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We discovered unique uniaxial negative thermal expansion (NTE) behavior for a weak-itinerant-ferromagnetic phase of CoZr$_{2}$H$_{3.49}$. CoZr$_{2}$ is known as a superconductor exhibiting uniaxial NTE along the $c$-axis, which is called…

Materials Science · Physics 2025-09-26 Yuto Watanabe , Kota Suzuki , Takayoshi Katase , Akira Miura , Aichi Yamashita , Yoshikazu Mizuguchi

In this work, we show that the CuAl2-type superconductor CoZr2 and alloyed systems exhibit anomalous thermal expansion in a wide temperature range. We performed neutron powder diffraction and X-ray powder diffraction on CoZr2 and observed…

Materials Science · Physics 2022-09-23 Yoshikazu Mizuguchi , Md. Riad Kasem , Yoichi Ikeda

Recently, uniaxial negative thermal expansion (NTE) has been observed in transition-metal zirconides including tetragonal (CuAl2-type) CoZr2 and orthorhombic (Re3B-type) CoZr3. Here, we report the observation of uniaxial NTE in tetragonal…

Materials Science · Physics 2023-06-14 Yoshikazu Mizuguchi

The negative thermal expansion (NTE) compound ZrW2O8 has been well-studied because it remains cubic with a nearly constant, isotropic NTE coefficient over a broad temperature range. However, its elastic constants seem just as strange as its…

Materials Science · Physics 2007-05-23 C. Pantea , A. Migliori , P. B. Littlewood , Y. Zhao , H. Ledbetter , T. Kimura , J. Van Duijn , G. R. Kowach

We investigated the structural, electronic, and superconducting properties of Co1-xNixZr2, in which c-axis thermal expansion is systematically controlled. At x (smaller than) 0.3, c-axis negative thermal expansion (NTE) was observed, and…

Superconductivity · Physics 2023-03-28 Yuto Watanabe , Hiroto Arima , Hidetomo Usui , Yoshikazu Mizuguchi

We investigated the temperature evolution of crystal structure of orthorhombic CoZr3, which is a superconductor with a transition temperature of 4.3 K, by synchrotron and laboratory (CuK{\alpha}) X-ray diffraction. Uniaxial negative thermal…

The negative thermal expansion (NTE) mechanism in Cu2O has been characterised via mapping of different Cu2O structural flexibility models onto phonons obtained using ab-initio lattice dynamics. Low frequency acoustic modes that are…

Recently, huge uniaxial negative thermal expansion (NTE) along a $c$-axis has been observed in transition-metal ($Tr$) zirconides $Tr$Zr$_{2}$ with a tetragonal CuAl$_{2}$-type structure. In a recent study on FeZr$_{2}$ [M. Xu et al., Nat.…

We use a combination of variable-temperature / variable-pressure neutron powder diffraction, variable-pressure inelastic neutron scattering, and quantum chemical calculations to interrogate the behaviour of the negative thermal expansion…

Pressure and temperature dependence of the negative thermal expansion in Zn(CN)$_2$ is fully investigated using molecular dynamics simulations with a built potential model. The advantage of this study allows us to reproduce all the exotic…

Materials Science · Physics 2014-07-02 Hong Fang , Martin T. Dove , Leila H. N. Rimmer , Alston J. Misquitta

Negative thermal expansion (NTE) is unusual but important property for control of thermal expansion. In the present study, the chemical modification is utilized to engineer controllable thermal expansion in cubic NTE ScF3. A broad window of…

Materials Science · Physics 2016-12-09 Xiaojian Wang , Jun Chen , Fei Han , Yang Ren , Tao Wang , Jinxia Deng , Xianran Xing

Negative thermal expansion in ZrW2O8 was investigated using a flexibility analysis of ab-initio phonons. It was shown that no previously proposed mechanism adequately describes the atomic-scale origin of negative thermal expansion in this…

Materials Science · Physics 2016-02-17 Leila H. N. Rimmer , Martin T. Dove , Keith Refson

Origin and composition dependence of the anisotropic thermomechanical properties are elucidated for Ba1-xSrxZn2Si2O7 (BZS) solid solutions. The high-temperature phase of BZS shows negative thermal expansion (NTE) along one crystallographic…

We have devised an isotropic interaction potential that gives rise to negative thermal expansion (NTE) behavior in equilibrium many-particle systems in both two and three dimensions over a wide temperature and pressure range (including zero…

Materials Science · Physics 2008-07-24 Mikael C. Rechtsman , Frank H. Stillinger , Salvatore Torquato

We have investigated temperature dependence of the lattice parameters and the unit cell volume of ZnF$_2$ by neutron diffraction and have discovered negative thermal expansion (NTE) at low temperature. To understand why this simple compound…

Materials Science · Physics 2012-07-03 Tapan Chatterji , Mohamed Zbiri , Thomas C. Hansen

Very recently, NiTe2 has been reported to be a type II Dirac semimetal with Dirac nodes near the Fermi surface. Furthermore, it is unveiled that NiTe2 presents the Hall Effect, which is ascribed to orbital magnetoresistance. The physical…

This study examines the temperature-dependent evolution of the lattice constants for various CuAl2-type compounds, including NiZr2, (Co,Rh,Ir)Zr2, (Fe,Co,Rh,Ir)Zr2, and (Co,Ni,Cu,Rh,Ir)Zr2, in the pursuit of negative or zero thermal…

Materials Science · Physics 2023-09-06 Hiroto Arima , Md. Riad Kasem , Yoshikazu Mizuguchi

Previous experiments and numerical simulations have revealed that a limited number of two- and three-dimensional particle systems contract in volume upon heating isobarically. This anomalous phenomenon is known as negative thermal expansion…

Soft Condensed Matter · Physics 2025-07-21 Igor Travěnec , Ladislav Šamaj

The recent discovery of large and non-saturating magnetoresistance (LMR) in WTe2 provides a unique playground to find new phenomena and significant perspective for potential applications. Here we report the first observation of…

The discovery of unusual negative thermal expansion (NTE) provides the opportunity to control the common but much desired property of thermal expansion, which is valuable not only in scientific interests but also in practical applications.…

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