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We review some recent developments which make use of the concept of `superstatistics', an effective description for nonequilibrium systems with a varying intensive parameter such as the inverse temperature. We describe how the asymptotic…

Statistical Mechanics · Physics 2017-08-23 Christian Beck

The concept of temperature is one of the key ideas in describing the thermodynamical properties of a physical system. In classical statistical mechanics of ideal gases, the notion of temperature can be described in two different ways, the…

Statistical Mechanics · Physics 2007-11-12 Krishna R. Narayanan , Arun R. Srinivasa

We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the…

Statistical Mechanics · Physics 2007-11-09 Stephen R. Williams , Denis J. Evans

What is the best description that we can construct of a thermodynamic system that is not in equilibrium, given only one, or a few, extra parameters over and above those needed for a description of the same system at equilibrium? Here, we…

Statistical Mechanics · Physics 2007-07-05 Gavin E. Crooks

The general fluctuation theory is reviewed with special attention to the role played by different ensembles, and is extended to incorporate stationary metastable states obtained in the long time limit. The fluctuation in a quantity depends…

Statistical Mechanics · Physics 2007-05-23 P. D. Gujrati

In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a 'consistent thermostatistics' which forbids negative absolute temperatures. Here we argue that the Gibbs entropy…

Statistical Mechanics · Physics 2015-01-22 Daan Frenkel , Patrick B Warren

Many complex systems are characterized by non-Boltzmann distribution functions of their statistical variables. If one wants to -- justified or not -- hold on to the maximum entropy principle for complex statistical systems (non-Boltzmann)…

Statistical Mechanics · Physics 2009-11-13 Stefan Thurner , Rudolf Hanel

The relationships between reversible Carnot cycles, the absence of perpetual motion machines and the existence of a non-decreasing, globally unique entropy function forms the starting point of many textbook presentations of the foundations…

Statistical Mechanics · Physics 2015-05-14 O. J. E. Maroney

We give a brief review of violations of the fluctuation-dissipation theorem (FDT) in out-of-equilibrium systems; in mean field scenarios the corresponding fluctuation-dissipation (FD) plots can, in the limit of long times, be used to define…

Statistical Mechanics · Physics 2007-05-23 P Sollich , S Fielding , P Mayer

The domain of validity of standard thermodynamics and Boltzmann-Gibbs statistical mechanics is discussed and then formally enlarged in order to hopefully cover a variety of anomalous systems. The generalization concerns {\it nonextensive}…

Statistical Mechanics · Physics 2007-05-23 C. Tsallis

Within the Tsallis thermodynamics' framework, and using scaling properties of the entropy, we derive a generalization of the Gibbs-Duhem equation. The analysis suggests a transformation of variables that allows standard thermodynamics to be…

Statistical Mechanics · Physics 2009-11-07 Eduard Vives , Antoni Planes

This study shows that the generalized Boltzmann distribution is the only distribution mathematically consistent with thermodynamics when the system is described by an ensemble of a certain mathematical form. This mathematical form is very…

Statistical Mechanics · Physics 2022-02-10 Xiang Gao

Superstatistics is an elegant framework for the description of steady-state thermodynamics, mostly used for systems with long-range interactions such as plasmas. In this work, we show that the potential energy distribution of a classical…

Statistical Mechanics · Physics 2025-03-25 Sergio Davis , Claudia Loyola , Carlos Femenías , Joaquín Peralta

A considerable body of experimental and theoretical work claims the existence of negative absolute temperatures in spin systems and ultra-cold quantum gases. Here, we clarify that such findings can be attributed to the use of a popular yet…

Statistical Mechanics · Physics 2015-06-15 Jörn Dunkel , Stefan Hilbert

Statistical thermodynamics has a universal appeal that extends beyond molecular systems, and yet, as its tools are being transplanted to fields outside physics, the fundamental question, \textit{what is thermodynamics?}, has remained…

Statistical Mechanics · Physics 2019-09-17 Themis Matsoukas

We develop the argument that the Gibbs-von Neumann entropy is the appropriate statistical mechanical generalisation of the thermodynamic entropy, for macroscopic and microscopic systems, whether in thermal equilibrium or not, as a…

Quantum Physics · Physics 2008-01-23 O. J. E. Maroney

We propose a general approach, named by us hyperstatistics, to treat complex systems, in which Boltzmann-Gibbs statistics breaks down in domains of the system. Hyperstatistics preserves the concavity of nonadditive $q$-entropy. We obtain…

Statistical Mechanics · Physics 2026-04-29 Lucas Squillante , Samuel M. Soares , Constantino Tsallis , Mariano de Souza

We deal with a generalized statistical description of nonequilibrium complex systems based on least biased distributions given some prior information. A maximum entropy principle is introduced that allows for the determination of the…

Statistical Mechanics · Physics 2009-11-13 Erik Van der Straeten , Christian Beck

Statistical mechanics can only be ultimately justified in terms of microscopic dynamics (classical, quantum, relativistic, or any other). It is known that Boltzmann-Gibbs statistics is based on the hypothesis of exponential sensitivity to…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis

In this paper we elaborate on the recently proposed superstatistics formalism [C. Beck and E.G.D. Cohen, Physica A 322, 267 (2003)], used to interpret unconventional statistics. Their interpretation is that unconventional statistics in…

Statistical Mechanics · Physics 2007-05-23 F. Sattin