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Excited-state calculations, notably for quasiparticle band structures, are nowadays routinely performed within the GW approximation for the electronic self-energy. Nevertheless, certain numerical approximations and simplifications are still…

We present a new reciprocal space analytical method to cutoff the long range interactions in supercell calculations for systems that are infinite and periodic in 1 or 2 dimensions, extending previous works for finite systems. The proposed…

Other Condensed Matter · Physics 2009-11-11 Carlo A. Rozzi , Daniele Varsano , Andrea Marini , Eberhard K. U. Gross , Angel Rubio

Separating the Coulomb potential into short-range and long-range components enables the use of different electron repulsion integral algorithms for each component. The short-range part can be efficiently computed using the analytical…

Chemical Physics · Physics 2023-09-27 Qiming Sun

We present a reciprocal space technique for the calculation of the Coulomb integral in two dimensions in systems with reduced periodicity, i.e., finite systems, or systems that are periodic only in one dimension. The technique consists in…

Other Condensed Matter · Physics 2009-10-09 Alberto Castro , Esa Rasanen , Carlo Andrea Rozzi

Coulomb interaction, following an inverse-square force-law, quantifies the amount of force between two stationary and electrically charged particles. The long-range nature of Coulomb interactions poses a major challenge to molecular…

Computational Physics · Physics 2022-01-26 Jiuyang Liang , Pan Tan , Yue Zhao , Lei Li , Shi Jin , Liang Hong , Zhenli Xu

Quadratic methods with heuristic weighting (e.g. pseudo-C_l or correlation function methods) represent an efficient way to estimate power spectra of the cosmic microwave background (CMB) anisotropies and their polarization. We construct the…

Astrophysics · Physics 2008-11-26 Anthony Challinor , Gayoung Chon

We study the decomposition of the Coulomb integrals of periodic systems into a tensor contraction of six matrices of which only two are distinct. We find that the Coulomb integrals can be well approximated in this form already with small…

Chemical Physics · Physics 2017-04-05 Felix Hummel , Theodoros Tsatsoulis , Andreas Grüneis

We present an efficient approach for simulating Coulomb systems confined by planar polarizable surfaces. The method is based on the solution of Poisson equation using periodic Green functions. It is shown that the electrostatic energy…

Soft Condensed Matter · Physics 2017-12-12 Alexandre P. dos Santos , Matheus Girotto , Yan Levin

A one-dimensional many-body model is established to mimic the charge distribution and dynamics in nonfullerene organic solar cells. Two essential issues are taken into account in the model: The alternating donor and acceptor structure and…

Materials Science · Physics 2018-12-05 Yao Yao

A method to sum over logarithmic potential in 2D and Coulomb potential in 3D with periodic boundary conditions in all directions is given. We consider the most general form of unit cells, the rhombic cell in 2D and the triclinic cell in 3D.…

Soft Condensed Matter · Physics 2009-11-10 Sandeep Tyagi

A Hartree-Fock and Hartree-Fock-Bogoliubov study of a few body system of spatially separated charge carriers was carried out. Using these variational states, we compute an approximation to the correlation energy of a finite system of…

Mesoscale and Nanoscale Physics · Physics 2009-11-30 Ian Mondragon-Shem , Francisco E. Lopez , Boris A. Rodriguez

I propose a method to calculate logarithmic interaction in two dimensions and coulomb interaction in three dimensions under periodic boundary conditions. This paper considers the case of a rectangular cell in two dimensions and an…

Statistical Mechanics · Physics 2009-11-10 Sandeep Tyagi

A field theoretic representation of the classical partition function is derived for a system composed of a mixture of anisotropic and isotropic mobile charges that interact {\sl via} long range Coulomb and short range nematic interactions.…

Soft Condensed Matter · Physics 2021-01-29 Rudolf Podgornik

An implementation of the Hartree-Fock (HF) method capable of robust convergence for well-behaved arbitrary central potentials is presented. The Hartree-Fock equations are converted to a generalized eigenvalue problem by employing a B-spline…

Atomic Physics · Physics 2021-08-13 D. T. Waide , D. G. Green , G. F. Gribakin

A practical method to solve cut-off Coulomb problems of two-cluster systems in the momentum space is given. When a sharply cut-off Coulomb force with a cut-off radius $\rho$ is introduced at the level of constituent particles, two-cluster…

Nuclear Theory · Physics 2012-09-03 Yoshikazu Fujiwara , Kenji Fukukawa

We derive formulas for the Coulomb matrix within the full-potential linearized augmented-plane-wave (FLAPW) method. The Coulomb matrix is a central ingredient in implementations of many-body perturbation theory, such as the Hartree-Fock and…

Materials Science · Physics 2010-03-01 Christoph Friedrich , Arno Schindlmayr , Stefan Bluegel

We report on a methodology for the treatment of the Coulomb energy and potential in Kohn-Sham density functional theory that is free from self-interaction effects. Specifically, we determine the Coulomb potential given as the functional…

Materials Science · Physics 2016-06-29 M. Däne , A. Gonis , D. M. Nicholson , G. M. Stocks

We present an efficient algorithm for the all-electron periodic Coulomb matrix based on the Ewald summation combined with the Fourier-transformed Coulomb method. The short-range contributions involving compact densities are evaluated in…

Chemical Physics · Physics 2025-09-23 Hieu Q. Dinh , Adam Rettig , Xintian Feng , Joonho Lee

Bootstrap methods, initially developed for solving statistical and quantum field theories, have recently been shown to capture the discrete spectrum of quantum mechanical problems, such as the single particle Schr\"odinger equation with an…

Mesoscale and Nanoscale Physics · Physics 2021-12-15 Serguei Tchoumakov , Serge Florens

Analytical Hartree-Fock gradients with respect to the cell parameter have been implemented in the electronic structure code CRYSTAL, for the case of three-dimensional periodicity. The code is based on Gaussian type orbitals, and the…

Materials Science · Physics 2007-05-23 K. Doll , R. Dovesi , R. Orlando
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