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Hydrogen diffusion in metals and alloys plays an important role in the discovery of new materials for fuel cell and energy storage technology. While analytic models use hand-selected features that have clear physical ties to hydrogen…

Materials Science · Physics 2023-10-30 Grace M. Lu , Matthew Witman , Sapan Agarwal , Vitalie Stavila , Dallas R. Trinkle

Understanding and accurately predicting hydrogen diffusion in materials is challenging due to the complex interactions between hydrogen defects and the crystal lattice. These interactions span large length and time scales, making them…

The reported diffusion constants for hydrogen in silicon vary over six orders of magnitude. This spread in measured values is caused by the different concentrations of defects in the silicon that has been studied. Hydrogen diffusion is…

In recent years, metal hydride research has become one of the driving forces of the high-pressure community, as it is believed to hold the key to superconductivity close to ambient temperature. While numerous novel metal hydride compounds…

Garnet has been widely used to decipher the pressure-temperature-time history of rocks, but its physical properties such as elasticity and diffusion are strongly affected by trace amounts of hydrogen. Experimental measurements of H…

Materials Science · Physics 2025-02-17 Xin Zhong , Felix Höfling , Timm John

Hydrogen diffusion is critical to the performance of metals for hydrogen storage as well as other important applications. As compared to its crystalline counterpart which follows the Arrhenius relation, hydrogen diffusion in amorphous…

Materials Science · Physics 2023-10-25 Chunguang Tang , Gang Sun , Yun Liu

Thermal conductivity of the lowermost mantle governs the heat flow out of the core energizing planetary-scale geological processes. Yet, there are no direct experimental measurements of thermal conductivity at relevant pressure-temperature…

MgSiO_3-perovskite (MgPv) plays a crucial role in the Earth's lower mantle. This study combines deep-learning potential (DP) with density functional theory (DFT) to investigate the structural and elastic properties of MgPv under lower…

Geophysics · Physics 2023-08-21 Tianqi Wan , Chenxing Luo , Yang Sun , Renata M. Wentzcovitch

Deep saline aquifers are one of the best options for large-scale and long-term hydrogen storage. Predicting the diffusion coefficient of hydrogen molecules at the conditions of saline aquifers is critical for modelling hydrogen storage. The…

The Earth's mantle transition zone (MTZ) is widely recognized as a major water reservoir, exerting significant influence on the planet's water budget and deep cycling processes. Here, we employ crystal structure prediction and…

Geophysics · Physics 2025-11-05 Zifan Wang , Yu He , Ho-kwang Mao , Duck Young Kim

New X-ray and neutron diffraction experiments have been performed on ethanol-water mixtures as a function of decreasing temperature, so that such diffraction data are now available over the entire composition range. Extensive molecular…

Soft Condensed Matter · Physics 2021-08-05 Szilvia Pothoczki , Ildikó Pethes , László Pusztai , László Temleitner , Koji Ohara , Imre Bakó

The United States Department of Energy (DOE) has set ambitious targets for hydrogen storage materials for onboard light-duty cars which are to be achieved by 2027. One of the major problems in solid hydrogen storage materials is the…

Materials Science · Physics 2023-12-12 Sourabh Singha , Abhijit Chatterjee

Iron disproportionation reactions in mantle silicates can produce metallic iron that drives Earth's deep mantle toward metal saturation under reduced conditions. Subducting slabs transport hydrated silicates to these depths, where…

Geophysics · Physics 2026-05-13 Junjie Dong , Lars P Stixrude , Paul D Asimow , Jie Li

The diffusivity of hydrogen in cold-rolled pure iron is investigated using permeation and desorption methods. Electrochemical charging, electro-permeation and thermal desorption spectroscopy (TDS) experiments are conducted. Firstly, the…

Materials Science · Physics 2021-12-02 A. Zafra , Z. Harris , C. Sun , E. Martínez-Pañeda

Hydrous minerals contribute largely to the transport and distribution of water into the mantle of earth to regulate the process of deep-water cycle. Brucite is one of the simplest layered dense hydrous mineral belonging to MgO-SiO2-H2O…

Materials Science · Physics 2023-09-12 Sudip Kumar Mondal , Pratik Kumar Das , Nibir Mandal

The efficiency of silicon solar cells gradually decreases in various environments, with humidity being a key factor contributing to this decline through moisture-induced degradation (MID) involving multiple mechanisms including encapsulant…

Materials Science · Physics 2026-03-13 Bo Li , Feifei Zhang , Yu Pang , Jinyu Hu , Huiyan Zhao , Guocai Liu , Chao He , Xingtao An

We investigate the optical properties of hydrogen as it undergoes a transition from the insulating molecular to the metallic atomic phase, when heated by a pulsed laser at megabar pressures in a diamond anvil cell. Most current experiments…

Materials Science · Physics 2016-04-20 N. Van den Broeck , F. Brosens , J. Tempere , I. F. Silvera

Hydrogen diffusion on metals exhibits rich quantum behavior, which is not yet fully understood. Using simulations, we show that many hydrogen diffusion barriers can be categorized into those with "parabolic-tops" and those with…

Chemical Physics · Physics 2017-10-11 W. Fang , J. O. Richardson , J. Chen , X. -Z. Li , A. Michaelides

Diffusion of atomic and molecular hydrogen in the interstitial space between graphite sheets has been studied by molecular dynamics simulations. Interatomic interactions were modeled by a tight-binding potential fitted to density-functional…

Materials Science · Physics 2011-08-12 Carlos P. Herrero , Rafael Ramirez

The transition to a low-carbon economy demands efficient and sustainable energy-storage solutions, with hydrogen emerging as a promising clean-energy carrier and with metal hydrides recognized for their hydrogen-storage capacity. Here, we…

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