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The magnetic response of the Tsai-type 1/1 Au-Al-Gd approximant crystals (ACs) was quantitatively investigated in terms of the magnetic entropy change ($\Delta S_{M}$) for different magnetic ground states. A comprehensive $\Delta S_{M}$ map…

The present research introduces a novel strategy for tuning magnetic properties by overcoming the compositional limitation of stoichiometric intermetallic compounds via extension of their stability into a new dimension within valence…

Materials Science · Physics 2025-06-06 Farid Labib , Hiroyuki Takakura , Asuka Ishikawa , Takenori Fujii , Ryuji Tamura

Systematic research was performed to investigate magnetic properties of the Tsai-type Ga-Pd-RE (RE = Gd, Tb, Dy, and Ho) systems, where both 1/1 and 2/1 quasicrystal approximants (ACs) are attainable at the same compositions as…

Materials Science · Physics 2023-05-19 Farid Labib , Hiroyuki Takakura , Asuka Ishikawa , Ryuji Tamura

A systematic investigation has been performed to elucidate effects of Rare-Earth (RE) type and local atomic configuration on magnetic properties of icosahedral quasicrystal (iQC) and their cubic approximants (2/1 and 1/1 ACs) in the ternary…

The structural and physical properties of two single-grain Au-Al-Gd 1/1 approximant crystals (ACs) with analyzed compositions Au73.67Al12.24Gd14.09 and Au74.67Al11.35Gd13.98 were thoroughly investigated. The two variants are iso-structural…

Materials Science · Physics 2025-03-18 Farid Labib , Takanori Sugimoto , Hiroyuki Takakura , Asuka Ishikawa , Ryuji Tamura

Rare-earth element containing aperiodic quasicrystals and their related periodic approximant crystals can exhibit non-trivial physical properties at low temperatures. Here, we investigate the 1/1 and 2/1 approximant crystal phases of the…

Strongly Correlated Electrons · Physics 2025-03-24 A. Khansili , Y. -C. Huang , U. Häussermann , C. Pay Gomez , A. Rydh

Magnetic orders of non-Heisenberg Tsai-type 1/1 approximant crystals (ACs) in the Au-Ga-Dy system were studied through bulk magnetization, neutron diffraction, and inelastic neutron scattering techniques. The results uncovered noncoplanar,…

We report a new Au-Ga-Ce 1/1 approximant crystal (AC) which possesses a significantly wide single-phase region of 53 - 70 at% Au and 13.6 - 15.1 at% Ce. Single crystal X-ray structural analyses reveal the existence of two types of…

We investigate the structural, magnetocrystalline anisotropy, critical behaviour, and magnetocaloric effect in the layered room-temperature monoclinic ferromagnet Cr$_{1.38}$Te$_2$. The critical behavior is studied by employing various…

The various magnetic orders observed in approximant crystals of Tsai-type quasicrystal are important for deepening our understanding of mysterious magnetism in quasicrystals. Using an icosahedral cluster model with inter-cluster…

Materials Science · Physics 2025-03-26 Takanori Sugimoto , Shintaro Suzuki , Ryuji Tamura , Takami Tohyama

Quantum criticality has been considered to be specific to crystalline materials such as heavy fermions. Very recently, however, the Tsai-type quasicrystal Au51Al34Yb15 has been reported to show unusual quantum critical behavior. To obtain a…

Motivated by recent discovery of canted ferromagnetism in Tsai-type approximants Au-Si-RE (RE = Tb, Dy, Ho), we propose a phenomenological magnetic model reproducing their magnetic structure and thermodynamic quantities. In the model, cubic…

Strongly Correlated Electrons · Physics 2016-05-04 Takanori Sugimoto , Takami Tohyama , Takanobu Hiroto , Ryuji Tamura

We study the magnetocaloric effect and critical behavior of Co$_2$Cr$_{1-x}$Mn$_x$Al ($x=$ 0.25, 0.5, 0.75) Heusler alloys across the ferromagnetic (FM) transition (T$_{\rm C}$). The Rietveld refinement of x-ray diffraction patterns exhibit…

Materials Science · Physics 2020-01-08 Priyanka Nehla , V. K. Anand , Bastian Klemke , Bella Lake , R. S. Dhaka

In a narrow composition range centered at Zn74.5Au10.5Yb15.0, Tsai-type icosahedral quasicrystal is formed in alloys quenched from 880 C. This quasicrystal belongs to the primitive type with the 6-dimensional lattice parameter a6D=7.378 A.…

Materials Science · Physics 2020-01-08 Tsutomu Ishimasa

We investigate the magnetocrystalline anisotropy, critical behavior, and magnetocaloric effect in ferromagnetic-layered Cr$_2$Te$_3$. We have studied the critical behavior around the Curie temperature ($T_C$) using various techniques,…

Materials Science · Physics 2024-07-26 Shubham Purwar , Tushar Kanti Bhowmik , Soumya Ghorai , Setti Thirupathaiah

A magnetic phase diagram of the non-Heisenberg Tsai-type 1/1 Au-Ga-Tb approximant crystal (AC) has been established across a wide electron-per-atom (e/a) range via magnetization and powder neutron diffraction measurements. The diagram…

We have synthesized new Tsai-type Yb-based intermediate-valence approximant crystals (ACs) with different degree of approximation to quasicrystal, Zn--Au--Yb 1/1 and 2/1 AC, and studied the external pressure effect on their Yb mean-valence…

Ground-state properties of rare-earth based 1/1 periodic approximants of icosahedral quasicrystal are clarified theoretically on the basis of an effective model for magnetism taking into account uniaxial anisotropy arising from crystalline…

Strongly Correlated Electrons · Physics 2026-03-12 Shinji Watanabe , Tatsuya Iwasaki

We investigate the magnetic behavior and critical exponents of quaternary CoFeV$_{0.8}$Mn$_{0.2}$Si Heusler alloy to understand the interactions across the Curie temperature ($T_{\rm C}$). The Rietveld refinement of the x-ray diffraction…

Materials Science · Physics 2023-10-04 Guru Dutt Gupt , P. D. Babu , R. S. Dhaka

For ferromagnets, varying from simple metals to strongly correlated oxides,the critical behaviors near the Curie temperature (TC) can be grouped into several universal classes. In this paper, we report an unusual critical behavior in…

Strongly Correlated Electrons · Physics 2015-03-05 J. C. Lin , P. Tong , D. P. Cui , C. Yang , J. Yang , S. Lin , B. S. Wang , W. Tong , L. Zhang , Y. M. Zou , Y. P. Sun
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