interaction of atoms and molecules with quantum light as realized in cavities has become a highly topical and fast growing field of research. This interaction leads to the formation of hybrid light-matter states giving rise to new…

Chemical Physics · Physics 2022-12-15 Lorenz S. Cederbaum , Jacqueline Fedyk

We study light-mediated interactions between spatially separated molecules using real-time quantum electrodynamical time-dependent density functional theory based on the Pauli-Fierz Hamiltonian. An ultrashort delta-kick excitation…

Chemical Physics · Physics 2026-01-22 Yetmgeta Aklilu , Tiany Yang , Cody Covington , Kalman Varga

Mean-field mixed quantum--classical dynamics could provide a much-needed means to inexpensively model quantum electrodynamical phenomena, by describing the optical field and its vacuum fluctuations classically. However, this approach is…

Chemical Physics · Physics 2023-12-11 Ming-Hsiu Hsieh , Alex Krotz , Roel Tempelaar

Light beams offer many degrees of freedom to be explored in discrete and continuous domains. In addition to the possibility of entangling photons in these many degrees of freedom, it makes light a very useful and versatile tool for quantum…

Quantum Physics · Physics 2020-11-12 Thais de Lima Silva

Semi-classical approaches approximate fully quantum descriptions with partially classical ones. Here we use a toy model to highlight the failings of the standard mean-field semi-classical approach, and show how including environmental…

Quantum Physics · Physics 2026-04-10 Isaac Layton

Quantum-matter theory (QMT), based on the Schr\"odinger or Dirac equations, is firmly established for both intra- and intermolecular interactions. However, there are two key issues with QMT. First, its applicability to large molecular…

Chemical Physics · Physics 2026-03-19 Reza Karimpour , Matteo Gori , Alexandre Tkatchenko

Nonclassical states of light and their correlations lie at the heart of quantum optics, serving as fundamental resources that underpin both the exploration of quantum phenomena and the realisation of quantum information protocols. These…

Quantum Physics · Physics 2026-01-29 Jhoan Eusse , Esteban Vasquez , Tom Rivlin , Elizabeth Agudelo

We analytically tackle opto-vibronic interactions in molecular systems driven by either classical or quantum light fields. In particular, we examine a simple model of molecules with two relevant electronic levels, characterized by potential…

Quantum Physics · Physics 2024-02-28 Q. Zhang , M. Asjad , M. Reitz , C. Sommer , B. Gurlek , C. Genes

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum