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Metal nanoparticles are attractive for plasmon-enhanced generation of hot carriers, which may be harnessed in photochemical reactions. In this work, we analyze the coherent femtosecond dynamics of photon absorption, plasmon formation, and…

Mesoscale and Nanoscale Physics · Physics 2021-01-14 Tuomas P. Rossi , Paul Erhart , Mikael Kuisma

Hot electrons generated from the decay of localized surface plasmons in metallic nanostructures have the potential to transform photocatalysis, photodetection and other optoelectronic applications. However, the understanding of hot-carrier…

Hot electrons and holes generated from the decay of localized surface plasmons in metallic nanoparticles can be harnessed for applications in solar energy conversion and sensing. In this paper, we study the generation of hot carriers in…

Mesoscale and Nanoscale Physics · Physics 2024-02-09 Shreyas Ramachandran , Simao Joao , Hanwen Jin , Johannes Lischner

Hot electrons and holes generated from the decay of localized surface plasmons (LSPs) in aluminum nanostructures have significant potential for applications in photocatalysis, photodetection and other optoelectronic devices. Here, we…

Optics · Physics 2025-11-03 Gengyue Dong , Simão João , Hanwen Jin , Johannes Lischner

Metal alloys hold the promise of providing hot carrier generation distributions superior to pure metals in applications such as sensing, catalysis and solar energy harvesting. Guidelines for finding the optimal alloy configuration for a…

Materials Science · Physics 2024-02-20 Matej Bubaš , Jordi Sancho-Parramon

Nanoscale localization of electromagnetic fields near metallic nanostructures underpins the fundamentals and applications of plasmonics. The unavoidable energy loss from plasmon decay, initially seen as a detriment, has now expanded the…

In plasmonics, and particularly in plasmonic photochemistry, the effect of hot-electron generation is an exciting phenomenon driving new fundamental and applied research. However, obtaining a microscopic description of the hot-electron…

Understanding and controlling properties of plasmon-induced hot carriers is a key step towards next-generation photovoltaic and photocatalytic devices. Here, we uncover a route to engineering hot-carrier generation rates of silver…

Materials Science · Physics 2021-01-26 Lara Román Castellanos , Ortwin Hess , Johannes Lischner

Hot carriers produced from the decay of localized surface plasmons in metallic nanoparticles are intensely studied because of their optoelectronic, photovoltaic and photocatalytic applications. From a classical perspective, plasmons are…

Mesoscale and Nanoscale Physics · Physics 2019-04-09 Lara Román Castellanos , Ortwin Hess , Johannes Lischner

Harnessing non-equilibrium hot carriers from plasmonic metal nanostructures constitutes a vibrant research field. It promises to enable control of activity and selectivity of photochemical reactions, especially for solar fuel generation.…

Harnessing hot electrons and holes resulting from the decay of localized surface plasmons in nanomaterials has recently led to new devices for photovoltaics, photocatalysis and optoelectronics. Properties of hot carriers are highly tunable…

Materials Science · Physics 2018-02-15 Stefano Dal Forno , Luigi Ranno , Johannes Lischner

We present a quantum-mechanical model for surface-assisted carrier excitation by optical fields in plasmonic nanostructures of arbitrary shape. We derive an explicit expression, in terms of local fields inside the metal structure, for…

Mesoscale and Nanoscale Physics · Physics 2019-04-15 Tigran V. Shahbazyan

Surface plasmon mediated hot carrier generation is widely utilized for the manipulation of the electron-photon interactions in many types of optoelectronic devices including solar cells, photodiodes, and optical modulators. A diversity of…

The coherent oscillations of mobile charge carriers near the surface of good conductors-surface plasmons-are been exploited in many applications in information technologies, clean energy, high-density data storage, photovoltaics, chemistry,…

Mesoscale and Nanoscale Physics · Physics 2023-12-20 Jacob Khurgin , Anton Yu. Bykov , Anatoly V. Zayats

Understanding the interplay between illumination and the electron distribution in metallic nanostructures is a crucial step towards developing applications such as plasmonic photo-catalysis for green fuels, nano-scale photo-detection and…

Optics · Physics 2019-07-23 Yonatan Dubi , Yonatan Sivan

We theoretically investigate equilibrium behaviors and photothermal effects of a flexible plasmonic metamaterial composed of aramid nanofibers and gold nanoparticles. The fiber matrix is considered as an external field to reconfigure a…

Mesoscale and Nanoscale Physics · Physics 2020-11-12 Anh D. Phan , Vu D. Lam , Katsunori Wakabayashi

Bimetallic nanoreactors in which a plasmonic metal is used to funnel solar energy towards a catalytic metal have recently been studied experimentally, but a detailed theoretical understanding of these systems is lacking. Here, we present…

Materials Science · Physics 2023-12-19 Hanwen Jin , Matias Herran , Emiliano Cortes , Johannes Lischner

While direct hot-carrier transfer can increase photo-catalytic activity, it is difficult to discern experimentally and competes with several other mechanisms. To shed light on these aspects, here, we model from first principles hot-carrier…

Mesoscale and Nanoscale Physics · Physics 2023-11-20 Jakub Fojt , Tuomas P Rossi , Paul Erhart

Metal photocathodes are an important source of high-brightness electron beams, ubiquitous in the operation of both large-scale accelerators and table-top microscopes. When the surface of a metal is nano-engineered with patterns on the order…

Aluminum nanostructures have recently been at the focus of numerous studies due to their properties including oxidation stability and surface plasmon resonances covering the ultraviolet and visible spectral windows. In this article, we…

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