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We investigate the interaction of ground and excited states of a silver atom with noble gases (NG), including helium. Born-Oppenheimer potential energy curves are calculated with quantum chemistry methods and spin-orbit effects in the…

Chemical Physics · Physics 2015-06-12 J. Loreau , H. R. Sadeghpour , A. Dalgarno

In this study, we reexamine a recent optimal control simulation targeting the preparation of a superposition of two excited electronic states in the UV range in a complex molecular system. We revisit this control from the perspective of…

Quantum Physics · Physics 2023-12-20 Amine Jaouadi , Etienne Mangaud , Michèle Desouter-Lecomte

We report on accurate variational calculations of the Born-Oppenheimer potential for excited states of the hydrogen molecule with $\Pi$, $\Delta$, and $\Phi$ symmetries. The obtained potential energy curves reach the relative precision of…

Atomic Physics · Physics 2023-01-11 Michał Siłkowski , Krzysztof Pachucki

We derive the exact reduced density matrix for the electrons in an analytically solvable electron-phonon model. Here, the electrons are described as a Luttinger liquid that is coupled to Einstein phonons. We further derive analytical…

Strongly Correlated Electrons · Physics 2022-11-23 Gergő Roósz , Karsten Held

We present a computationally efficient framework for predicting the excited-state properties of thermally activated delayed fluorescence (TADF) emitters, integrating extended tight-binding (\xtb), simplified Tamm-Dancoff approximation…

The ground state of an homogeneous electron gas is a paradigmatic state that has been used to model and predict the electronic structure of matter at equilibrium for nearly a century. For half a century, it has been successfully used to…

Chemical Physics · Physics 2024-06-11 Tim Gould , Stefano Pittalis

In this paper, we investigate the second and third pseudo R\'enyi entanglement entropies (PREE) for a locally excited state $| \psi \rangle $ and its time evolution $| \phi \rangle = e^{- i H t} | \psi \rangle$ in a two-dimensional…

High Energy Physics - Theory · Physics 2023-09-28 Farzad Omidi

Eigenvector continuation (EC) has recently attracted a lot attention in nuclear structure and reactions as a variational resummation tool for many-body expansions. While previous applications focused on ground-state energies, excited states…

Nuclear Theory · Physics 2022-06-09 Margarida Companys Franzke , Alexander Tichai , Kai Hebeler , Achim Schwenk

Large-scale calculations of the E1 strength are performed within the random phase approximation (RPA) based on the relativistic point-coupling mean field approach in order to derive the radiative neutron capture cross sections for all…

Nuclear Theory · Physics 2015-06-11 I. Daoutidis , S. Goriely

Intense few-to-sub-femtosecond soft x-ray pulses can produce neutral, two-site excited double-core-hole states by promoting two core electrons to the same unoccupied molecular orbital. We theoretically investigate double nitrogen K-edge…

Chemical Physics · Physics 2023-06-28 Adam E. A. Fouda , Dimitris Koulentianos , Linda Young , Gilles Doumy , Phay J. Ho

Many recent applications of time-dependent density functional theory begin in an initially excited state, and propagate it using an adiabatic approximation for the exchange-correlation potential. This however inserts the excited-state…

Chemical Physics · Physics 2012-04-02 Peter Elliott , Neepa T. Maitra

We discuss an expansion of the detection probabilities of biphoton states in terms of increasing orders of the joint spectral amplitude. The expansion enables efficient time- or frequency-resolved numerical simulations involving quantum…

Quantum Physics · Physics 2024-12-03 Philipp Kleinpaß , Thomas Walther , Erik Fitzke

We propose a relaxation time approximation for the description of the dynamics of strongly excited fermion systems. Our approach is based on time-dependent density functional theory at the level of the local density approximation. This…

Atomic and Molecular Clusters · Physics 2016-01-26 P. -G. Reinhard , E. Suraud

We propose a state-averaged orbital optimization scheme for improving the accuracy of excited states of the electronic structure Hamiltonian for use on near-term quantum computers. Instead of parameterizing the orbital rotation operator in…

Chemical Physics · Physics 2024-04-09 Joel Bierman , Yingzhou Li , Jianfeng Lu

The observation of neutron star mergers with gravitational waves (GWs) has provided a new method to constrain the dense-matter equation of state (EOS) and to better understand its nuclear physics. However, inferring nuclear microphysics…

High Energy Astrophysical Phenomena · Physics 2026-03-20 Brendan T. Reed , Cassandra L. Armstrong , Rahul Somasundaram , Duncan A. Brown , Collin Capano , Soumi De , Ingo Tews

We study the entanglement R\'{e}nyi $\alpha$-entropy (ER$\alpha $E) as the measure of entanglement. Instead of a single quantity in standard entanglement quantification for a quantum state by using the von Neumann entropy for the…

Quantum Physics · Physics 2016-02-24 Yu-Xin Wang , Liang-Zhu Mu , Vlatko Vedral , Heng Fan

Excited electronic states of molecules and solids play a fundamental role in fields such as catalysis and electronics. In electronic structure calculations, excited states typically correspond to saddle points on the surface described by…

178m2-Hf is an extremely interesting isomeric state due to its potential energy capacity level. One possible way to obtain it is by irradiation of a nat-Ta sample with a high-current proton accelerator. Up to now, there was no information…

We report a leading-order calculation of radiative ${}^{7}\mathrm{Li}$ neutron captures to both the ground and first excited state of ${}^{8}\mathrm{Li}$ in the framework of a low-energy effective field theory (Halo-EFT). Each of the…

Nuclear Theory · Physics 2014-03-05 Xilin Zhang , Kenneth M. Nollett , D. R. Phillips

In the environment of a hot plasma, as achieved in stellar explosions, capture and photodisintegration reactions proceeding on excited states in the nucleus can considerably contribute to the astrophysical reaction rate. Such reaction rates…

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