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When an isolated quantum system is driven out of equilibrium, expectation values of general observables start oscillating in time. This article reviews the general theory of such temporal fluctuations. We first survey some results on the…

Statistical Mechanics · Physics 2015-09-02 Lorenzo Campos Venuti , Paolo Zanardi

We study current fluctuations in lattice gases in the hydrodynamic scaling limit. More precisely, we prove a large deviation principle for the empirical current in the symmetric simple exclusion process with rate functional I. We then…

Probability · Mathematics 2015-12-18 L. Bertini , A. De Sole , D. Gabrielli , G. Jona-Lasinio , C. Landim

We consider quantum batteries given by composite interacting quantum systems in terms of the thermodynamic work cost of local random unitary processes. We characterize quantum correlations by monitoring the average energy change and its…

Quantum Physics · Physics 2026-03-30 Satoya Imai , Otfried Gühne , Stefan Nimmrichter

An open question of fundamental importance in thermodynamics is how to describe the fluctuations of work for quantum coherent processes. In the standard approach, based on a projective energy measurement both at the beginning and at the end…

For a four-stroke asymmetrically driven quantum Otto engine with working medium modeled by a single qubit, we study the bounds on non-equilibrium fluctuations of work and heat. We find strict relations between the fluctuations of work and…

Statistical Mechanics · Physics 2023-08-02 Sandipan Mohanta , Madhumita Saha , B. Prasanna Venkatesh , Bijay Kumar Agarwalla

We consider a particle dragged through a medium at constant temperature as described by a Langevin equation with a time-dependent potential. The time-dependence is specified by an external protocol. We give conditions on potential and…

Statistical Mechanics · Physics 2007-08-21 Marco Baiesi , Tim Jacobs , Christian Maes , Nikos S. Skantzos

Free energy fixes the maximum work of a thermodynamic process once the state and Hamiltonian are specified. A work-extraction task asks a different question: how much average work can a single device realize across several preparations and…

Quantum Physics · Physics 2026-05-06 Sumit Rout , Aravinth Balaji Ravichandran , Paweł Horodecki , Anubhav Chaturvedi

The decay rate for a particle in a metastable cubic potential is investigated in the quantum regime by the Euclidean path integral method in semiclassical approximation. The imaginary time formalism allows one to monitor the system as a…

Statistical Mechanics · Physics 2008-04-22 Marco Zoli

For systems performing a weakly isothermal process, the decorrelation time dictates how fast the relaxation function decorrelates. However, like many other thermally isolated systems, the transverse-field quantum Ising chain presents an…

Statistical Mechanics · Physics 2023-12-05 Pierre Nazé

For driven open systems in contact with multiple heat reservoirs, we find the marginal distributions of work or heat do not satisfy any fluctuation theorem, but only the joint distribution of work and heat satisfies a family of fluctuation…

Statistical Mechanics · Physics 2023-03-08 Jin-Fu Chen , H. T. Quan

The thermodynamic uncertainty relation, originally derived for classical Markov-jump processes, provides a trade-off relation between precision and dissipation, deepening our understanding of the performance of quantum thermal machines.…

Statistical Mechanics · Physics 2021-03-31 Junjie Liu , Dvira Segal

In this work, I analyze the quantum fluctuations and the thermal fluctuations in the framework of quantum mechanics. Being recognized as incoherent perturbations with different features, fluctuations of these two types lead to dissipative…

Quantum Physics · Physics 2025-06-12 Weitao Liu

The postulational basis of classical thermodynamics has been expanded to incorporate equilibrium fluctuations. The main additional elements of the proposed thermodynamic theory are the concept of quasi-equilibrium states, a definition of…

Statistical Mechanics · Physics 2019-06-11 Y. Mishin

We consider work extraction from $N$ copies of a quantum system. When the same work-extraction process is implemented on each copy, the relative size of fluctuations is expected to decay as $1/\sqrt{N}$. Here, we consider protocols where…

Quantum Physics · Physics 2019-08-15 Martí Perarnau-Llobet , Raam Uzdin

Fluctuation relations allow for the computation of equilibrium properties, like free energy, from an ensemble of non-equilibrium dynamics simulations. Computing them for quantum systems, however, can be difficult, as performing dynamic…

Quantum Physics · Physics 2021-09-07 Lindsay Bassman , Katherine Klymko , Diyi Liu , Norman M. Tubman , Wibe A. de Jong

In this work, we present a compact analytical approximation for the quantum partition function of systems composed of quantum oscillators. The proposed formula is general and applicable to an arbitrary number of oscillators described by a…

Statistical Mechanics · Physics 2025-07-08 Michel Caffarel

The asymptotic behaviour of the work probability distribution in driven non-equilibrium systems is determined using the method of optimal fluctuations. For systems described by Langevin dynamics the corresponding Euler-Lagrange equation…

Statistical Mechanics · Physics 2013-05-29 A. Engel

The generating functional is derived for the fluctuation-dissipation relations which result from the unitarity and reversibility of microscopic dynamics and connect various statistical characteristics of many consecutive (continuous)…

Statistical Mechanics · Physics 2007-05-23 Yuriy E. Kuzovlev

Thermodynamic uncertainty relations (TURs) are a set of inequalities expressing a fundamental trade-off between precision and dissipation in non-equilibrium classical and quantum thermodynamic processes. TURs show that achieving low…

Quantum Physics · Physics 2025-03-07 Mario Motta , Antonio Mezzacapo , Giacomo Guarnieri

Nonequilibrium stationary states of thermodynamic systems dissipate a positive amount of energy per unit of time. If we consider transformations of such states that are realized by letting the driving depend on time, the amount of energy…

Statistical Mechanics · Physics 2015-09-25 L. Bertini , D. Gabrielli , G. Jona-Lasinio , C. Landim