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We formulate a general mean-field theory of a flat electric double layer in ionic liquids and electrolyte solutions with ions possessing static polarizability and a permanent dipole moment on a charged electrode. We establish a new…

Statistical Mechanics · Physics 2021-08-17 Yu. A. Budkov , S. V. Zavarzin , A. L. Kolesnikov

An independent control of the flux and energy of ions impacting on an object immersed in a plasma is often desirable for many industrial processes such as microelectronics manufacturing. We demonstrate that a simultaneous control of these…

Plasma Physics · Physics 2018-08-29 Sarveshwar Sharma , Igor Kaganovich , Alexander Khrabrov , Predhiman Kaw , Abhijit Sen

Biomembranes are thin capacitors with the unique feature of displaying phase transitions in a physiologically relevant regime. We investigate the voltage and lateral pressure dependence of their capacitance close to their chain melting…

Biological Physics · Physics 2012-09-18 Thomas Heimburg

We use a coarse-grained molecular dynamics model to study the electrophoretic behaviour of flexible polyelectrolyte chains. We first characterize the static properties of the model with respect to the chain length, the polyelectrolyte…

Soft Condensed Matter · Physics 2008-12-16 Kai Grass , Christian Holm

The Polarizable Continuum Model (PCM) can be used in conjunction with Density Functional Theory (DFT) and its time-dependent extension (TDDFT) to simulate the electronic and optical properties of molecules and nanoparticles immersed in a…

Materials Science · Physics 2015-10-28 Alain Delgado , Stefano Corni , Stefano Pittalis , Carlo Andrea Rozzi

Understanding the evolution of electrified solid-liquid interfaces during electrochemical reactions is crucial. However, capturing the dynamic behavior of the interfaces with high temporal resolution and accuracy over long timescales…

Chemical Physics · Physics 2024-11-26 Letian Chen , Yun Tian , Xu Hu , Suya Chen , Huijuan Wang , Xu Zhang , Zhen Zhou

The effective potential of electron--electron interaction and the two-particle \textquotedblleft density--density\textquotedblright\ correlation function have been calculated for a simple semiinfinite metal making allowance for the…

Mesoscale and Nanoscale Physics · Physics 2015-03-29 B. M. Markovych , I. M. Zadvorniak

Metasurfaces have provided a novel and promising platform for the realization of compact and large-scale optical devices. The conventional metasurface design approach assumes periodic boundary conditions for each element, which is…

In molecular simulations, neural network force fields aim at achieving \emph{ab initio} accuracy with reduced computational cost. This work introduces enhancements to the Deep Potential network architecture, integrating a message-passing…

Computational Physics · Physics 2024-04-09 Ruiqi Gao , Yifan Li , Roberto Car

Controlling electrochemical reactivity requires a detailed understanding of the charging behavior and thermodynamics of the electrochemical interface. Experiments can independently probe the overall charge response of the electrochemical…

Chemical Physics · Physics 2022-03-10 Abhishek Shandilya , Kathleen Schwarz , Ravishankar Sundararaman

The response of a model micro-electrochemical system to a time-dependent applied voltage is analyzed. The article begins with a fresh historical review including electrochemistry, colloidal science, and microfluidics. The model problem…

Soft Condensed Matter · Physics 2009-11-10 Martin Z. Bazant , Katsuyo Thornton , Armand Ajdari

This thesis explores two different avenues aimed at improving our ability to calculate reliably in the Standard Model of particle physics and probing possible new particles which may exist beyond it. In the first part, we explore whether…

High Energy Physics - Phenomenology · Physics 2007-05-23 Christopher Lee

The dynamic of thermosensitive neuronal networks under the influence of external electric fields is explored, focusing on hybrid coupling models that incorporate both electrical and chemical synapses. Numerical simulations reveal a variety…

Chaotic Dynamics · Physics 2025-09-19 Ediline L. F. Nguessap , Antonio C. Roque , Fernando F. Ferreira

The electric double layer (EDL) governs electrocatalysis, energy conversion, and storage, yet its atomic structure, capacitance, and reactivity remain elusive. Here we introduce a machine learning interatomic potential framework that…

Chemical Physics · Physics 2025-09-18 Xiaoyu Wang , Junmin Chen , Zezhu Zeng , Frederick Stein , Junho Lim , Bingqing Cheng

Based on two-dimensional particle-in-cell simulations a novel approach towards Electron Energy Probability Function (EEPF) and plasma chemistry control by Current Waveform Tailoring (CWT) in the coil of inductively coupled discharges is…

Surface effects on the electronic energy loss of charged particles entering a metal surface are investigated within linear-response theory, in the framework of time-dependent density functional theory. Interesting phenomena occur in the…

Materials Science · Physics 2007-05-23 A. Garcia-Lekue , J. M. Pitarke

Modelling the ionic transport in battery cells requires precise parametrization of the involved electrolytes. For carbonate-based electrolytes, however, the evaluation of their parameters suffers from interphase effects between the bulk…

Density functional theory has been an essential analysis tool for both theoretical and experimental chemists since accurate hybrid functionals were developed. Here we propose a local hybrid method derived from the optimized effective…

Chemical Physics · Physics 2017-03-24 Jaewook Kim , Kwangwoo Hong , Sang-Yeon Hwang , Seongok Ryu , Sunghwan Choi , Woo Youn Kim

An application for high-performance computing (HPC) is shown that is relevant in the field of battery development. Simulations of electrolyte wetting and flow are conducted using pore network models (PNM) and the lattice Boltzmann method…

Computational Engineering, Finance, and Science · Computer Science 2024-01-22 Benjamin Kellers , Martin P. Lautenschlaeger , Julius Weinmiller , Lukas Krumbein , Simon Hein , Timo Danner , Arnulf Latz

We model cyclic voltammetry experiments on supported lipid films where a non-trivial dependence of the capacitance on the applied voltage is observed. Previously, based on a mean-field treatment of the Flory-Huggins type, under the…

Soft Condensed Matter · Physics 2010-07-28 Andrey V. Brukhno , Anna Akinshina , Zachary Coldrick , Andrew Nelson , Stefan Auer