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Singlet fission is a photoconversion process that generates a doubly excited, maximally spin entangled pair state. This state has applications to quantum information and computing that are only beginning to be realized. In this article, we…

Chemical Physics · Physics 2020-11-11 Kori Smyser , Joel Eaves

Singlet fission, a spin-allowed energy transfer process generating two triplet excitons from one singlet exciton, has the potential to dramatically increase the efficiency of organic solar cells. However, the dynamical mechanism of this…

Materials Science · Physics 2015-06-12 Timothy C. Berkelbach , Mark S. Hybertsen , David R. Reichman

Singlet fission describes the spin-conserving production of two triplet excitons from one singlet exciton. The existence of a spin-2 (quintet) triplet-pair state as a product of singlet fission is well established in the literature, and…

Mesoscale and Nanoscale Physics · Physics 2022-06-03 Miles I. Collins , Francesco Campaioli , Murad J. Y. Tayebjee , Jared H. Cole , Dane R. McCamey

Singlet fission is a spin-allowed exciton multiplication process in organic semiconductors that converts one spin-singlet exciton to two triplet excitons. It offers the potential to enhance solar energy conversion by circumventing the…

This study explores the role of nucleon exchange for the generation of the fission fragment angular momenta. For a number of typical fission cases, samples of 10,000 shape evolutions are generated by Langevin simulation and, subsequently,…

Nuclear Theory · Physics 2026-03-31 Jorgen Randrup , Pavel Nadtochy , Christelle Schmitt , Katarzyna Mazurek

Singlet fission is a form of multiple exciton generation which occurs in organic chromophores when a high energy singlet exciton separates into two lower energy triplet excitons, each with approximately half the singlet energy. Since this…

We investigate the physical mechanisms for spin-dependent recombination of a strongly bound pair of triplet excitons generated by singlet fission and forming a spin quintet (total spin of two) bi-exciton. For triplet excitons the…

Mesoscale and Nanoscale Physics · Physics 2024-02-16 Yan Sun , L. R. Weiss , V. Derkach , J. E. Anthony , M. Monteverde , A. D. Chepelianskii

Metastable condensed matter typically fluctuates about local energy minima at the femtosecond time scale before transitioning between local minima after nanoseconds or microseconds. This vast scale separation limits the applicability of…

Computational Physics · Physics 2017-11-22 Brittan A Farmer , Mitchell Luskin , Petr Plecháč , Gideon Simpson

Singlet fission, a process that splits a singlet exciton into a biexciton, has promise in quantum information. We report time-resolved electron paramagnetic resonance measurements on a molecule, TIPS-BP1$'$, designed to exhibit strongly…

Chemical Physics · Physics 2022-02-22 Ryan D. Dill , Kori E. Smyser , Niels H. Damrauer , Joel D. Eaves

Singlet fission, the molecular process through which photons are effectively converted into pairs of lower energy triplet excitons, holds promise as a means of boosting photovoltaic device efficiencies. In the preceding article of this…

Materials Science · Physics 2017-05-12 Roel Tempelaar , David R. Reichman

The emergent dynamical processes associated with magnetic excitations in heavy-fermion SmB$_6$ are investigated. By imposing multiorbital interactions on a first-principles model, we find the interplay between spin and orbital fluctuations…

Strongly Correlated Electrons · Physics 2018-06-22 Christopher N. Singh , Wei-Cheng Lee

We characterize fluctuations in atom number and spin populations in F=1 sodium spinor condensates. We find that the fluctuations enable a quantitative measure of energy dissipation in the condensate. The time evolution of the population…

Other Condensed Matter · Physics 2015-05-13 Yingmei Liu , Eduardo Gomez , Stephen E. Maxwell , Lincoln D. Turner , Eite Tiesinga , Paul D. Lett

Energy dependence of fission observables is a key issue for wide nuclear applications. We studied real-time fission dynamics from low-energy to high excitations in the compound nucleus $^{240}$Pu with the time-dependent Hartree-Fock+BCS…

Nuclear Theory · Physics 2021-03-31 Yu Qiang , Junchen Pei , Paul Stevenson

To push commercial electronics beyond its current size limits, atomic-scale communication channels and logic units need to be designed, making the use of quantum entities an imperative. In this regime, quantum fluctuations naturally become…

Mesoscale and Nanoscale Physics · Physics 2017-04-12 Leonardo Banchi , Joaquin Fernandez-Rossier , Cyrus F. Hirjibehedin , Sougato Bose

Singlet fission may boost photovoltaic efficiency [by transforming a singlet exciton into two triplet excitons and thereby doubling the number of excited charge carriers. The primary step of singlet fission is the ultrafast creation of the…

We report on the control of spin pair fluctuations using two-tone Floquet engineering. We consider a one-dimensional spin-1/2 lattice with periodically modulated spin exchanges using parametric resonances. The stroboscopic dynamics…

Quantum Physics · Physics 2024-12-25 Ruben Peña , Felipe Torres , Guillermo Romero

Singlet fission is commonly defined to involve a process by which an overall singlet state with local triplet structure spin-decoheres into two triplet states, thereby completing the fission process. This process, often defined in loose…

Chemical Physics · Physics 2020-07-29 Max Marcus , William Barford

Several recent electron spin resonance studies have observed a quintet multiexciton state during the singlet fission process. Here we provide a general theoretical explanation for the generation of this state by invoking a time-varying…

Materials Science · Physics 2020-01-08 Miles I. Collins , Dane R. McCamey , Murad J. Y. Tayebjee

We study photon-mediated interactions between molecular spin qudits in the dispersive regime of operation. We derive from a microscopic model the effective interaction between molecular spins, including their crystal field anisotropy (i.e.,…

Quantum Physics · Physics 2022-08-17 Álvaro Gómez-León

The mechanisms underlying coherent and thermally activated singlet exciton fission in pi-stacked acene crystals are clarified based on quantum dynamics simulations parameterized against a highly correlated description of the electronic…

Materials Science · Physics 2015-04-21 Hiroyuki Tamura , Miquel Huix-Rotllant , Irene Burghardt , Yoann Olivier , David Beljonne
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