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Density estimation is a fundamental task in statistics and machine learning applications. Kernel density estimation is a powerful tool for non-parametric density estimation in low dimensions; however, its performance is poor in higher…

Machine Learning · Computer Science 2022-08-08 Joseph A. Gallego , Fabio A. González

We investigate bulk structural properties of tetravalent associating particles within the framework of classical density functional theory, building upon Wertheim's thermodynamic perturbation theory. To this end, we calculate density…

Soft Condensed Matter · Physics 2021-12-08 Daniel Stopper , Frank Hirschmann , Martin Oettel , Roland Roth

Machine learning is a powerful tool to design accurate, highly non-local, exchange-correlation functionals for density functional theory. So far, most of those machine learned functionals are trained for systems with an integer number of…

A density matrix describes the statistical state of a quantum system. It is a powerful formalism to represent both the quantum and classical uncertainty of quantum systems and to express different statistical operations such as measurement,…

Machine Learning · Computer Science 2024-05-01 Fabio A. González , Alejandro Gallego , Santiago Toledo-Cortés , Vladimir Vargas-Calderón

One central theme in machine learning is function estimation from sparse and noisy data. An example is supervised learning where the elements of the training set are couples, each containing an input location and an output response. In the…

Machine Learning · Computer Science 2023-10-05 Alberto Giaretta , Mauro Bisiacco , Gianluigi Pillonetto

Spherically-symmetric atom-centered descriptors of atomic environments have been widely used for constructing potential or free energy surfaces of atomistic and colloidal systems and to characterize local structures using machine learning…

Soft Condensed Matter · Physics 2022-07-27 Gerardo Campos-Villalobos , Giuliana Giunta , Susana Marín-Aguilar , Marjolein Dijkstra

The fundamental measure density functional theory for hard spheres is generalized to binary mixtures of arbitrary positive and moderate negative non-additivity between unlike components. In bulk the theory predicts fluid-fluid phase…

Soft Condensed Matter · Physics 2009-11-10 Matthias Schmidt

We use machine learning methods to approximate a classical density functional. As a study case, we choose the model problem of a Lennard Jones fluid in one dimension where there is no exact solution available and training data sets must be…

Soft Condensed Matter · Physics 2019-03-04 Shang-Chun Lin , Martin Oettel

A geometry-based density functional theory is presented for mixtures of hard spheres, hard needles and hard platelets; both the needles and the platelets are taken to be of vanishing thickness. Geometrical weight functions that are…

Soft Condensed Matter · Physics 2009-11-11 Ansgar Esztermann , Hendrik Reich , Matthias Schmidt

Patchy particles are a popular paradigm for the design and synthesis of nanoparticles and colloids for self-assembly. In "traditional" patchy particles, anisotropic interactions arising from patterned coatings, functionalized molecules,…

Soft Condensed Matter · Physics 2014-02-18 Greg van Anders , N. Khalid Ahmed , Ross Smith , Michael Engel , Sharon C. Glotzer

Fluid flow around a random distribution of stationary spherical particles is a problem of substantial importance in the study of dispersed multiphase flows. In this paper we present a machine learning methodology using Generative…

Fluid Dynamics · Physics 2021-11-02 B. Siddani , S. Balachandar , W. C. Moore , Y. Yang , R. Fang

We present a hybrid scheme based on classical density functional theory and machine learning for determining the equilibrium structure and thermodynamics of inhomogeneous fluids. The exact functional map from the density profile to the…

Soft Condensed Matter · Physics 2023-12-12 Florian Sammüller , Sophie Hermann , Daniel de las Heras , Matthias Schmidt

Modern machine learning systems are increasingly trained on large amounts of data embedded in high-dimensional spaces. Often this is done without analyzing the structure of the dataset. In this work, we propose a framework to study the…

Machine Learning · Computer Science 2023-04-27 Carlos Hurtado , Sarath Shekkizhar , Javier Ruiz-Hidalgo , Antonio Ortega

Machine-learning models based on a point-cloud representation of a physical object are ubiquitous in scientific applications and particularly well-suited to the atomic-scale description of molecules and materials. Among the many different…

Chemical Physics · Physics 2023-03-08 Filippo Bigi , Sergey N. Pozdnyakov , Michele Ceriotti

Density estimation is a crucial component of many machine learning methods, and manifold learning in particular, where geometry is to be constructed from data alone. A significant practical limitation of the current density estimation…

Classical Analysis and ODEs · Mathematics 2016-01-06 Tyrus Berry , Timothy Sauer

Accurate description of deformed atomic nuclei by the orbital-free density functional theory has been a longstanding textbook challenge, due to the difficulty in accounting for the intricate quantum shell effects that are present in such…

Nuclear Theory · Physics 2024-12-31 X. H. Wu , Z. X. Ren , P. W. Zhao

We aim at estimating in a non-parametric way the density $\pi$ of the stationary distribution of a $d$-dimensional stochastic differential equation $(X_t)_{t \in [0, T]}$, for $d \ge 2$, from the discrete observations of a finite sample…

Statistics Theory · Mathematics 2022-12-29 Chiara Amorino , Arnaud Gloter

Kernel-based methods offer a powerful and flexible mathematical framework for addressing histopolation problems. In histopolation, the available input data does not consist of pointwise function samples but of averages taken over intervals…

Numerical Analysis · Mathematics 2026-01-14 Ludovico Bruni Bruno , Giacomo Cappellazzo , Wolfgang Erb , Mohammad Karimnejad Esfahani

A unified formulation of the density functional theory is constructed on the foundations of entropic inference in both the classical and the quantum regimes. The theory is introduced as an application of entropic inference for inhomogeneous…

Statistical Mechanics · Physics 2021-12-20 Ahmad Yousefi

Recently, clustering of inertial particles in turbulence has been thoroughly analyzed for statistically homogeneous isotropic flows. Phenomenologically, spatial homogeneity of particles configurations is broken by the advection of a range…

Chaotic Dynamics · Physics 2015-05-13 P. Gualtieri , F. Picano , C. M. Casciola