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We report an experiment to measure the femtosecond electric field of the signal emitted from an optical third-order nonlinear interaction in carbon dioxide molecules. Using degenerate four-wave mixing with femtosecond near infrared laser…

Quantum Physics · Physics 2022-10-05 Francis Walz , Siddhant Pandey , Liang Z. Tan , Niranjan Shivaram

We describe an experiment to measure the emitted real-time electric field from an ultrafast third-order nonlinear optical interaction in molecules, using a phase-tracked spectral interferometry scheme. By combining a software lock-in…

Optics · Physics 2025-03-11 Siddhant Pandey , Francis Walz , Niranjan Shivaram

Four-wave mixing processes are ubiquitous in ultrafast optics and the determination of the coefficients of the $\chi^{(3)}$ tensor is thus essential. We introduce a novel time-resolved ultrafast spectroscopic method to characterize the…

We report a novel experimental technique to investigate ultrafast dynamics in photoexcited molecules by probing the third-order nonlinear optical susceptibility. A non-colinear 3-pulse scheme is developed to probe the ultrafast dynamics of…

Measuring an electric field waveform beyond radio frequencies is often accomplished via a second-order nonlinear interaction with a laser pulse shorter than half of the field's oscillation period. However, synthesizing such a gate pulse is…

In ultrafast experiments with gas phase molecules, the alignment of the molecular axis relative to the polarization of the interacting laser pulses plays a crucial role in determining the dynamics following this light-matter interaction.…

Chemical Physics · Physics 2025-04-14 Shashank Kumar , Eric Liu , Liang Z. Tan , Varun Makhija , Niranjan Shivaram

Present photoionization experiments cannot measure molecular frame photoelectron angular distributions (MFPAD) from the outermost valence electrons of molecules. We show that details of the MFPAD can be retrieved with high-order harmonics…

Atomic Physics · Physics 2009-05-24 Anh-Thu Le , R. R. Lucchese , M. T. Lee , C. D. Lin

We combine different wavelengths from an intense high-order harmonics source with variable delay at the focus of a split-mirror interferometer to conduct pump-probe experiments on gas-phase molecules. We report measurements of the time…

Chemical Physics · Physics 2015-05-27 T. K. Allison , T. W. Wright , A. M. Stooke , C. Khurmi , J. van Tilborg , Y. Liu , R. W. Falcone , A. Belkacem

We use extreme-ultraviolet interferometry to measure the phase of high-order harmonic generation from transiently aligned CO2 molecules. We unambiguously observe a reversal in phase of the high order harmonic emission for higher harmonic…

Atomic Physics · Physics 2009-11-13 Xibin Zhou , Robynne Lock , Wen Li , Nick Wagner , Margaret. M. Murnane , Henry C. Kapteyn

Ultrafast two-dimensional spectroscopy utilizes correlated multiple light-matter interactions for retrieving dynamic features that may otherwise be hidden under the linear spectrum. Its extension to the terahertz regime of the…

In recent years, electro-optic sampling, which is based on Pockel's effect between an electromagnetic mode and a copropagating, phase-matched ultrashort probe, has been largely used for the investigation of broadband quantum states of…

Quantum Physics · Physics 2023-10-03 Francesca Fabiana Settembrini , Alexa Herter , Jèrôme Faist

We introduce and experimentally demonstrate a method, where the two intrinsic time scales of a molecule, the slow nuclear motion and the fast electronic motion, are simultaneously measured in a photo-electron photo-ion coincidence…

A magnetometric technique is demonstrated that may be suitable for precision measurements of fields ranging from the sub-microgauss level to above the Earth field. It is based on resonant nonlinear magneto-optical rotation caused by atoms…

Atomic Physics · Physics 2009-11-07 D. Budker , D. F. Kimball , V. V. Yashchuk , M. Zolotorev

Nonstationary molecular states which contain electronic coherences can be impulsively created and manipulated by using recently-developed ultrashort optical and X-ray pulses via photoexcitation, photoionization and Auger processes. We…

Chemical Physics · Physics 2015-09-02 Konstantin E. Dorfman , Kochise Bennett , Shaul Mukamel

We present high resolution two-photon excitation microscopy studies combining two-photon fluorescence (TPF) and second harmonic generation (SHG) in order to probe orientational distributions of molecular ensembles at room temperature. A…

Soft Condensed Matter · Physics 2007-05-23 Veronique Le Floc'h , Sophie Brasselet , Jean-Francois Roch , Joseph Zyss

We present an optical method to measure radio-frequency electro-optic phase modulation profiles by employing spectrum-to-time mapping realized by highly chirped optical pulses. We directly characterize temporal phase modulation profiles of…

Instrumentation and Detectors · Physics 2017-11-23 Michał Jachura , Jan Szczepanek , Wojciech Wasilewski , Michal Karpinski

Major advances in X-ray sources including the development of circularly polarized and orbital angular momentum pulses make it possible to probe matter chirality at unprecedented energy regimes and with Angstr\"om and femtosecond…

Chemical Physics · Physics 2022-09-20 Jeremy R. Rouxel , Shaul Mukamel

Photoelectron spectroscopy is a powerful method that provides insight into the quantum mechanical properties of a wide range of systems. The ionized electron wavefunction carries information on the structure of the bound orbital, the ionic…

We describe a technique for mapping the spatial variation of static electric, static magnetic, and rf magnetic fields using a pulsed atomic or molecular beam. The method is demonstrated using a beam designed to measure the electric dipole…

Atomic Physics · Physics 2009-11-13 J. J. Hudson , H. T. Ashworth , D. M. Kara , M. R. Tarbutt , B. E. Sauer , E. A. Hinds

Nontrivial symmetry of order parameters is crucial in some of the most interesting quantum many-body states of ultracold atoms and condensed matter systems. Examples in cold atoms include p-wave Feshbach molecules and d-wave paired states…

Quantum Gases · Physics 2011-05-02 Takuya Kitagawa , Alain Aspect , Marcus Greiner , Eugene Demler
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