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We present a comprehensive first-principles investigation of boron fullerenes and two-dimensional boron sheets, unified under a coordination-based framework. By classifying over a dozen boron nanostructures, including B$_{12}$, B$_{40}$,…

Materials Science · Physics 2025-07-10 Nevill Gonzalez Szwacki

We report on total-energy electronic-structure calculations in the density-functional theory performed for both monolayer and bilayer silicene on Ag(111) surfaces. The rt3 x rt3 structure observed experimentally and argued to be the…

Mesoscale and Nanoscale Physics · Physics 2014-04-15 Zhi-Xin Guo , Atsushi Oshiyama

Borophene (two-dimensional boron sheet) is a new type of two-dimensional material, which was recently grown successfully on single crystal Ag substrates. In this paper, we investigate the electronic structure and bonding characteristics of…

Mesoscale and Nanoscale Physics · Physics 2016-06-23 Bo Peng , Hao Zhang , Hezhu Shao , Yuanfeng Xu , Rongjun Zhang , Heyuan Zhu

Borophene, the boron atom analogue to graphene, being atomic thick have been just recently experimentally fabricated. In this work, we employ first-principles density functional theory calculations to investigate the interaction of Ca, Mg,…

Materials Science · Physics 2017-04-17 B Mortazavi , A Dianat , O Rahaman , G Cuniberti , T Rabczuk

High-level first-principles computations predict blue phosphorene bilayer to be a two-dimensional metal. This structure has not been considered before and was identified by employing a block-diagram scheme that yields the complete set of…

The structures, stability, mechanical and electronic properties of a-boron and its twined brother a*-boron have been studied by first-principles calculations. Both a-boron and a*-boron consist of equivalent icosahedra B12 clusters in…

Materials Science · Physics 2013-02-27 Chaoyu He , Jianxin Zhong

Two dimensional materials are attracting new research for optoelectronics and spintronics due to their unique physical properties. A wide range of emerging spintronic devices are achieved from parent and doped two dimensional materials.…

Materials Science · Physics 2023-09-15 S. Koley

Using a first-principles total energy methodology, we investigated the properties of graphene-like carbon mono and bilayers, functionalized with nitrogen and boron atoms. The resulting stable structures were explored in terms of their…

Materials Science · Physics 2019-09-12 B. Ipaves , J. F. Justo , L. V. C. Assali

In this work, we foresee the structure of a new class of borophenes with smaller 2D densities of atoms than those explored so far for 2D boron crystals. Boron atoms in the porous borophenes tend to be $5$-coordinated in contrast to commonly…

Materials Science · Physics 2021-11-25 T. Tarkowski , M. Marchwiany , N. Gonzalez Szwacki

Bilayer graphene nanoribbon with zigzag edge is investigated with the tight binding model. Two stacking structures, alpha and beta, are considered. The band splitting is seen in the alpha structure, while the splitting in the wave number…

Mesoscale and Nanoscale Physics · Physics 2012-03-13 Kikuo Harigaya , Hiroshi Imamura

A complex interplay between the crystal structure and electron behavior within borophene renders this material an intriguing 2D system with many of its electronic properties still undiscovered. Experimental insight into those properties is…

Two-dimensional (2D) materials as electrodes is believed to be the trend for future Li-ion and Na-ion batteries technologies. Here, by using first-principles methods, we predict that the recently reported borophene (2D born sheet) can serve…

Mesoscale and Nanoscale Physics · Physics 2016-10-19 Xiaoming Zhang , Junping Hu , Yingchun Cheng , Hui Ying Yang , Yugui Yao , Shengyuan A. Yang

We have performed a density functional theory study of the possible layered geometries occurring after dehydrogenation of a self-assembled monolayer (SAM) of biphenyl-thiol molecules (BPTs) adsorbed on a Au(111), as it has been…

Mesoscale and Nanoscale Physics · Physics 2011-11-10 Pepa Cabrera-Sanfelix , Andrés Arnau , Daniel Sánchez-Portal

Superconductivity in two-dimensional compounds is widely concerned, not only due to its application in constructing nano-superconducting devices, but also for the general scientific interests. Very recently, borophene (two-dimensional boron…

Superconductivity · Physics 2017-01-13 Miao Gao , Qi-Zhi Li , Xun-Wang Yan , Jun Wang

In this paper, we report a new boron nitride molecular structure called BN-nanobelt, an inorganic analog of (12) cyclophenacene synthesized in 2017. An extensive investigation using Density Functional Theory (DFT) and Quantum Molecular…

Materials Science · Physics 2022-01-03 Leonardo S. Barbosa , Bruna , C. C. de Almeida , Edvan Moreira , David L. Azevedo

Two-dimensional systems have strengthened their position as one of the key materials for novel applications. Very recently, boron joined the distinguished group of elements that are confirmed to possess 2D allotropes, named borophenes. In…

Materials Science · Physics 2021-09-21 N. Gonzalez Szwacki

Although many binary compounds have the B2 (CsCl-type) structure in the thermodynamic phase diagram, an origin of the structural stability is not understood well. Here, we focus on 416 compounds in the B2 structure extracted from the…

Materials Science · Physics 2021-11-02 Shota Ono , Daigo Kobayashi

We introduce two-dimensional borane, a single-layered material of BH stoichiometry, with promising electronic properties. We show that, according to Density Functional Theory calculations, two-dimensional borane is semimetallic, with two…

Materials Science · Physics 2017-12-01 Miguel Martinez-Canales , Timur R. Galeev , Alexander I. Boldyrev , Chris J. Pickard

The subcarbides B12C3 and B13C2 known for their abrasive properties, can be structurally considered as carbon inserted rhombohedral alpha-B12 and expressed as B12{C-C-C} and B12(C-B-C). Using density functional theory DFT computations, the…

Materials Science · Physics 2021-04-07 Samir F. Matar

Borophene, a monoatomic layer of boron atoms, stands out among two-dimensional (2D) materials, with its versatile properties of polymorphism, metallicity, plasmonics, superconductivity, tantalizing for physics exploration and…

Materials Science · Physics 2021-11-25 Qiyuan Ruan , Luqing Wang , Ksenia V. Bets , Boris I. Yakobson