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This is the first in a series of two papers investigating the effect of electron-phonon coupling in two-dimensional Fourier transformed electronic spectroscopy. We present a series of one- and two-dimensional nonlinear spectroscopic…

The last two decades experimentally affirmed the quantum nature of free electron wavepackets by the rapid development of transmission electron microscopes into ultrafast, quantum-coherent systems. In particular, ultrafast electron pulses…

Optics · Physics 2022-09-30 Roy Shiloh , Tomas Chlouba , Peter Hommelhoff

High-harmonic spectroscopy driven by circularly-polarized laser pulses and their counter-rotating second harmonic is a new branch of attosecond science which currently lacks quantitative interpretations. We extend this technique to the…

Atomic Physics · Physics 2019-09-04 Denitsa Baykusheva , Simon Brennecke , Manfred Lein , Hans Jakob Wörner

With the recently introduced particle interpretation of the double-slit experiment for light fields [Phys. Rev. Lett. 134, 13360 (2025)], all related interference phenomena can be reinterpreted in terms of light particle states that either…

Using a quantum wave packet simulation including the nuclear and electronic degrees of freedom, we investigate the femtosecond and picosecond energy- and angle-resolved photoelectron spectra of the E($^1\Sigma_g^+$) electronic state of…

Chemical Physics · Physics 2019-04-04 R. Chamakhi , R. Puthumpally-Joseph , M. Telmini , E. Charron

Quantum states are described by wave functions whose phases cannot be directly measured, but which play a vital role in quantum effects such as interference and entanglement. The loss of the relative phase information, termed decoherence,…

Chemical Physics · Physics 2019-12-20 Jia Chen , Cong Hu , John F. Stanton , Stephen Hill , Hai-Ping Cheng , Xiao-Guang Zhang

We propose a novel measurement technique capable of determining the temporal duration of an intense laser pulse directly in its focus at full intensity. We show that the electromagnetic radiation pattern emitted by an electron bunch with a…

Optics · Physics 2019-12-30 Felix Mackenroth , Amol R. Holkundkar

Advances in our ability to understand and utilize the world around us have always relied on the development of advanced tools for probing and manipulating materials properties. X-ray matter interactions played a critical role in the…

Materials Science · Physics 2021-08-13 Mariano Trigo , Mark P. M. Dean , David A. Reis

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

We show that combination of a linearly polarized resonant microwave field and a parallel static electric field may be used to create a non-dispersive electronic wavepacket in Rydberg atoms. The static electric field allows for manipulation…

Quantum Physics · Physics 2007-05-23 Dominique Delande , Krzysztof Sacha , Jakub Zakrzewski

Long-lived particles (LLPs) are particles that are stable or that live long enough for their decays to be experimentally distinguishable in time or position from their production point. We provide an overview of the phenomenology and…

High Energy Physics - Phenomenology · Physics 2025-11-25 Laura Jeanty , Brian Shuve

Among polycyclic aromatic hydrocarbons, pyrene is widely used as an optical probe thanks to peculiar ultraviolet absorption and infrared emission features. Interestingly, this molecule is also an abundant component of the interstellar…

Chemical Physics · Physics 2021-11-19 Katherine R. Herperger , Jannis Krumland , Caterina Cocchi

Recent technological advances allowed the coherent optical manipulation of high-energy electron wavepackets with attosecond precision. Here we theoretically investigate the collision of optically-modulated pulsed electron beams with atomic…

Atomic Physics · Physics 2021-04-21 Yuya Morimoto , Peter Hommelhoff , Lars Bojer Madsen

Quantum coherence is highly involved in photochemical functioning of complex molecular systems. Co-existence and intermixing of electronic and/or vibrational coherences, while never unambiguously identified experimentally, has been proposed…

The rates and outcomes of virtually all photophysical and photochemical processes are determined by Conical Intersections. These are regions of degeneracy between electronic states on the nuclear landscape of molecules where electrons and…

Chemical Physics · Physics 2022-05-25 Daniel Keefer , Thomas Schnappinger , Regina de Vivie-Riedle , Shaul Mukamel

The phase shift's influence of two strong pulsed laser waves on effective interaction of electrons was studied. Considerable amplification of electrons repulsion in the certain range of phase shifts and waves intensities is shown. That…

Classical Physics · Physics 2017-06-12 S. S. Starodub , S. P. Roshchupkin , V. V. Dubov

We introduce and experimentally demonstrate a method, where the two intrinsic time scales of a molecule, the slow nuclear motion and the fast electronic motion, are simultaneously measured in a photo-electron photo-ion coincidence…

Irradiation of a molecular system by an intense laser field can trigger dynamics of both electronic and nuclear subsystems. The lighter electrons usually move on much faster, attosecond time scale but the slow nuclear rearrangement damps…

Chemical Physics · Physics 2020-08-26 Nikolay V. Golubev , Tomislav Begušić , Jiří Vaníček

Recently we reported a series of numerical simulations proving that it is possible in principle to create an electronic wave packet and subsequent electronic motion in a neutral molecule photoexcited by a UV pump pulse within a few…

Atomic and Molecular Clusters · Physics 2016-10-24 P. Decleva , N. Quadri , A. Perveaux , D. Lauvergnat , F. Gatti , B. Lasorne , G. J. Halász , Á. Vibók

Light-induced molecular dynamics often involve the excitation of several electronic, vibrational, and rotational states. Since the ensuing electronic and nuclear motion determines the pathways and outcomes of photoinduced reactions, our…

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