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The properties of a hard-sphere fluid in contact with hard spherical and cylindrical walls are studied. Rosenfeld's density functional theory (DFT) is applied to determine the density profile and surface tension $\gamma$ for wide ranges of…

Statistical Mechanics · Physics 2007-05-23 P. Bryk , R. Roth , K. R. Mecke , S. Dietrich

Using classical density functional theory (DFT) in a modified mean-field approximation we investigate the fluid phase behavior of quasi-two dimensional dipolar fluids confined to a plane. The particles carry three-dimensional dipole moments…

Statistical Mechanics · Physics 2013-06-18 R. Geiger , S. H. Klapp

The structure of polydisperse hard sphere fluids, in the presence of a wall, is studied by the Rosenfeld density functional theory. Within this approach, the local excess free energy depends on only four combinations of the full set of…

Soft Condensed Matter · Physics 2009-10-31 I. Pagonabarraga , M. E. Cates , G. J. Ackland

Snapshots of colloidal particles moving on disordered two-dimensional substrates can be used to extract equal-time many-body correlations in their positions. To understand the systematics of these correlations, we perform Monte Carlo…

Soft Condensed Matter · Physics 2019-10-23 N. Shankaraiah , Surajit Sengupta , Gautam I. Menon

A formulation of the density functional theory is constructed on the foundations of entropic inference. The theory is introduced as an application of maximum entropy for inhomogeneous fluids in thermal equilibrium. It is shown that entropic…

Statistical Mechanics · Physics 2023-12-29 Ahmad Yousefi , Ariel Caticha

When a fluid is subject to an external field, as is the case near an interface or under spatial confinement, then the density becomes spatially inhomogeneous. Although the one-body density provides much useful information, a higher level of…

Soft Condensed Matter · Physics 2022-07-14 S. M. Tschopp , F. Sammüller , S. Hermann , M. Schmidt , J. M. Brader

We study the two-point correlation function of density perturbations in a spherically symmetric void universe model which does not employ the Copernican principle. First we solve perturbation equations in the inhomogeneous universe model…

Cosmology and Nongalactic Astrophysics · Physics 2013-12-25 Ryusuke Nishikawa , Chul-Moon Yoo , Ken-ichi Nakao

Many strongly correlated states, such as those arising in the fractional quantum Hall effect and spin liquids, are described by wave functions obtained by dividing particles into multiple clusters, constructing a readily evaluable wave…

Strongly Correlated Electrons · Physics 2025-10-24 Koyena Bose , Steven H. Simon , Ajit C. Balram

In a granular gas, inelastic collisions produce an instability in which the constituent particles cluster heterogeneously. These clusters then interact with each other, further decreasing their kinetic energy. We report experiments of the…

Soft Condensed Matter · Physics 2015-06-17 Justin C. Burton , Peter Y. Lu , Sidney R. Nagel

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

The consolidation of suspended particulate matter under external forces such as pressure or gravity is of widespread interest. In this work, we derive a constitutive relation to describe the deformation of a {\it two-dimensional} strongly…

Soft Condensed Matter · Physics 2014-02-26 Saikat Roy , Mahesh S Tirumkudulu

The influence of poor solvent quality on fluid demixing of a model mixture of colloids and nonadsorbing polymers is investigated using density functional theory. The colloidal particles are modelled as hard spheres and the polymer coils as…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

Soft matters whose constituents are deformable are ubiquitous in nature especially in biological systems-including cells and their organelles-as well as in foams and emulsions. The capacity for deformation in these soft materials gives rise…

Soft Condensed Matter · Physics 2026-03-05 Padmanabha Bose , Smarajit Karmakar

Over the last few decades, classical density-functional theory (DFT) and its dynamic extensions (DDFTs) have become powerful tools in the study of colloidal fluids. Recently, previous DDFTs for spherically-symmetric particles have been…

Statistical Mechanics · Physics 2016-08-02 Miguel A. Durán-Olivencia , Benjamin D. Goddard , Serafim Kalliadasis

Using a dynamical density functional theory we analyze the density profile of a colloidal liquid near a wall under shear flow. Due to the symmetries of the system considered, the naive application of dynamical density functional theory does…

Soft Condensed Matter · Physics 2015-05-20 J. M. Brader , M. Krüger

The influence of clustering on the collision rate of inertial particles in a smooth random velocity field, mimicking the smaller scales of a turbulent flow, is analyzed. For small values of the the ratio between the relaxation time of the…

Statistical Mechanics · Physics 2009-11-13 Piero Olla

We develop a dynamical density functional theory based model for the drying of colloidal films on planar surfaces. We consider mixtures of two different sizes of hard-sphere colloids. Depending on the solvent evaporation rate and the…

Soft Condensed Matter · Physics 2021-01-28 Boshen He , Ignacio Martin-Fabiani , Roland Roth , Gyula I. Tóth , Andrew J. Archer

We consider a coupled system consisting of a kinetic equation coupled to a macroscopic Stokes (or Navier-Stokes) equation and describing the motion of a suspension of rigid rods in gravity. A reciprocal coupling leads to the formation of…

Fluid Dynamics · Physics 2015-10-13 Christiane Helzel , Athanasios E. Tzavaras

Based on density-functional theory we analyze the full phase diagram, the occurrence of long-ranged orientational order, and the structural properties of dipolar fluids. As a model system we consider the Stockmayer fluid that consists of…

Soft Condensed Matter · Physics 2009-09-25 B. Groh , S. Dietrich

We investigate the behavior of a patchy particle model close to a hard-wall via Monte Carlo simulation and density functional theory (DFT). Two DFT approaches, based on the homogeneous and inhomogeneous versions of Wertheim's first order…