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Simulating electrified metal/water interfaces with explicit solvent under constant potential is essential for understanding electrochemical processes, yet remains prohibitively expensive with ab initio methods. We present TRECI, a…

To further develop accurate and large-scale simulations of electrochemical interfaces, we propose a unified explicit electric potential framework to simultaneously predict atomic forces and electron density distributions. The framework…

Chemical Physics · Physics 2026-04-14 Jingwen Zhou , Yawen Yu , Xuwei Liu , Chungen Liu

The interplay of electronic and nuclear degrees of freedom presents an outstanding problem in condensed matter physics and chemistry. Computational challenges arise especially for large systems, long time scales, in nonequilibrium, or in…

Strongly Correlated Electrons · Physics 2024-02-14 Arne Schobert , Jan Berges , Erik G. C. P. van Loon , Michael A. Sentef , Sergey Brener , Mariana Rossi , Tim O. Wehling

Electropermeabilization is a clinical technique in cancer treatment to locally stimulate the cell metabolism. It is based on electrical fields that change the properties of the cell membrane. With that, cancer treatment can reach the cell…

Analysis of PDEs · Mathematics 2016-03-03 Habib Ammari , Thomas Widlak , Wenlong Zhang

The Darwin approximation is investigated for its possible use in simulation of electromagnetic effects in large size, high frequency capacitively coupled discharges. The approximation is utilized within the framework of two different fluid…

Plasma Physics · Physics 2015-06-11 Denis Eremin , Torben Hemke , Ralf Peter Brinkmann , Thomas Mussenbrock

Due to critical environmental and technological issues, there is a pressing need to switch from current refrigeration methods based on compression of gases to novel solid-state cooling technologies. Solid-state cooling is based on the…

Materials Science · Physics 2020-05-12 Claudio Cazorla

We investigate the possibility of electrostatic potential saturation, which may lead to the phenomenon of effective charge saturation. The system under study is a uniformly charged infinite plane immersed in an arbitrary electrolyte made up…

Soft Condensed Matter · Physics 2007-05-23 Gabriel Tellez , Emmanuel Trizac

Semilocal density functional theory is the most used computational method for electronic structure calculations in theoretical solid-state physics and quantum chemistry of large systems, providing good accuracy with a very attractive…

Other Condensed Matter · Physics 2016-03-31 L. A. Constantin , E. Fabiano , J. M. Pitarke , F. Della Sala

In solid-state electrochemical experiments, the boundary between the sample and the electrolyte plays a crucial role, and the rest of the sample acting as a buffer that maintains a fixed composition. Due to the presence of an…

Materials Science · Physics 2023-10-24 Yakov I. Korepanov

Hydrogen is vital for sectors like chemicals and others, driven by the need to reduce carbon emissions. Proton Electrolyte Membrane Water Electrolysis (PEMWE) is a key technology for the production of green hydrogen under fluctuating…

Numerical Analysis · Mathematics 2024-10-10 Dayron Chang Dominguez , An Phuc Dam , Thomas Richter , Kai Sundmacher , Shaun M. Alia

Electrode-electrolyte interfaces are crucial for electrochemical energy conversion and storage. At these interfaces, the liquid electrolytes form electrical double layers (EDLs). However, despite more than a century of active research, the…

In this work, the changes in the energy of electrons and holes, oscillator strength and interband transition time when external fields are applied to a GaAs/AlGaAs semiconductor double ring grown by the droplet epitaxy technique are…

Computational Physics · Physics 2023-09-11 Adrian Radu , Cristina Stan , Doina Bejan

In CFD simulations of two-phase flows, accurate drag force modeling is essential for predicting particle dynamics. However, a generally valid formulation is lacking, as all available drag force correlations have been established for…

Fluid Dynamics · Physics 2023-02-08 Gizem Ozler , Mustafa Demircioglu , Holger Grosshans

Understanding the dynamics of electric-double-layer (EDL) charging in porous media is essential for advancements in next-generation energy storage devices. Due to the high computational demands of direct numerical simulations and a lack of…

Chemical Physics · Physics 2023-09-04 Filipe Henrique , Pawel J. Zuk , Ankur Gupta

Electric double layers (EDL) with counterions only, say electrons with the elementary charge $-e$, in thermal equilibrium at the inverse temperature $\beta$ are considered. In particular, we study the effect of the surface charge modulation…

Statistical Mechanics · Physics 2022-07-26 Ladislav Šamaj

A system of soft ellipsoid molecules confined between two planar walls is studied using classical Density Functional Theory (DFT). Both the isotropic and nematic phases are considered. The excess free energy is evaluated using two different…

Materials Science · Physics 2009-11-10 David Cheung , Friederike Schmid

Dielectric interfaces are crucial to the behavior of charged membranes, from graphene to synthetic and biological lipid bilayers. Understanding electrolyte behavior near these interfaces remains a challenge, especially in the case of rough…

Soft Condensed Matter · Physics 2024-04-03 Nicholas Pogharian , Alexandre P. dos Santos , Ali Ehlen , Monica Olvera de la Cruz

Understanding the local structure of water at the interfaces of metallic electrodes is a key problem in aqueous-based electrochemistry. Nevertheless, a realistic simulation of such setup is challenging, particularly when the electrodes are…

In most PIC/MCC simulations of radio frequency capacitively coupled plasmas (CCPs) several simplifications are made: (i) fast neutrals are not traced, (ii) heavy particle induced excitation and ionization are neglected, (iii) secondary…

Plasma Physics · Physics 2015-06-23 A. Derzsi , I. Korolov , E. Schuengel , Z. Donko , J. Schulze

The inductance/impedance due to thin metallic structures in non-destructive testing (NDT) is difficult to evaluate. In particular, in Finite Element Method (FEM) eddy current simulation, an extremely fine mesh is required to accurately…

Signal Processing · Electrical Eng. & Systems 2019-05-31 Wuliang Yin , Jiawei Tang , Mingyang Lu , Hanyang Xu , Ruochen Huang , Qian Zhao , Zhijie Zhang , Anthony Peyton
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