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Positron binding energies in the negative ions H$^-$, F$^-$, Cl$^-$ and Br$^-$, and the closed-shell atoms Be, Mg, Zn and Ca, are calculated via a many-body theory approach developed by the authors [J.~Hofierka \emph{et al.} Nature~{\bf…

Atomic Physics · Physics 2023-11-23 J. Hofierka , B. Cunningham , C. M. Rawlins , C. H. Patterson , D. G. Green

Positron binding energies and Dyson orbitals for five-membered heterocycles with N, O, S and NH substituents are predicted \emph{ab initio} via many-body theory. The positron-molecule correlation potential (self energy) is calculated via…

Chemical Physics · Physics 2026-05-11 S. K. Gregg , D. G. Green

Positron binding energies in halogenated hydrocarbons are calculated \emph{ab initio} using many-body theory. For chlorinated molecules, including planars for which the interaction is highly anisotropic, very good to excellent agreement…

Chemical Physics · Physics 2024-04-24 J. P. Cassidy , J. Hofierka , B. Cunningham , C. M. Rawlins , C. H. Patterson , D. G. Green

Computational studies have shown that one or more positrons can stabilize two repelling atomic anions through the formation of two-center positronic bonds. In the present work, we study the energetic stability of a system containing two…

Positrons bind to molecules leading to vibrational excitation and spectacularly enhanced annihilation. Whilst positron binding energies have been measured via resonant annihilation spectra for $\sim$90 molecules in the past two decades, an…

Atomic Physics · Physics 2023-03-23 J. Hofierka , B. Cunningham , C. M. Rawlins , C. H. Patterson , D. G. Green

A many-body theory approach developed by the authors [Phys. Rev. A 70, 032720 (2004)] is applied to positron bound states and annihilation rates in atomic systems. Within the formalism, full account of virtual positronium (Ps) formation is…

Atomic Physics · Physics 2014-11-20 J. A. Ludlow , G. F. Gribakin

Diagrammatic many-body theory is used to calculate the scattering phase shifts, normalized annihilation rates $Z_{\rm eff}$ and annihilation gamma spectra for positron collisions with the hydrogen-like ions He$^+$, Li$^{2+}$, B$^{4+}$ and…

Atomic Physics · Physics 2014-04-22 D. G. Green , G. F. Gribakin

We present a theoretical framework to describe polarons from first principles within a many-body Green's function formalism. Starting from a general electron-phonon Hamiltonian, we derive a self-consistent Dyson equation in which the…

The many-body-theory approach to positronium-atom interactions developed in [Phys. Rev. Lett. \textbf{120}, 183402 (2018)] is applied to the sequence of noble-gas atoms He-Xe. The Dyson equation is solved separately for an electron and…

Atomic Physics · Physics 2023-05-24 A. R. Swann , D. G. Green , G. F. Gribakin

Positron binding in parabenzoquinone is studied using \textit{ab initio} many-body theory. The effects of electron-positron correlations including polarization, virtual positronium formation and positron-hole repulsion, as well as those of…

Chemical Physics · Physics 2025-02-17 S. K. Gregg , J. Hofierka , B. Cunningham , D. G. Green

In this paper we report first-principles calculations on the ground-state electronic structure of two infinite one-dimensional systems: (a) a chain of carbon atoms and (b) a chain of alternating boron and nitrogen atoms. Meanfield results…

Condensed Matter · Physics 2010-01-14 Ayjamal Abdurahman , Alok Shukla , Michael Dolg

The recently developed ab initio many-body theory of positron molecule binding [J. Hofierka et al., Nature, 606, 688 (2022)] is combined with the shifted pseudostates method [A. R. Swann and G. F. Gribakin, Phys. Rev. A 101, 022702 (2020)]…

Atomic Physics · Physics 2023-07-11 C. M. Rawlins , J. Hofierka , B. Cunningham , C. H. Patterson , D. G. Green

A many-body theory approach is developed for the problem of positron-atom scattering and annihilation. Strong electron-positron correlations are included non-perturbatively through the calculation of the electron-positron vertex function.…

Atomic Physics · Physics 2007-05-23 G. F. Gribakin , J. Ludlow

We present the positron coupled cluster singles and doubles (POS-CCSD) method to calculate positron binding energies in molecules. This framework treats electrons and positrons on an equal footing and includes up to simultaneous…

Chemical Physics · Physics 2026-03-23 Rosario R. Riso , Jan Haakon M. Trabski , Federico Rossi , Dermot Green , Henrik Koch

Positron scattering and annihilation on noble gas atoms below the positronium formation threshold is studied ab initio using many-body theory methods. The many-body theory provides a near-complete understanding of the…

Atomic Physics · Physics 2014-09-12 D. G. Green , J. A. Ludlow , G. F. Gribakin

Few-body correlations often express the distinguishing characteristic features of a many-body system. This thesis studies such correlations within dilute Bose-Einstein condensates in the case of arbitrary negative s-wave scattering length.…

Soft Condensed Matter · Physics 2007-05-23 H. H. Sorensen

We derive a general effective many-body theory for bosonic polar molecules in strong interaction regime, which cannot be correctly described by previous theories within the first Born approximation. The effective Hamiltonian has additional…

Other Condensed Matter · Physics 2008-05-08 Daw-Wei Wang

We present a formal derivation of the many-body perturbation theory for a system of electrons and bosons subject to a nonlinear electron-boson coupling. The interaction is treated at an arbitrary high order of bosons scattered. The…

Strongly Correlated Electrons · Physics 2018-08-15 Andrea Marini , Yaroslav Pavlyukh

In the author's previous works, it is derived from the Dirac equation that particles can have negative kinetic energy (NKE) solutions, and they should be treated on an equal footing as the positive kinetic energy (PKE) solutions. More than…

General Physics · Physics 2023-07-24 Huai-Yu Wang

We investigate an atomic ensemble of interacting bosons trapped in a symmetric double well potential in contact with a single tightly trapped ion which has been recently proposed [R. Gerritsma et al., Phys. Rev. Lett. 109, 080402 (2012)] as…

Quantum Gases · Physics 2016-06-08 J. M. Schurer , R. Gerritsma , P. Schmelcher , A. Negretti
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