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We apply a recently developed unsupervised machine learning scheme for local atomic environments to characterize large-scale, disordered aggregates formed by sequence-defined macromolecules. This method provides new insight into the…

Soft Condensed Matter · Physics 2023-01-03 Antonia Statt , Devon C. Kleeblatt , Wesley F. Reinhart

Measuring similarities/dissimilarities between atomic structures is important for the exploration of potential energy landscapes. However, the cell vectors together with the coordinates of the atoms, which are generally used to describe…

The development of high-performance materials for microelectronics, energy storage, and extreme environments depends on our ability to describe and direct property-defining microstructural order. Our present understanding is typically…

We introduce a new fingerprint that allows distinguishing between liquid-like and solid-like atomic environments. This fingerprint is based on an approximate expression for the entropy projected on individual atoms. When combined with a…

Materials Science · Physics 2020-04-10 Pablo M. Piaggi , Michele Parrinello

Despite numerous efforts from numerical approaches to complement experimental measurements, several fundamental challenges have still hindered one's ability to truly provide an atomistic picture of the nucleation process in nanocrystals.…

Crystallization within the discrete spheres of a block copolymer mesophase was studied by time-resolved x-ray scattering. The cubic packing of microdomains, established by self-assembly in the melt, is preserved throughout crystallization…

Soft Condensed Matter · Physics 2009-10-31 Yueh-Lin Loo , Richard A. Register , Anthony J. Ryan

Originating from image recognition, methods of machine learning allow for effective feature extraction and dimensionality reduction in multidimensional datasets, thereby providing an extraordinary tool to deal with classical and quantum…

Statistical Mechanics · Physics 2019-01-16 Albert A. Shirinyan , Valerii K. Kozin , Johan Hellsvik , Manuel Pereiro , Olle Eriksson , Dmitry Yudin

Homogeneous nucleation process of polyethylene (PE) is studied with full-atom molecular dynamic simulation. To account the complex shape with low symmetry and the peculiar intra-chain conformational order of polymer, we introduce a shape…

Soft Condensed Matter · Physics 2017-12-13 Xiaoliang Tang , Junsheng Yang , Tingyu Xu , Fucheng Tian , Chun Xie , Liangbin Li

Understanding the nature of glass transition, as well as precise estimation of the glass transition temperature for polymeric materials, remain open questions in both experimental and theoretical polymer sciences. We propose a data-driven…

Soft Condensed Matter · Physics 2023-08-03 Atreyee Banerjee , Hsiao-Ping Hsu , Kurt Kremer , Oleksandra Kukharenko

Spontaneous self-assembly of hard convex polyhedra are known to form orientationally disordered crystalline phases, where particle orientations do not follow the same pattern as the positional arrangement of the crystal. A distinct type of…

Soft Condensed Matter · Physics 2024-12-02 Sumitava Kundu , Kaustav Chakraborty , Avisek Das

We investigate crystal nucleation in supersaturated colloid suspensions using enhanced molecular dynamics simulations augmented with machine learning techniques. The simulations reveal that crystallization in the model colloidal system…

Soft Condensed Matter · Physics 2024-04-30 Vanessa J. Meraz , Ziyue Zou , Pratyush Tiwary

High-fidelity measurements are important for the physical implementation of quantum information protocols. Current methods for classifying measurement trajectories in superconducting qubit systems produce fidelities that are systematically…

Quantum Physics · Physics 2015-05-27 Easwar Magesan , Jay M. Gambetta , A. D. Córcoles , Jerry M. Chow

Most of the current understanding of structure-property relations at the molecular and the supramolecular scales can be formulated in terms of the stability of and the interactions between a limited number of recurring structural motifs…

Chemical Physics · Physics 2018-01-29 Piero Gasparotto , Robert Horst Meißner , Michele Ceriotti

This paper proposes a machine learning (ML) method to predict stable molecular geometries from their chemical composition. The method is useful for generating molecular conformations which may serve as initial geometries for saving time…

We propose a computationally lean, two-stage approach that reliably predicts self-assembly behavior of complex charged molecules on a metallic surfaces under electrochemical conditions. Stage one uses ab initio simulations to provide…

Computational Physics · Physics 2020-07-15 Benedikt Hartl , Shubham Sharma , Oliver Brügner , Stijn F. L. Mertens , Michael Walter , Gerhard Kahl

The crystallisation of entangled polymers from their melt is investigated using computer simulation with a coarse-grained model. Using hybrid Monte Carlo simulations enables us to probe the behaviour of long polymer chains. We identify…

Soft Condensed Matter · Physics 2020-06-12 Xiaoliang Tang , Fucheng Tian , Tingyu Xu , Liangbin Li , Aleks Reinhardt

By molecular dynamics simulations and free energy calculations based on Monte Carlo method, the detailed balance between Pt cluster isomers was investigated. For clusters of n<=50, stationary equilibrium is achieved in 100 ns in the…

Chemical Physics · Physics 2014-12-16 Zheng-Zhe Lin

We report a novel multi-scale simulation methodology to quantitatively predict the thermodynamic behaviour of polymer mixtures, that exhibit phases with broken orientational symmetry. Our system consists of a binary mixture of oligomers and…

Soft Condensed Matter · Physics 2021-12-07 William S. Fall , Hima Bindu Kolli , Biswaroop Mukherjee , Buddhapriya Chakrabarti

Polymer-derived ceramics combine the thermal stability of ceramics with the versatile properties of carbon domains, but modeling their atomic-scale evolution during processing remains elusive due to the limitations of traditional…

We report a deep learning (DL) framework viz. deep autoencoder that autonomously discovers an appropriate order parameter from molecular dynamics (MD) simulation data to characterize the coil to globule phase transition of a polymer. The…

Materials Science · Physics 2021-02-25 Debjyoti Bhattacharya , Tarak K Patra