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Molecular exciton polaritons are hybrid states resulting from the strong coupling of molecular electronic excitations with an optical cavity mode, presenting a promising approach for controlling photophysical and photochemical properties in…

Chemical Physics · Physics 2025-03-04 Nguyen Thanh Phuc

We present a general method by which linear quantum Hamiltonian dynamics with exponentially many degrees of freedom is replaced by approximate classical nonlinear dynamics with the number of degrees of freedom (phase space dimensionality)…

Quantum Physics · Physics 2018-08-01 Jonathan Wurtz , Anatoli Polkovnikov , Dries Sels

We introduce the parafermionic truncated Wigner approximation ($p$TWA), a semiclassical phase-space framework for simulating the nonequilibrium dynamics of lattice systems with fractional exchange statistics. The method extends truncated…

Strongly Correlated Electrons · Physics 2026-04-01 Javad Vahedi , Martin Garttner

We study the out-of-equilibrium dynamics of ultracold bosons in a double- and triple-well potential within the Bose-Hubbard model by means of the semiclassical Herman-Kluk propagator and compare the results to the frequently applied…

Quantum Physics · Physics 2015-06-19 Lena Simon , Walter T. Strunz

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

Polaritons have gained significant attention for the tantalizing possibility of modifying chemical properties and dynamics by coupling molecules to resonant cavity modes to create hybrid light-matter quantum states. Herein, we implement the…

Chemical Physics · Physics 2025-06-24 Scott M. Garner , Xiaosong Li , Sharon Hammes-Schiffer

We develop and utilize the SU(3) truncated Wigner approximation (TWA) in order to analyze far-from-equilibrium quantum dynamics of strongly interacting Bose gases in an optical lattice. Specifically, we explicitly represent the…

Quantum Gases · Physics 2021-11-22 Kazuma Nagao , Yosuke Takasu , Yoshiro Takahashi , Ippei Danshita

Quench dynamics in a two-dimensional system of interacting fermions is analyzed within the semiclassical truncated Wigner approximation (TWA). The models with short-range and long-range interactions are considered. We show that in the…

Quantum Gases · Physics 2021-01-01 Adam S. Sajna , Anatoli Polkovnikov

We present a systematic approach for the semiclassical treatment of many-body dynamics of interacting, open spin systems. Our approach overcomes some of the shortcomings of the recently developed discrete truncated Wigner approximation…

Quantum Physics · Physics 2022-12-01 Christopher D. Mink , David Petrosyan , Michael Fleischhauer

Recent experiments have demonstrated that polariton formation provides a novel strategy for modifying local molecular processes when a large ensemble of molecules is confined within an optical cavity. Herein, a numerical strategy based on…

Chemical Physics · Physics 2025-05-16 Andres Felipe Bocanegra Vargas , Tao E. Li

We study a quantum many-body variant of the parametric oscillator, by investigating the driven sine-Gordon model with a modulated tunnel coupling via a semi-classical Truncated Wigner Approximation (TWA). We first analyze the parametric…

Although highly successful, the Truncated Wigner Approximation (TWA) does not account for genuine many-body quantum interference between different solutions of the mean-field equations of a bosonic many-body (MB) system. This renders the…

Quantum Gases · Physics 2022-09-07 Quirin Hummel , Peter Schlagheck

Although highly successful, the truncated Wigner approximation (TWA) leaves out many-body quantum interference between mean-field Gross-Pitaevskii solutions as well as other quantum effects, and is therefore essentially classical. Turned…

Quantum Gases · Physics 2019-11-27 Peter Schlagheck , Denis Ullmo , Juan Diego Urbina , Klaus Richter , Steven Tomsovic

We apply the semi-classical limit of the generalized $SO(3)$ map for representation of variable-spin systems in a four-dimensional symplectic manifold and approximate their evolution terms of effective classical dynamics on $T^{\ast…

The spectral and temporal response of a set of $N$ quantum emitters embedded in a photonic cavity is studied. Quantum mechanically, such systems can be described by the Tavis-Cummings (TC) model of $N$ two-level systems coupled to a single…

Mesoscale and Nanoscale Physics · Physics 2021-11-24 K. Jürgens , F. Lengers , D. Groll , D. E. Reiter , D. Wigger , T. Kuhn

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…

Quantum Physics · Physics 2025-01-14 Thomas Schnappinger , Cyril Falvo , Markus Kowalewski

A theoretical framework is presented for the computation of rovibrational polaritonic states of a molecule in a lossless infrared (IR) microcavity. In the proposed approach the quantum treatment of the rotational and vibrational motion of…

Chemical Physics · Physics 2023-10-30 Tamás Szidarovszky
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