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The distribution of the eigenvalues of a Hermitian matrix (or of a Hermitian matrix pencil) reveals important features of the underlying problem, whether a Hamiltonian system in physics, or a social network in behavioral sciences. However,…

Numerical Analysis · Mathematics 2017-06-22 Yuanzhe Xi , Ruipeng Li , Yousef Saad

We present a $G_0W_0$ implementation that assesses the two major bottlenecks of traditional plane-waves implementations, the summations over conduction states and the inversion of the dielectric matrix, without introducing new…

Materials Science · Physics 2015-03-24 Jonathan Laflamme Janssen , Bruno Rousseau , Michel Côté

The work is devoted to the formation energy calculations of intrinsic defects in silicon based on the GW method and the Galitskii-Migdal formula. The two methods for calculating the electronic response function are applied. The first one…

Computational Physics · Physics 2023-11-06 N. L. Matsko

We present an approach for GW calculations of quasiparticle energies with quasi-quadratic scaling by approximating high-energy contributions to the Green's function in its Lehmann representation with effective stochastic vectors. The method…

Materials Science · Physics 2023-12-07 Aaron R. Altman , Sudipta Kundu , Felipe H. da Jornada

We present a new all-electron, augmented-wave implementation of the GW approximation using eigenfunctions generated by a recent variant of the full-potential LMTO method. The dynamically screened Coulomb interaction W is expanded in a mixed…

Materials Science · Physics 2009-11-07 Takao Kotani , Mark van Schilfgaarde

Hedin's scheme is solved with the inclusion of the vertex function ($GW\Gamma$) for a set of small molecules. The computational scheme allows for the consistent inclusion of the vertex both at the polarizability level and in the…

Materials Science · Physics 2017-08-17 Emanuele Maggio , Georg Kresse

This article is devoted to computing the eigenvalue of the Laplace eigenvalue problem by the weak Galerkin (WG) finite element method with emphasis on obtaining lower bounds. The WG method is on the use of weak functions and their weak…

Numerical Analysis · Mathematics 2015-08-24 Hehu Xie , Qilong Zhai , Ran Zhang

The $GW$ method delivers substantially improved accuracy in electronic band structure calculations over conventional Kohn-Sham density functional theory (KS-DFT) by explicitly incorporating the electron self-energy effect beyond mean-field…

Materials Science · Physics 2026-05-13 Huanjing Gong , Min-Ye Zhang , Peize Lin , Bohan Jia , Ziqing Guan , Lixin He , Xinguo Ren

Recent work introduced a new framework for analyzing correlation functions with improved convergence and signal-to-noise properties, as well as rigorous quantification of excited-state effects, based on the Lanczos algorithm and spurious…

High Energy Physics - Lattice · Physics 2025-08-25 Daniel C. Hackett , Michael L. Wagman

The quasiparticle self-consistent QS$GW$ approach incorporates the corrections of the quasiparticle energies from their Kohn-Sham density functional theory (DFT) eigenvalues by means of an energy independent and Hermitian self-energy matrix…

Materials Science · Physics 2022-06-08 Ozan Dernek , Dmitry Skachkov , Walter R. L. Lambrecht , Mark van Schilfgaarde

In recent years, the $GW$ method has emerged as a reliable tool for computing core-level binding energies. The contour deformation (CD) technique has been established as an efficient, scalable, and numerically stable approach to compute the…

Computational Physics · Physics 2023-10-23 Ramón L. Panadés-Barrueta , Dorothea Golze

We test the performance of self-consistent GW and several representative implementations of vertex corrected G0W0 (G0W0{\Gamma}). These approaches are tested on benchmark data sets covering full valence spectra (first ionization potentials…

Chemical Physics · Physics 2024-04-09 Ming Wen , Vibin Abraham , Gaurav Harsha , Avijit Shee , K. Birgitta Whaley , Dominika Zgid

We examine the accuracy of the microcanonical Lanczos method (MCLM) developed by Long, {\it et al.} [Phys. Rev. B {\bf 68}, 235106 (2003)] to compute dynamical spectral functions of interacting quantum models at finite temperatures. The…

Strongly Correlated Electrons · Physics 2018-04-23 Satoshi Okamoto , Gonzalo Alvarez , Elbio Dagotto , Takami Tohyama

Within the framework of the full potential projector-augmented wave methodology, we present a promising low-scaling $GW$ implementation. It allows for quasiparticle calculations with a scaling that is cubic in the system size and linear in…

Materials Science · Physics 2016-10-12 Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

We analyze the Lanczos method for matrix function approximation (Lanczos-FA), an iterative algorithm for computing $f(\mathbf{A}) \mathbf{b}$ when $\mathbf{A}$ is a Hermitian matrix and $\mathbf{b}$ is a given vector. Assuming that $f :…

Numerical Analysis · Mathematics 2022-05-19 Tyler Chen , Anne Greenbaum , Cameron Musco , Christopher Musco

We present an algorithm that uses block encoding on a quantum computer to exactly construct a Krylov space, which can be used as the basis for the Lanczos method to estimate extremal eigenvalues of Hamiltonians. While the classical Lanczos…

Quantum Physics · Physics 2023-05-24 William Kirby , Mario Motta , Antonio Mezzacapo

This paper analyses the GW method for finite electronic systems. In a first step, we provide a mathematical framework for the usual one-body operators that appear naturally in many-body perturbation theory. We then discuss the GW equations…

Mathematical Physics · Physics 2025-05-20 Eric Cancès , David Gontier , Gabriel Stoltz

We expand on a recently introduced alternate framework for $GW$ simulation of charged excitations [Scott et. al., J. Chem. Phys., 158, 124102 (2023)], based around the conservation of directly computed spectral moments of the GW…

Chemical Physics · Physics 2025-08-08 Oliver J. Backhouse , Marcus K. Allen , Charles C. J. Scott , George H. Booth

The $GW$ approximation has become an important tool for predicting charged excitations of isolated molecules and condensed systems. Its popularity can be attributed to many factors, including a favorable scaling and relatively good…

Chemical Physics · Physics 2023-12-18 Daniel Mejia-Rodriguez

The dielectric response function and its inverse are crucial physical quantities in materials science. We propose an accurate and efficient strategy to invert the dielectric function matrix. The GW approximation, a powerful approach to…

Numerical Analysis · Mathematics 2024-06-13 Zhengbang Zhou , Huanhuan Ma , Wentiao Wu , Weiguo Gao , Jinlong Yang , Meiyue Shao , Wei Hu