English
Related papers

Related papers: Free-energy estimates from nonequilibrium trajecto…

200 papers

The work fluctuations of a harmonic oscillator in contact with a thermostat and driven out of equilibrium by an external force are studied experimentally. For the work both the transient and stationary state fluctuation theorems hold. The…

Statistical Mechanics · Physics 2016-08-14 Sylvain Joubaud , Nicolas Garnier , Frédéric Douarche , Artem Petrosyan , Sergio Ciliberto

Statistical properties of Brownian motion that arise by analyzing, separately, trajectories over which the system energy increases (upside) or decreases (downside) with respect to a threshold energy level, are derived. This selective…

Statistical Mechanics · Physics 2019-08-02 Galen T. Craven , Abraham Nitzan

It is shown that the work fluctuations and work distribution functions are fundamentally different in systems with short-range versus long-range correlations. The two cases considered with long- range correlations are magnetic work…

Statistical Mechanics · Physics 2017-07-26 T. R. Kirkpatrick , J. K. Bhattacherjee , J. V. Sengers

Determining the work which is supplied to a system by an external agent, provides a crucial step in any experimental realization of transient fluctuation relations. This, however, poses a problem for quantum systems, where the standard…

Statistical Mechanics · Physics 2014-05-15 Gentaro Watanabe , B. Prasanna Venkatesh , Peter Talkner

Nonequilibrium work-Hamiltonian connection for a microstate plays a central role in diverse branches of statistical thermodynamics (fluctuation theorems, quantum thermodynamics, stochastic thermodynamics, etc.). We show that the change in…

Statistical Mechanics · Physics 2017-02-03 P. D. Gujrati

In open quantum systems, a clear distinction between work and heat is often challenging, and extending the quantum Jarzynski equality to systems evolving under general quantum channels beyond unitality remains an open problem in quantum…

Quantum Physics · Physics 2020-08-10 Akira Sone , Yi-Xiang Liu , Paola Cappellaro

It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions…

Quantum Physics · Physics 2018-06-14 Harry J. D. Miller , Janet Anders

The difference Delta F between free energies has applications in biology, chemistry, and pharmacology. The value of Delta F can be estimated from experiments or simulations, via fluctuation theorems developed in statistical mechanics.…

Statistical Mechanics · Physics 2016-06-03 Nicole Yunger Halpern , Christopher Jarzynski

We present a derivation of the Jarzynski identity and the Crooks fluctuation theorem for systems governed by deterministic dynamics that conserves the canonical distribution such as Hamiltonian dynamics, Nose-Hoover dynamics, Nose-Hoover…

Statistical Mechanics · Physics 2009-11-11 Elisabeth Scholl-Paschinger , Christoph Dellago

Calculating free energy differences is a topic of substantial interest and has many applications including molecular docking and hydration, solvation, and binding free energies which is used in computational drug discovery. However, in…

Chemical Physics · Physics 2013-10-16 Asaf Farhi

We study the thermodynamics of quantum projective measurements by using the set up for the Jarzynski equality. We prove the fluctuations of energy change induced by measurements satisfy the Jarzynski equality, revealing that the quantum…

Statistical Mechanics · Physics 2015-08-31 Juyeon Yi , Yong Woon Kim

This article sets up a formalism to describe stochastic thermodynamics for driven out-of-equilibrium open quantum systems. A stochastic Schr\"odinger equation allows to construct quantum trajectories describing the dynamics of the system…

Statistical Mechanics · Physics 2016-10-17 Cyril Elouard , Alexia Auffèves , Maxime Clusel

In recent years a quantum information theoretic framework has emerged for incorporating non-classical phenomena into fluctuation relations. Here we elucidate this framework by exploring deviations from classical fluctuation relations…

Quantum Physics · Physics 2021-12-09 Zoe Holmes , Erick Hinds Mingo , Calvin Y. -R. Chen , Florian Mintert

A central endeavor of thermodynamics is the measurement of free energy changes. Regrettably, although we can measure the free energy of a system in thermodynamic equilibrium, typically all we can say about the free energy of a…

Statistical Mechanics · Physics 2012-04-10 David A. Sivak , Gavin E. Crooks

In this paper we study computationally feasible bounds for relative free energies between two many-particle systems. Specifically, we consider systems out of equilibrium that do not necessarily satisfy a fluctuation-dissipation relation,…

Statistical Mechanics · Physics 2024-03-19 Luigi Delle Site , Carsten Hartmann

We study the motion of an overdamped colloidal particle in a time-dependent non-harmonic potential. We demonstrate the first law-like balance between applied work, exchanged heat, and internal energy on the level of a single trajectory. The…

Statistical Mechanics · Physics 2007-05-23 V. Blickle , T. Speck , L. Helden , U. Seifert , C. Bechinger

The two-time measurement scheme is well studied in the context of quantum fluctuation theorem. However, it becomes infeasible when the random variable determined by a single measurement trajectory is associated with the von-Neumann entropy…

Quantum Physics · Physics 2023-04-20 Akira Sone , Naoki Yamamoto , Tharon Holdsworth , Prineha Narang

The past twenty years have seen a resurgence of interest in nonequilibrium thermodynamics, thanks to advances in the theory of stochastic processes and in their thermodynamic interpretation. Fluctuation theorems provide fundamental…

Statistical Mechanics · Physics 2017-11-16 Robert Marsland , Jeremy England

The formation and transition of patterns of two-dimensional turbulent flows observed in various geophysical systems are commonly explained in terms of statistical mechanics. Different from ordinary systems, for a two-dimensional flow, the…

Fluid Dynamics · Physics 2023-01-11 Yohei Onuki

Energy-based models (EBMs) are generative models inspired by statistical physics with a wide range of applications in unsupervised learning. Their performance is best measured by the cross-entropy (CE) of the model distribution relative to…

Machine Learning · Computer Science 2023-12-14 Davide Carbone , Mengjian Hua , Simon Coste , Eric Vanden-Eijnden