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Ensembles of nitrogen-vacancy (NV) centers are used as sensors to detect NMR signals from micron-sized samples at room temperature. In this scenario, the regime of large magnetic fields is especially interesting as it leads to a large…

Quantum Physics · Physics 2023-04-04 C. Munuera-Javaloy , A. Tobalina , J. Casanova

Chemical shifts and J-couplings are fundamental parameters in NMR spectroscopy as they provide structural information about molecules. Extracting these quantities from isotopes such as carbon or nitrogen results in reduced sensitivity due…

Quantum Physics · Physics 2025-06-23 P. Alsina-Bolívar , J. Casanova

Advances in sensing devices that utilize nitrogen-vacancy (NV) center ensembles in diamond are driving progress in microscale nuclear magnetic resonance spectroscopy. Utilizing quantum sensing techniques in the high-field regime…

Quantum Physics · Physics 2025-10-22 Ainitze Biteri-Uribarren , Ana Martin , Jorge Casanova

Over the years, an enormous effort has been made to establish nitrogen vacancy (NV) centers in diamond as easily accessible and precise magnetic field sensors. However, most of their sensing protocols rely on the application of bias…

Diamond-based quantum sensors have enabled high-resolution NMR spectroscopy at the microscale in scenarios where fast molecular motion averages out dipolar interactions among target nuclei. However, in samples with low-diffusion, ubiquitous…

Quantum Physics · Physics 2025-08-26 Carlos Munuera-Javaloy , Ander Tobalina , Jorge Casanova

Nitrogen-vacancy (NV) centers in diamond have emerged as quantum sensors capable of detecting nuclear magnetic resonance (NMR) signals at unprecedented length scales, ranging from picoliter sample volumes down to single spins at the diamond…

Chemical Physics · Physics 2025-01-07 Nick R. von Grafenstein , Karl D. Briegel , Jorge Casanova , Dominik B. Bucher

The integration of NMR and high pressure technique brings unique opportunities to study electronic, structural and dynamical properties under extreme conditions. Despite a great degree of success has been achieved using coil-based schemes,…

Quantum Physics · Physics 2022-03-22 Yan-Xing Shang , Fang Hong , Jian-Hong Dai , Ya-Nan Lu , Hui Yu , Yong-Hong Yu , Xiao-Hui Yu , Xin-Yu Pan , Gang-Qin Liu

Nitrogen vacancy (NV) centers in diamond have been used as ultrasensitive magnetometers to perform nuclear magnetic resonance (NMR) spectroscopy of statistically polarized samples at 1 - 100 nm length scales. However, the spectral linewidth…

Quantum technologies have seen a rapid developmental surge over the last couple of years. Though often overshadowed by quantum computation, quantum sensors show tremendous potential for widespread applications in chemistry and biology. One…

Quantum Physics · Physics 2022-05-30 Robin D. Allert , Karl D. Briegel , Dominik B. Bucher

In recent years, the field of quantum sensing has garnered increasing attention due to its potential to revolutionize various scientific and technological domains. Among the different quantum sensors, the nitrogen-vacancy (NV) color center…

Quantum Physics · Physics 2024-10-01 C. Munuera-Javaloy

We present theoretical proposals for two-dimensional nuclear magnetic resonance spectroscopy protocols based on Nitrogen-vacancy (NV) centers in diamond that are strongly coupled to the target nuclei. Continuous microwave and…

Quantum Physics · Physics 2024-10-31 Matthias Kost , Jianming Cai , Martin B. Plenio

Nuclear magnetic resonance (NMR) schemes can be applied to micron-, and nanometer-sized samples by the aid of quantum sensors such as nitrogen-vacancy (NV) color centers in diamond. These minute devices allow for magnetometry of nuclear…

Quantum Physics · Physics 2021-07-19 C. Munuera-Javaloy , R. Puebla , J. Casanova

The nitrogen-vacancy (NV) centre in diamond has emerged as a candidate to non-invasively hyperpolarise nuclear spins in molecular systems to improve the sensitivity of nuclear magnetic resonance (NMR) experiments. Several promising proof of…

Mesoscale and Nanoscale Physics · Physics 2021-05-26 A. J. Healey , L. T. Hall , G. A. L. White , T. Teraji , M. -A. Sani , F. Separovic , J. -P. Tetienne , L. C. L. Hollenberg

Nanodiamonds containing nitrogen vacancy (NV-) centers show promise for a number of emerging applications including targeted in vivo imaging and generating nuclear spin hyperpolarization for enhanced NMR spectroscopy and imaging. Here, we…

After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

Sensing of signals from biological processes, such as action potential propagation in nerves, are essential for clinical diagnosis and basic understanding of physiology. Sensing can be performed electrically by placing sensor probes near or…

Nuclear magnetic resonance (NMR) imaging with shallow nitrogen-vacancy (NV) centers in diamond offers an exciting route toward sensitive and localized chemical characterization at the nanoscale. Remarkable progress has been made to combat…

Solid state defects such as nitrogen vacancy (NV) centers in diamond have been utilized for NMR sensing at ambient temperatures for samples at the nano-scale and up to the micro-scale. Similar to standard NMR, NV-sensitivities can be…

Quantum Physics · Physics 2026-01-28 Oliver T. Whaites , Jaime García Oliván , Jorge Casanova

The detection of individual molecules and their dynamics has been a long-standing challenge in the field of nanotechnology. In this work, we present a method that utilizes a nitrogen vacancy (NV) center and a dangling-bond on the diamond…

Quantum Physics · Physics 2023-12-15 A. Biteri-Uribarren , P. Alsina-Bolívar , C. Munuera-Javaloy , R. Puebla , J. Casanova

Nitrogen vacancy (NV) centers in diamond are atom-scale defects with long spin coherence times that can be used to sense magnetic fields with high sensitivity and spatial resolution. Typically, the magnetic field projection at a single…

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